European Journal of Chemistry 2019, 10(4), 381-385 | doi: https://doi.org/10.5155/eurjchem.10.4.381-385.1922 | Get rights and content






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Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one


Stability Nongrum (1) orcid , Susma Das (2) orcid , Shikpika Khanikar (3) orcid , Jai Narain Vishwakarma (4,*) orcid

(1) Organic Research Laboratory, Department of Chemical Science, Assam Don Bosco University, Tapesia Gardens, Kamarkuchi, Sonapur, 782 402 Assam, India
(2) Organic Research Laboratory, Department of Chemical Science, Assam Don Bosco University, Tapesia Gardens, Kamarkuchi, Sonapur, 782 402 Assam, India
(3) Organic Research Laboratory, Department of Chemical Science, Assam Don Bosco University, Tapesia Gardens, Kamarkuchi, Sonapur, 782 402 Assam, India
(4) Organic Research Laboratory, Department of Chemical Science, Assam Don Bosco University, Tapesia Gardens, Kamarkuchi, Sonapur, 782 402 Assam, India
(*) Corresponding Author

Received: 03 Sep 2019 | Revised: 24 Sep 2019 | Accepted: 06 Oct 2019 | Published: 31 Dec 2019 | Issue Date: December 2019

Abstract


A new enaminone was synthesized by reacting 3,5-bis-(trifluoromethyl)acetophenones and N,N-dimethylformamide dimethyl acetal and its detailed structural and crystalline properties were studied. The crystal data were found to be as C13H11F6NO, monoclinic, space group P21/c (no. 14), a = 8.1556(8) Å, b = 24.877(3) Å, c = 7.6067(7) Å, β = 116.745(6)°, = 1378.2(3) Å3, Z = 4, T = 293(2) K, μ(MoKα) = 0.150 mm-1, Dcalc = 1.500 g/cm3, 40777 reflections measured (5.594° ≤ 2Θ ≤ 56.786°), 3413 unique (Rint = 0.1040, Rsigma = 0.0584) which were used in all calculations. The final R1 was 0.0771 (I > 2σ(I)) and wR2 was 0.2541 (all data).


Keywords


Enaminones; Acetophenone; Trifluoromethyl; X-ray crystallography; Geometric parameters; N,N-Dimethylformamide dimethyl acetal

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DOI: 10.5155/eurjchem.10.4.381-385.1922

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Funding information


Department of Biotechnology, Government of India, India.

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Nongrum, S.; Das, S.; Khanikar, S.; Vishwakarma, J. Eur. J. Chem. 2019, 10(4), 381-385. doi:10.5155/eurjchem.10.4.381-385.1922
Nongrum, S.; Das, S.; Khanikar, S.; Vishwakarma, J. Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one. Eur. J. Chem. 2019, 10(4), 381-385. doi:10.5155/eurjchem.10.4.381-385.1922
Nongrum, S., Das, S., Khanikar, S., & Vishwakarma, J. (2019). Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one. European Journal of Chemistry, 10(4), 381-385. doi:10.5155/eurjchem.10.4.381-385.1922
Nongrum, Stability, Susma Das, Shikpika Khanikar, & Jai Narain Vishwakarma. "Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one." European Journal of Chemistry [Online], 10.4 (2019): 381-385. Web. 8 Apr. 2020
Nongrum, Stability, Das, Susma, Khanikar, Shikpika, AND Vishwakarma, Jai. "Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one" European Journal of Chemistry [Online], Volume 10 Number 4 (31 December 2019)

DOI Link: https://doi.org/10.5155/eurjchem.10.4.381-385.1922

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