European Journal of Chemistry

Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies

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Published: Mar 31, 2019
DOI: https://doi.org/10.5155/eurjchem.10.1.64-71.1820
Keywords:
SEM, TEM, Kinetics, Adsorption, Modification, Photocatalytic
Section
Research Article
Issue
Vol. 10 No. 1 (2019): March 2019
Dates
Received 2018-11-24
Accepted 2018-12-26
Published 2019-03-31
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Ibtighaa Kadhim Radhi
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0002-1424-8811
Mouayed Abdulaali Hussein
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0001-7465-1939
Zaki Naser Kadhim
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0002-7475-269X

Abstract

Successful removal of nigrosine, alizarin, indigo and acid fuchsin dyes from aqueous solutions using modified CaO nanoparticles has been investigated. The CaO was obtained from eggshells and modified with AgI. The adsorbents were characterized using X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy and transmission electron microscopy. The kinetic studies were also investigated, the results showed that the adsorption of alizarin dye follows the pseudo-first-order model, while the adsorption of the nigrosine, indigo, and acid fuchsin follow the pseudo-second-order model onto modified and unmodified CaO. Moreover, the photocatalytic activity of modified adsorbent was tested under sunlight. The modified adsorbent showed a strong photocatalytic activity, a 0.01 g modified adsorbent was sufficient to absorb 100% of acid fuchsin through only 5 min after exposes to sunlight.


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Radhi, I. K.; Hussein, M. A.; Kadhim, Z. N. Investigation of Nigrosine, Alizarin, Indigo and Acid Fuchsin Removal by Modification of CaO Derived from Eggshell With AgI: Adsorption, Kinetic and Photocatalytic Studies. Eur. J. Chem. 2019, 10, 64-71.

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