European Journal of Chemistry 2015, 6(1), 44-47. doi:10.5155/eurjchem.6.1.44-47.1140

Synthesis and characterization of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes with new Schiff base derived from 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione and thiosemicarbazide


Mahmoud Najim Al-Jibouri (1,*) , Saad Mohammad Hasun (2)

(1) Department of Chemistry, College of Science, Al-Mustansiriya University, Baghdad, 964, Iraq
(2) Department of Chemistry, College of Science, Al-Mustansiriya University, Baghdad, 964, Iraq
(*) Corresponding Author

Received: 01 Sep 2014, Accepted: 26 Sep 2014, Published: 31 Mar 2015

Abstract


New transition metal complexes of quinoxaline-2,3-dione-thiosemicarbazone ligand were prepared and characterized by elemental analysis, 1H and 13C NMR spectroscopy. The ligand (LH) was obtained by the reaction of 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione with thiosemicarbazide. All the complexes are found to be monomer in nature and have tetrahedral geometry. The IR spectra data revealed that the new Schiff base behaved as monobasic tridentate ligand through deprotonation of thiol-SH group, oxygen atom of C=O of pyrazine moiety and nitrogen atom of azomethine -C=N- group. However, the molar conductivity measurements proved the neutral nature of all metal complexes in DMSO solution, as well as the magnetic moment measurements investigated the high spin properties of all complexes.


Keywords


Schiff base; Quinoxaline; Benzopyrazine; Thiosemicarbazone; Quinoxalin-2,3-dione; Transition metal complexes

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DOI: 10.5155/eurjchem.6.1.44-47.1140

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[2]. Chandran Muthuselvi, Sankara Sabapathy , Bhagatsingh Ravikumar, Shunmuganarayanan Athimoolam, Navaneethakrishnan Srinivasan, Rajaputi Venkatrama
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[3]. Mahmoud Najim Abid Al-jibouri, Araf Ismael Jabbar, Ahmad H. Ismail
Synthesis and Structural Investigation of Some Transition Metal Complexes Derived from Assembled NO Donor Lewis Base of 6,7-Dimethyl-Quinoxaline-2,3-dione
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[4]. Chandran Muthuselvi, Sankara Sabapathy Pandiaraja, Bhagatsingh Ravikumar, Shunmuganarayanan Athimoolam, Navaneethakrishnan Srinivasan, Rajaputi Venkatraman Krishnakum
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[5]. Chandran Muthuselvi, Sankara Sabapathy Pandiaraja, Bhagatsingh Ravikumar, Shunmuganarayanan Athimoolam, Rajaputi Venkatraman Krishnakum
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How to cite


Al-Jibouri, M.; Hasun, S. Eur. J. Chem. 2015, 6(1), 44-47. doi:10.5155/eurjchem.6.1.44-47.1140
Al-Jibouri, M.; Hasun, S. Synthesis and characterization of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes with new Schiff base derived from 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione and thiosemicarbazide. Eur. J. Chem. 2015, 6(1), 44-47. doi:10.5155/eurjchem.6.1.44-47.1140
Al-Jibouri, M., & Hasun, S. (2015). Synthesis and characterization of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes with new Schiff base derived from 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione and thiosemicarbazide. European Journal of Chemistry, 6(1), 44-47. doi:10.5155/eurjchem.6.1.44-47.1140
Al-Jibouri, Mahmoud, & Saad Mohammad Hasun. "Synthesis and characterization of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes with new Schiff base derived from 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione and thiosemicarbazide." European Journal of Chemistry [Online], 6.1 (2015): 44-47. Web. 19 Nov. 2019
Al-Jibouri, Mahmoud, AND Hasun, Saad. "Synthesis and characterization of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes with new Schiff base derived from 6,7-dimethyl-quinoxaline-2,3(1H,4H)-dione and thiosemicarbazide" European Journal of Chemistry [Online], Volume 6 Number 1 (31 March 2015)

DOI Link: https://doi.org/10.5155/eurjchem.6.1.44-47.1140

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