European Journal of Chemistry

Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies

Article Sidebar

PDF SUPPLEMENTARY FILE
Published: Mar 31, 2019
DOI: https://doi.org/10.5155/eurjchem.10.1.64-71.1820
Keywords:
SEM, TEM, Kinetics, Adsorption, Modification, Photocatalytic
Section
Research Article
Issue
Vol. 10 No. 1 (2019): March 2019
Dates
Received 2018-11-24
Accepted 2018-12-26
Published 2019-03-31
Crossmark


Main Article Content

Ibtighaa Kadhim Radhi
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0002-1424-8811
Mouayed Abdulaali Hussein
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0001-7465-1939
Zaki Naser Kadhim
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
http://orcid.org/0000-0002-7475-269X

Abstract

Successful removal of nigrosine, alizarin, indigo and acid fuchsin dyes from aqueous solutions using modified CaO nanoparticles has been investigated. The CaO was obtained from eggshells and modified with AgI. The adsorbents were characterized using X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy and transmission electron microscopy. The kinetic studies were also investigated, the results showed that the adsorption of alizarin dye follows the pseudo-first-order model, while the adsorption of the nigrosine, indigo, and acid fuchsin follow the pseudo-second-order model onto modified and unmodified CaO. Moreover, the photocatalytic activity of modified adsorbent was tested under sunlight. The modified adsorbent showed a strong photocatalytic activity, a 0.01 g modified adsorbent was sufficient to absorb 100% of acid fuchsin through only 5 min after exposes to sunlight.


icon graph This Abstract was viewed 1468 times | icon graph Article PDF downloaded 726 times icon graph Article SUPPLEMENTARY FILE downloaded 0 times

How to Cite
(1)
Radhi, I. K.; Hussein, M. A.; Kadhim, Z. N. Investigation of Nigrosine, Alizarin, Indigo and Acid Fuchsin Removal by Modification of CaO Derived from Eggshell With AgI: Adsorption, Kinetic and Photocatalytic Studies. Eur. J. Chem. 2019, 10, 64-71.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Angyu, C.; Yasuhiro, O.; Fumihide, S. Chem. Eng. J. 2010, 156, 98-105.
https://doi.org/10.1016/j.cej.2009.10.003

[2]. Hu, J.; Song, Z.; Chen, L.; Yang, H.; Li, J.; Richards, R. J. Chem. Eng. Data 2010, 55, 3742-3748.
https://doi.org/10.1021/je100274e

[3]. Hejazifar, M.; Azizian, S.; Sarikhan, H.; Li, Q.; Zhao, D. J. Anal. Appl Pyrolysis 2011, 92, 258-266.
https://doi.org/10.1016/j.jaap.2011.06.007

[4]. Belessi, V.; Romanos, G.; Boukos, N.; Lambropoulou, D.; Trapalis, C. J. Hazard. Mater. 2009, 170, 836-844.
https://doi.org/10.1016/j.jhazmat.2009.05.045

[5]. Tan, X.; Liu, Y.; Zeng, G.; Wang, X.; Hu, X.; Gu, Y.; Yang, Z. Chemosphere 2015, 125, 70-85.
https://doi.org/10.1016/j.chemosphere.2014.12.058

[6]. Ahmad, M.; Lee, S. S.; Dou, X.; Mohan, D.; Sung, J. K.; Yang, J. E.; Ok, Y. S. Bioresour. Technol. 2012, 118, 536-544.
https://doi.org/10.1016/j.biortech.2012.05.042

[7]. Robinson, T.; McMullan, G.; Marchant, R.; Nigam, P. Bioresour. Technol. 2001, 77, 247-255.
https://doi.org/10.1016/S0960-8524(00)00080-8

[8]. Muruganandham, M.; Amutha, R.; Lee, G. J.; Hsieh, S. H.; Wu, J. J.; Sillanpaa, M. J. Phys. Chem. C 2012, 116, 12906-12015.
https://doi.org/10.1021/jp302343f

[9]. Pimpaporn, S.; Sumpun, W. J. Sol-Gel Sci. Technol. 2014, 71, 86-95.
https://doi.org/10.1007/s10971-014-3327-3

[10]. Bhatnagar, A.; Sillanpaa, M. Chem. Eng. J. 2010, 157, 277-296.
https://doi.org/10.1016/j.cej.2010.01.007

[11]. Isık, M.; Sponza, D. T. Chemosphere 2004, 55, 119-128.
https://doi.org/10.1016/j.chemosphere.2003.10.008

[12]. Beak, M. H.; Ijagbemi, C. O.; Kim, D. O. J. Environ. Sci. Heal. A 2009, 44, 623-629.
https://doi.org/10.1080/10934520902784708

[13]. Lau, Y. Y.; Wong, Y. S.; Teng, T. T.; Morad, N.; Rafatullah, M.; Ong, S. A. Chem. Eng. J. 2014, 246, 383-390.
https://doi.org/10.1016/j.cej.2014.02.100

[14]. Venkata Mohan, S.; Karthikeyan, J. Clean Technol. Envir. J. 2004, 6, 196-212.

[15]. Nguyen-Phan, T. D.; Song, M. B.; Yun, H.; Kim, E. J.; Oh, E. S.; Shin, E. W. Appl. Surf. Sci. 2011, 27, 2024-2031.
https://doi.org/10.1016/j.apsusc.2010.09.046

[16]. Han, R.; Wang, Y.; Han, P.; Shi, J.; Yang, J.; Lu, Y. J. Hazard. Mater. 2006, 137, 550-554.
https://doi.org/10.1016/j.jhazmat.2006.02.029

[17]. Vadivelan, V.; Vasanth Kumar, K. J. Colloid Interface Sci. 2005, 286, 90-100.
https://doi.org/10.1016/j.jcis.2005.01.007

[18]. Otero, M.; Rozada, F.; Calvo, L. F.; Garcia, A. I.; Moran, A. Biochem. Eng. J. 2003, 15, 59-68.
https://doi.org/10.1016/S1369-703X(02)00177-8

[19]. Jafari, S.; Tryba, B.; Nejman, E.; Kozar, J.; Morawski, A. W.; Sillanpaa, M. J. Mol. Liq. 2016, 220, 504-512.
https://doi.org/10.1016/j.molliq.2016.02.014

[20]. Janus, M.; Kusiak, E.; Choina, J.; Ziebro, J.; Morawski, A. W. Desalination 2009, 249, 359-363.
https://doi.org/10.1016/j.desal.2009.04.013

[21]. Aksu, Z. Process Biochem. 2005, 40, 997-1026.
https://doi.org/10.1016/j.procbio.2004.04.008

[22]. Jafari, S.; Feiping Z.; Dongbo Z.; Manu L.; Amit B.; Mika S. J. Mol. Liq. 2015, 207, 90-98.
https://doi.org/10.1016/j.molliq.2015.03.026

[23]. Cheng, X.; Yu, X.; Xing, Z. Appl. Surf. Sci. 2012, 258, 3244-3248.
https://doi.org/10.1016/j.apsusc.2011.11.072

[24]. Koumanova, B.; Peeva, P.; Allen, S. J.; Gallagher, K. A.; Healy, M. G. J. Chem. Technol. Biotechnol. 2002, 77, 539-545.
https://doi.org/10.1002/jctb.601

[25]. Tsai, W. T.; Yang, J. M.; Lai, C. W.; Cheng, Y. H.; Lin, C. C.; Yeh, C. W. Bioresour. Technol. 2006, 97, 488-493.
https://doi.org/10.1016/j.biortech.2005.02.050

[26]. Saxen, B. Memoranda Soc. Fauna Flora Fennica 2011, 87, 29-40.

[27]. Aksu, Z. Sep. Purif. Technol. 2001, 21, 285-294.

[28]. Bulut, Y.; Baysal, Z. J. Environ. Manage. 2006, 78, 107-113.
https://doi.org/10.1016/j.jenvman.2005.03.010

[29]. Rauf, M. A.; Bukallah, S. B.; Hamour, F. A.; Nasir, A. S. Chem. Eng. J. 2008, 137, 238-243.
https://doi.org/10.1016/j.cej.2007.04.025

[30]. Banerjee, S.; Sharma, G. C.; Chattopadhyaya, M. C.; Sharma, Y. C. J. Environ. Chem. Eng. 2014, 2, 1870-1880.
https://doi.org/10.1016/j.jece.2014.06.020

Supporting Agencies

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).