European Journal of Chemistry 2017, 8(3), 293-304. doi:10.5155/eurjchem.8.3.293-304.1603

Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution


Liliana Giraldo (1) , Marlon Bastidas-Barranco (2) , Pablo Húmpola (3) , Juan Carlos Moreno-Piraján (4,*)

(1) Facultad de Ciencias, Universidad Nacional de Colombia, Bogotá, 11001000, Colombia
(2) Facultad de Ingeniería, Grupo DestaCar, Universidad de la Guajira, Guajira, 440001, Colombia
(3) Facultad de Bioquímica y Cs. Biológicas, Universidad Nacional del Litoral, Santa Fe, 3000, Argentina
(4) Facultad de Ciencias, Grupo de Investigación en Sólidos Porosos y Calorimetría, Universidad de los Andes, Bogotá, 11001000, Colombia
(*) Corresponding Author

Received: 28 Jun 2017, Accepted: 05 Aug 2017, Published: 30 Sep 2017

Abstract


In this work, the adsorption characteristics of metal-organic frameworks (MOFs: MOF-199 and ZIF-8) with two different types of structure were analyzed. MOF-199 consists of copper-based metal clusters while the ZIF-8 consists of organic molecules interlaced with zinc atoms and these have octahedral morphology and typical rhombic dodecahedron shape, respectively. The results of phenol (Ph) and p-nitro phenol (PNP) adsorption capacity from aqueous solution show that MOF-199 has a higher adsorption capacity: Ph 79.55% and PNP 89.3%, while for ZIF-8 the adsorption capacity was Ph 65.5% and PNP 77.0%. Adsorption of phenols was fit to Langmuir, Sips and Redlich-Peterson models and kinetics by pseudo-second order. Gibbs free energy (ΔG°) shows that adsorption processes studied are spontaneous.


Keywords


ZIF-8; Phenols; MOF-199; Microporous; Metal-organic framework; Adsorption characteristics

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.8.3.293-304.1603

Article Metrics


This Abstract was viewed 966 times | PDF Article downloaded 276 times

References

[1]. Shen, H. M.; Zhua, G. Y.; Yua, W. B.; Wua, H. K.; Jib, H. B.; Shia, H. X. Shea, Y. B.; Zheng, Y. F. Appl. Surf. Sci. 2015, 356, 1155-1167.
https://doi.org/10.1016/j.apsusc.2015.08.203

[2]. Arasteh, R.; Masoumi, M.; Rashidi, A. M.; Moradi, L.; Samimi, V.; Mostafavi, S. T. Appl. Surf. Sci. 2010, 256, 4447-4455.
https://doi.org/10.1016/j.apsusc.2010.01.057

[3]. Liu, W.; Jiang, X. Y.; Chen, X. Q. Appl. Surf. Sci. 2014, 320, 764-771.
https://doi.org/10.1016/j.apsusc.2014.09.165

[4]. Ofomaja, A. E. Unuabonah, E. I. Carbohyd. Polym. 2011, 83, 1192-1200.
https://doi.org/10.1016/j.carbpol.2010.09.023

[5]. Cotoruelo, L. M.; Marques, M. D.; Diaz, F. J.; Rodriguez-Mirasol, J.; Rodriguez, J. J.; Cordero, T. Chem. Eng. J. 2012, 184, 176-183.
https://doi.org/10.1016/j.cej.2012.01.026

[6]. Sarkar, B.; Xi, Y. F.; Megharaj, M.; Krishnamurti, G. S. R.; Naidu, R. J. Colloid. Interf. Sci. 2010, 350, 295-304.
https://doi.org/10.1016/j.jcis.2010.06.030

[7]. Han, S.; Zhao, F.; Sun, J.; Wang, B.; Wei, R. Y.; Yan, S. Q. J. Magn. Magn. Mater. 2013, 341, 133-137.
https://doi.org/10.1016/j.jmmm.2013.04.018

[8]. Isichei, T. O.; Okieimen, F. E. Environ. Pollut. 2014, 3, 99-111.

[9]. Ahmad, F.; Daud, W. M. A. W.; Ahmad, M. A.; Radzi, R. Chem. Eng. J. 2011, 178, 461-467.
https://doi.org/10.1016/j.cej.2011.10.044

[10]. Xue, G. H.; Gao, M. L.; Gu, Z.; Luo, Z. X.; Hu, Z. C. Chem. Eng. J. 2013, 218, 223-231.
https://doi.org/10.1016/j.cej.2012.12.045

[11]. Sarkar, B.; Megharaj, M.; Xi, Y. F.; Naidu, R. Chem. Eng. J. 2012, 185, 35-43.
https://doi.org/10.1016/j.cej.2011.05.062

[12]. Sun, Y. Y.; Zhou, J. B.; Cai, W. Q.; Zhao, R. S.; Yuan, J. P. Appl. Surf. Sci. 2015, 345, 897-903.
https://doi.org/10.1016/j.apsusc.2015.05.041

[13]. Liu, B. J.; Yang, F.; Zou, Y. X.; Peng, Y. J. Chem. Eng. Data. 2014, 59, 1476-1482.
https://doi.org/10.1021/je4010239

[14]. Adam, O. E. A. A.; Al-Dujaili, A. H. J. Chem. 2013, 1-8.
https://doi.org/10.1155/2013/694029

[15]. Park, Y.; Ayoko, G. A.; Kurdi, R.; Horvath, E.; Kristof, J.; Frost, R. L. J. Colloid. Interf. Sci. 2013, 406, 196-208.
https://doi.org/10.1016/j.jcis.2013.05.027

[16]. Bastami, T. R.; Entezari, M. H.; Chem. Eng. J. 2012, 210, 510-519.
https://doi.org/10.1016/j.cej.2012.08.011

[17]. Rivera-Utrilla, J.; Sanchez-Polo, M.; Gomez-Serrano, V.; Alvarez, P. M.; Alvim-Ferraz, M. C. M.; Dias, J. M. J. Hazard. Mater. 2011, 187, 1-23.
https://doi.org/10.1016/j.jhazmat.2011.01.033

[18]. Entezari, M. H.; Bastami, T. R. J. Hazard. Mater. 2006, 137, 959-964.
https://doi.org/10.1016/j.jhazmat.2006.03.019

[19]. Canizares, P.; Lobato, J.; Paz, R.; Rodrigo, M. A.; Saez, C. Water Res. 2005, 39, 2687-2703.
https://doi.org/10.1016/j.watres.2005.04.042

[20]. Shen, S. F.; Kentish, S. E.; Stevens, G. W. Sep. Purif. Technol. 2012, 95, 80-88.
https://doi.org/10.1016/j.seppur.2012.04.023

[21]. Praveen, P.; Loh, K. C. J. Membr. Sci. 2013, 437, 1-6.
https://doi.org/10.1016/j.memsci.2013.02.057

[22]. Peretti, S. W.; Tompkins C. J.; Goodall, J. L.; Michaels, A. S. J. Membr. Sci. 2002, 195, 193-202.
https://doi.org/10.1016/S0376-7388(01)00566-X

[23]. Yao, Y. X.; Li, H. B.; Liu, J. Y.; Tan, X. L; Yu, J. G.; Peng, Z. G. J. Nanomater. 2014, 1-9.

[24]. Zhang, B.; Li, F.; Wu, T.; Sun, D. J.; Li, Y. J. Colloid. Surf. A. 2015, 464, 78-88.
https://doi.org/10.1016/j.colsurfa.2014.10.020

[25]. Gimeno, O.; Carbajo, M.; Beltran, F. J.; Rivas, F. J. J. Hazard. Mater. 2005, 119, 99-108.
https://doi.org/10.1016/j.jhazmat.2004.11.024

[26]. Ksibi, M.; Zemzemi, A.; Boukchina, R. J. Photochem. Photobiol. A. 2003, 159, 61-70.
https://doi.org/10.1016/S1010-6030(03)00114-X

[27]. Erdem, M.; Yuksel, E.; Tay, T.; Cimen, Y.; Turk, H. J. Colloid. Interf. Sci. 2009, 333, 40-48.
https://doi.org/10.1016/j.jcis.2009.01.014

[28]. Koubaissy, B.; Joly, G.; Batonneau-Gener, I.; Magnoux, P. Ind. Eng. Chem. Res. 2011, 50, 5705-5713.
https://doi.org/10.1021/ie100420q

[29]. Huang, J. H.; Yan, C.; Huang, K. L J. Colloid. Interf. Sci. 2009, 332, 60-64.
https://doi.org/10.1016/j.jcis.2008.12.039

[30]. Lin, K. Y. A.; Yang, H.; Petit, C.; Hsu, F. H. Chem. Eng. J. 2014, 249, 293-301.
https://doi.org/10.1016/j.cej.2014.03.107

[31]. Stock, N.; Biswas, S. Morphol. Compos. Chem. Rev. 2011, 112, 933-969.

[32]. Janiak, C.; Vieth, J. K. New J. Chem. 2010, 34, 2366-2388.
https://doi.org/10.1039/c0nj00275e

[33]. Mueller, U.; Schubert, M.; Teich, F.; Puetter, H.; Schierle-Arndt, K.; Pastre, J. J. Mater. Chem. 2006, 16, 626-636.
https://doi.org/10.1039/B511962F

[34]. Yoon, J. W.; Jhung, S. H.; Hwang, Y. K.; Humphrey, S. M.; Wood, P. T.; Chang, J. S. Adv. Mater. 2007, 19, 1830-1834.
https://doi.org/10.1002/adma.200601983

[35]. Li, J. R.; Ma, Y.; McCarthy, M. C.; Sculley, J.; Yu, J.; Jeong, H. K.; Balbuena, P. B.; Zhou, H. C. Coord. Chem. Rev. 2011, 255, 1791-1823.
https://doi.org/10.1016/j.ccr.2011.02.012

[36]. Li, J. R.; Kuppler, R. J.; Zhou, H. C. Chem. Soc. Rev. 2009, 38, 1477-1504.
https://doi.org/10.1039/b802426j

[37]. Lee, J.; Farha, O. K.; Roberts, J.; Scheidt, K. A.; Nguyen, S. T.; Hupp, J. T. Chem. Soc. Rev. 2009, 38, 1450-1459.
https://doi.org/10.1039/b807080f

[38]. Corma, A.; García, H.; Xamena, F. X. Chem. Rev. 2010, 110, 4606-4655.
https://doi.org/10.1021/cr9003924

[39]. Gascon, J.; Corma, A.; Kapteijn, F.; Xamena, F. X. ACS. Catal. 2013, 3, 361-378.

[40]. Horcajada, P.; Chalati, T.; Serre, C.; Gillet, B.; Sebrie, C.; Baati, T.; Eubank, J. F.; Heurtaux, D.; Clayette, P.; Kreuz, C.; Chang, J. S.; Hwang, Y. K.; Marsaud, V.; Bories, P. N.; Cynober, L.; Gil, S.; Ferey, G.; Couvreur, P.; Gref, R. Nat. Mater. 2010, 9, 172-178.
https://doi.org/10.1038/nmat2608

[41]. Qiu, L. G.; Li, Z. Q.; Wu, Y.; Wang, W.; Xu, T.; Jiang, X. Chem. Commun. 2008, 3642-3644.
https://doi.org/10.1039/b804126a

[42]. Ke, F.; Qiu, L. G.; Yuan, Y. P.; Peng, F. M.; Jiang, X.; Xie, A. J.; Shen, Y. H.; Zhu, J. F. J. Hazard. Mater. 2011, 196, 36-43.
https://doi.org/10.1016/j.jhazmat.2011.08.069

[43]. Li, L.; Li, J. C.; Rao, Z.; Song, G. W.; Hu, B. Desalination. Water. Treat. 2014, 52, 7332-7338.
https://doi.org/10.1080/19443994.2013.821955

[44]. Tranchemontagne, D. J.; Hunt, J. R.; Yaghi, O. M. Tetrahedron 2008, 64, 8553-8557.
https://doi.org/10.1016/j.tet.2008.06.036

[45]. Britt, D.; Tranchemontagne, D.; Yaghi, O. M. Proc. Natl. Acad. Sci. 2008, 105, 11623-11627.
https://doi.org/10.1073/pnas.0804900105

[46]. Nguyen, L. T.; Nguyen, T. T.; Nguyen, K. D.; Phan, N. T. Appl. Catal. A. 2012, 425, 44-52.
https://doi.org/10.1016/j.apcata.2012.02.045

[47]. Rowsell, J. L.; Yaghi, O. M. J. Am. Chem. Soc. 2006, 128, 1304-1315.
https://doi.org/10.1021/ja056639q

[48]. Li, L.; Yao, J.; Xiao, P.; Shang, J.; Feng, Y.; Webley, P. A.; Wang, H. Colloid. Polym. Sci. 2013, 291, 2711-2717.
https://doi.org/10.1007/s00396-013-3024-8

[49]. Moellmer, J.; Celer, E. B.; Luebke, R.; Cairns, A. J.; Staudt, R.; Eddaoudi, M.; Thommes, M. Micropor. Mesoporr Mat. 2010, 129, 345-353
https://doi.org/10.1016/j.micromeso.2009.06.014

[50]. Barcia, P. S.; Guimarães, D.; Mendes, P. A. P.; Silva, J. A. C.; Guillerm, V.; Chevreau, H.; Serre, C.; Rodrigues, A. Micropor. Mesopor. Mat. 2011, 139, 67-73.
https://doi.org/10.1016/j.micromeso.2010.10.019

[51]. Francesc, X.; Xamena, F. X.; Abad, A.; Corma, A.; Garcia, H. J. Catal. 2007, 250, 294-298.
https://doi.org/10.1016/j.jcat.2007.06.004

[52]. Hosny, M. N. J. Therm. Anal. Calorim. 2015, 122, 89-95.
https://doi.org/10.1007/s10973-015-4721-y

[53]. Cieplak, P.; Bayly, S. C. I.; Gould, I. R.; Merz, Jr. K. M.; Ferguson D. M.; Spellmeyer, D. C.; Fox, T.; Caldwell, J. W.; Kollman. P. A. Am. Chem. Soc. 1995, 117, 5179-5197.

[54]. Thommes, M.; Cychosz, K. A.; Neimark, A. V. Advanced physical adsorption characterization of nanoporous carbons. In: Tascón, J. M. D. (ed.) Novels Carbons Adsorbent. Elsevier, Great Britain, 2012.
https://doi.org/10.1016/B978-0-08-097744-7.00004-1

[55]. Rouquerol, J.; Llewellyn, P.; Rouquerol, F. Is BET equation applicable to microporous adsorbents? In: P. Lewelling, F. Rodriguez-Reinoso, J. Rouquerol, N. Seaton, editors. Characterization of porous solids VII. Amsterdam: Elsevier, Stud. Surf. Sci. Catal., 2007.
https://doi.org/10.1016/S0167-2991(07)80008-5

[56]. Park, K. H.; Balathanigaimani, M. S.; Shim, W. G.; Lee, J. W.; Moon, H. Microporous. Mesoporous. Mater. 2010, 127, 1-8.
https://doi.org/10.1016/j.micromeso.2009.06.032

[57]. Chen, R; Yao, J.; Gu, Q.; Smeets, S.; Baerlocher, C.; Gu, H.; Zhu, D.; Morris, W.; Yaghi, O. M.; Wang, H. Chem. Commun. 2013, 49, 9500-9502.
https://doi.org/10.1039/c3cc44342f

[58]. Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T.; Wright, P. A.; Parsons, S.; Duren, T. J. Am. Chem. Soc. 2011, 133, 8900-8902.
https://doi.org/10.1021/ja202154j

[59]. Danaci, D.; Singh, R.; Xiao, P.; Webley, P. A. Chem. Eng. J. 2015, 280, 486-493.
https://doi.org/10.1016/j.cej.2015.04.090

[60]. Garrido, J.; Linares-Solano, A.; Martín Martínez, J. M.; Molina-Sabio, M.; Rodríguez-Reinoso, F.; Torregrosa, R. Langmuir 1987, 3, 76-81.

[61]. Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60, 309-319.
https://doi.org/10.1021/ja01269a023

[62]. Landers, J.; Gor, G. Y.; Neimark, A. V. Colloids Surf., A: Physicochem. Eng. Aspects 2013, 437, 3-32.
https://doi.org/10.1016/j.colsurfa.2013.01.007

[63]. Dubinin, M. M.; Astakhov, V. A. Biol. Bull. Acad. Sci. USSR. 1971, 20, 3-7.
https://doi.org/10.1007/BF00849307

[64]. Li, G.; Lan, J.; Liu, J.; Jiang, G. J. Colloid Interface Sci. 2013, 405, 164-170.
https://doi.org/10.1016/j.jcis.2013.05.055

[65]. Bordiga, S.; Regli, L.; Bonino, F.; Groppo, E.; Lamberti, C.; Xiao, B.; Wheatley, P. S.; Morris, R. E.; Zecchina, A. Phys. Chem. Chem. Phys. 2007, 9, 2676-2685.
https://doi.org/10.1039/b703643d

[66]. Lin, K. S.; Adhikari, A. K.; Ku, C. N.; Chiang, C. L.; Kuo, H. Int. J. Hydrogen Energy 2012, 37, 13865-13871.
https://doi.org/10.1016/j.ijhydene.2012.04.105

[68]. Yue, Y.; Binder, A. J.; Song, R.; Cui, Y.; Chen, J.; Hensley, D. K.; Dai, S. Dalton Trans 2014, 43, 17893-17898.
https://doi.org/10.1039/C4DT02516D

[69]. Fracaroli, A. M.; Furukawa, H.; Suzuki, M.; Dodd, M.; Okajima, S.; Gándara, F.; Reimer, J. A.; Yaghi, O. M. J. Am. Chem. Soc. 2014, 136, 8863-8866.
https://doi.org/10.1021/ja503296c

[70]. Pan, Y. C.; Liu, Y. Y.; Zeng, G. F.; Zhao, L.; Lai, Z. P. Chem. Commun. 2011, 47, 2071-2073.
https://doi.org/10.1039/c0cc05002d

[71]. Jian, M.; Liu, B.; Zhang, G.; Liu, R.; Zhang, X. Colloids Surf., A: Physicochemical Eng. Aspects 2015, 465, 67-76.
https://doi.org/10.1016/j.colsurfa.2014.10.023

[72]. Diaz-Flores, P. E.; Lopez-Urı, F.; Terrones, M.; Rangel-Mendez, J. R. J. Colloid Interface Sci. 2009, 334, 124-131.
https://doi.org/10.1016/j.jcis.2009.02.045

[73]. Abdel-Ghani, N. T.; El-Chaghaby, G. A.; Helal, F. S. J. Adv. Res. 2015, 6, 405-415.
https://doi.org/10.1016/j.jare.2014.06.001

[74]. Ahmed, M. J.; Theydan, S. K. Ecotoxicol. Environ. Saf. 2012, 84, 39-45.
https://doi.org/10.1016/j.ecoenv.2012.06.019

[75]. Ahmed, M. J.; Theydan, S. K.; Mohammed, A. H. A. J. Engineering 2012, 18, 1-13.

[76]. Al-Mutairi, N. Z. Desalination 2010, 250, 892-901.
https://doi.org/10.1016/j.desal.2008.10.035

[77]. Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221-2295.
https://doi.org/10.1021/ja02268a002

[78]. Freundlich, H. M. F. Z. Phys. Chem. 1906, 57, 385-470.

[79]. Uddin, M. T.; Islam, M. S.; Abedin, M. Z. J. Eng. Appl. Sci. 2007, 2, 121-128.

[80]. Radke, C. J.; Prausnitz, J. M. Ind. Eng. Chem. Fund. 1972, 11, 445-451.
https://doi.org/10.1021/i160044a003

[81]. Hamdaoui, O.; Naffrechoux, E. J. Hazard. Mater. 2007, 147, 401-411.
https://doi.org/10.1016/j.jhazmat.2007.01.023

[82]. Humpola, P., Odetti, H.; Moreno-Piraján, J. C.; Giraldo, L. Adsorption 2016, 22, 23-31.
https://doi.org/10.1007/s10450-015-9728-y

[83]. Duong, D. Do. In Adsorption Analysis: Equilibria and Kinetics. Practical Approaches of Pure Component Adsorption Equilibria. Imperial College Press, 1998.

[84]. Lagergren, S. K. Sven. Vetenskapsakad. Handl. 1898, 24, 1-39.

[85]. Zeldowitsch, J. Acta Physicochim. U. R. S. S. 1934, 1 364-449.

[86]. Allen, J. A.; Scaife, P. H. Aust. J. Chem. 1966, 19, 2015-2023.
https://doi.org/10.1071/CH9662015c

[87]. Fierro, V.; Torné-Fernández, V.; Montané, D.; Celzard, A. Microporous. Mesoporous. Mater. 2008, 111, 276-284.
https://doi.org/10.1016/j.micromeso.2007.08.002

[88]. Weber, W. J.; Morris, J. C. ASCE J. Sanit. Eng. Div. 1963, 89, 31-42.

[89]. McKay, G.; Poots, V. J. P. J. Chem. Technol. Biotechnol. 1980, 30, 279-292.
https://doi.org/10.1002/jctb.503300134

[90]. Crank, J. Oxford Clarendon 1965, 84, 84-88.

[91]. Asfour, H. M.; Nassar, M. M.; Fadali, O. A.; El‐Geundi, M. S. J. Chem. Technol. Biotechnol. 1985, 35, 28-35.
https://doi.org/10.1002/jctb.5040350106


How to cite


Giraldo, L.; Bastidas-Barranco, M.; Húmpola, P.; Moreno-Piraján, J. Eur. J. Chem. 2017, 8(3), 293-304. doi:10.5155/eurjchem.8.3.293-304.1603
Giraldo, L.; Bastidas-Barranco, M.; Húmpola, P.; Moreno-Piraján, J. Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution. Eur. J. Chem. 2017, 8(3), 293-304. doi:10.5155/eurjchem.8.3.293-304.1603
Giraldo, L., Bastidas-Barranco, M., Húmpola, P., & Moreno-Piraján, J. (2017). Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution. European Journal of Chemistry, 8(3), 293-304. doi:10.5155/eurjchem.8.3.293-304.1603
Giraldo, Liliana, Marlon Bastidas-Barranco, Pablo Húmpola, & Juan Carlos Moreno-Piraján. "Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution." European Journal of Chemistry [Online], 8.3 (2017): 293-304. Web. 19 Nov. 2019
Giraldo, Liliana, Bastidas-Barranco, Marlon, Húmpola, Pablo, AND Moreno-Piraján, Juan. "Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution" European Journal of Chemistry [Online], Volume 8 Number 3 (30 September 2017)

DOI Link: https://doi.org/10.5155/eurjchem.8.3.293-304.1603

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2019  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.