European Journal of Chemistry 2016, 7(3), 380-386 | doi: https://doi.org/10.5155/eurjchem.7.3.380-386.1442 | Get rights and content






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Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere


Ganesan Nalini (1) , Natesan Jayachandramani (2) , Radhakrishnan Suresh (3,*) , Venugopal Thanikachalam (4) , Govindasamy Manikandan (5)

(1) Department of Chemistry, Pachaiyappa’s College, Chennai, 600030, India
(2) Department of Chemistry, Pachaiyappa’s College, Chennai, 600030, India
(3) Department of Chemistry, Presidency College, Chennai, 600005, India
(4) Department of Chemistry, Annamalai University, Annamalainagar, 608002, India
(5) Department of Chemistry, Annamalai University, Annamalainagar, 608002, India
(*) Corresponding Author

Received: 24 Apr 2016 | Accepted: 21 May 2016 | Published: 30 Sep 2016 | Issue Date: September 2016

Abstract


The kinetics and decomposition of a new spirooxindole compound, 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro[indoline-3,4’-pyran]-3’,5’-dicarbonitrile was studied by thermo gravimetric technique under non-isothermal conditions. The kinetic parameters were calculated using model-free (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa methods) and model-fitting (Coats-Redfern) methods. The results of the Friedman isoconversional analysis of the thermo gravimetric data suggested that the investigated decomposition process follows a single-step.


Keywords


Spirooxindole; Coats-Redfern method; Thermal decomposition; Flynn-Wall-Ozawa method; Thermodynamic parameters; Kissinger-Akahira-Sunose method

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DOI: 10.5155/eurjchem.7.3.380-386.1442

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[1]. Ganesan Nalini, Natesan Jayachandramani, Radhakrishnan Suresh, Prakasam Thirumurugan, Venugopal Thanikachalam, Govindasamy Manikandan, Dharmalingam Sankari
Synthesis, characterization and thermal decomposition of ethyl-2’-amino-5’-cyano-6’-(1H-indole-3yl)-2-oxospiro[indoline-3,4’-pyran]-3’-carboxylate under non‐isothermal condition in nitrogen atmosphere
European Journal of Chemistry  10(1), 72, 2019
DOI: 10.5155/eurjchem.10.1.72-81.1812
/


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How to cite


Nalini, G.; Jayachandramani, N.; Suresh, R.; Thanikachalam, V.; Manikandan, G. Eur. J. Chem. 2016, 7(3), 380-386. doi:10.5155/eurjchem.7.3.380-386.1442
Nalini, G.; Jayachandramani, N.; Suresh, R.; Thanikachalam, V.; Manikandan, G. Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere. Eur. J. Chem. 2016, 7(3), 380-386. doi:10.5155/eurjchem.7.3.380-386.1442
Nalini, G., Jayachandramani, N., Suresh, R., Thanikachalam, V., & Manikandan, G. (2016). Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere. European Journal of Chemistry, 7(3), 380-386. doi:10.5155/eurjchem.7.3.380-386.1442
Nalini, Ganesan, Natesan Jayachandramani, Radhakrishnan Suresh, Venugopal Thanikachalam, & Govindasamy Manikandan. "Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere." European Journal of Chemistry [Online], 7.3 (2016): 380-386. Web. 8 Jul. 2020
Nalini, Ganesan, Jayachandramani, Natesan, Suresh, Radhakrishnan, Thanikachalam, Venugopal, AND Manikandan, Govindasamy. "Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere" European Journal of Chemistry [Online], Volume 7 Number 3 (30 September 2016)

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DOI Link: https://doi.org/10.5155/eurjchem.7.3.380-386.1442

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