European Journal of Chemistry 2016, 7(2), 146-151 | doi: https://doi.org/10.5155/eurjchem.7.2.146-151.1393 | Get rights and content






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Synthesis and studies on chromene based reactive azo dyes and their applications on different fabrics


Mohamed Gomaa Badrey (1,*) , Sobhi Mohamed Gomha (2) , Hamada Moustafa Mashaly (3)

(1) Chemistry Department, Faculty of Science, Fayoum University, El-Fayoum, 63514, Egypt
(2) Department of Chemistry, Faculty of Science, University of Cairo, Giza, 12613, Egypt
(3) Dyeing and Printing Department, Textile Division, National Research Center, Giza, 12622, Egypt
(*) Corresponding Author

Received: 07 Jan 2016 | Accepted: 07 Feb 2016 | Published: 30 Jun 2016 | Issue Date: June 2016

Abstract


A number of reactive azo dyes based on chromene moiety were prepared through two inversed routes using 2-amino-7-hydroxy-4-phenyl-4H-chromene-3-carbonitrile, which when coupled to different diazonium salts, yielded the corresponding dyes which were then further reacted with cyanuric chloride. The structures of the prepared dyes were elucidated from their spectral data, elemental analyses and colour measurements. Dyeing of cellulosic and nylon fibers using the prepared dyes was done under suitable conditions. Some properties of the prepared dyes such as fastness properties (washing, rubbing and perspiration) and colour measurements were investigated. The dyes showed very good fastness to washing properties when attached to nylon fibers but poor fastness to light properties were shown.


Keywords


Chromene; Diazonium salts; Fastness to light; Reactive azo dyes; Cyanauric chloride; Fastness to washing

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DOI: 10.5155/eurjchem.7.2.146-151.1393

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Funding information


Dyeing and Printing Department, Textile Division, National Research Center, Giza, 12622, Egypt

Citations

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[1]. Said Benkhaya, Souad M'rabet, Ahmed El Harfi
Classifications, properties, recent synthesis and applications of azo dyes
Heliyon  6(1), e03271, 2020
DOI: 10.1016/j.heliyon.2020.e03271
/


[2]. Amira A. Ghoneim, Nesrin M. Morsy
Synthesis and structure elucidation of some new azo dye from hydroxyquinolin-2(1H)-one derivatives and their antimicrobial evaluation
Journal of the Iranian Chemical Society  15(11), 2567, 2018
DOI: 10.1007/s13738-018-1445-5
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How to cite


Badrey, M.; Gomha, S.; Mashaly, H. Eur. J. Chem. 2016, 7(2), 146-151. doi:10.5155/eurjchem.7.2.146-151.1393
Badrey, M.; Gomha, S.; Mashaly, H. Synthesis and studies on chromene based reactive azo dyes and their applications on different fabrics. Eur. J. Chem. 2016, 7(2), 146-151. doi:10.5155/eurjchem.7.2.146-151.1393
Badrey, M., Gomha, S., & Mashaly, H. (2016). Synthesis and studies on chromene based reactive azo dyes and their applications on different fabrics. European Journal of Chemistry, 7(2), 146-151. doi:10.5155/eurjchem.7.2.146-151.1393
Badrey, Mohamed, Sobhi Mohamed Gomha, & Hamada Moustafa Mashaly. "Synthesis and studies on chromene based reactive azo dyes and their applications on different fabrics." European Journal of Chemistry [Online], 7.2 (2016): 146-151. Web. 8 Jul. 2020
Badrey, Mohamed, Gomha, Sobhi, AND Mashaly, Hamada. "Synthesis and studies on chromene based reactive azo dyes and their applications on different fabrics" European Journal of Chemistry [Online], Volume 7 Number 2 (30 June 2016)

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DOI Link: https://doi.org/10.5155/eurjchem.7.2.146-151.1393

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