European Journal of Chemistry 2011, 2(3), 314-316 | doi: https://doi.org/10.5155/eurjchem.2.3.314-316.307 | Get rights and content






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Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate


Zaouali Zgolli Donia (1,*) , Hbib Boughzala (2) , Ahmed Driss (3)

(1) Laboratoire des Matériaux et Cristallochimie, Département de chimie, Faculté des Sciences, El Manar, Tunis, TN-2092, Tunisie
(2) Laboratoire des Matériaux et Cristallochimie, Département de chimie, Faculté des Sciences, El Manar, Tunis, TN-2092, Tunisie
(3) Laboratoire des Matériaux et Cristallochimie, Département de chimie, Faculté des Sciences, El Manar, Tunis, TN-2092, Tunisie
(*) Corresponding Author

Received: 07 Nov 2010 | Accepted: 19 Dec 2010 | Published: 30 Sep 2011 | Issue Date: September 2011

Abstract


N,N,N',N'-tetramethylethylenediammonium dinitrate has been synthesized. The crystal and molecular structure of the title compound has been determined from single crystal X-ray diffraction data. C6H18N4O6, M =242.24, Triclinic, a = 6.040(2) Å, b = 6.834(3) Å, c = 7.867(2) Å, α = 74.1120(10)°, β = 83.700(2)°, γ = 80.314(2)°, V = 307.12(19) Å3, T = 298(2) K, space group P-1 (no. 2), Z = 1, μ(Mo-Kα) = 0.115, 2383 reflections measured, 1342 unique (Rint = 0.0169) which were used in all calculations. The final wR(F2) was 0.1262 (all data). In the title compound, C6H18N22+.2NO3-, both N atoms of the cationic moiety are protonated and linked via hydrogen bonds to two trigonal planar nitrate anions. Two types of classical hydrogen bonds are observed: N1-H…O1 and N1-H…O2. These bonds link the cations and the anions together, forming a one-dimensional network and reinforcing the cohesion of the ionic structure.

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Keywords


N,N,N',N'-tetramethylethylenediammonium dinitrate; Single crystal structure; Organic-inorganic; Synthesis; Characterization; Hydrogen‐bond

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DOI: 10.5155/eurjchem.2.3.314-316.307

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Funding information


Laboratory of Coordination Chemistry, UPR-CNRS 8241, Toulouse, France

References

[1]. Gessner, V. H.; Daschlein, C.; Strohmann, C. Acta Cryst. 2009, E65, o383-o383.

[2]. Gessner, V. H.; Strohmann, C. J. Am. Chem. Soc. 2008, 130, 14412-14413.
http://dx.doi.org/10.1021/ja8058205
PMid:18842047

[3]. Kohler, F. H; Hertkorn, N. J. Blumel. Chem. Ber. 1987, 120, 2081-2082.

[4]. Misra, T. K.; Cheng, J.; Liao, F. L.; Lu, T. H.; Chung, C. S. J. Coord. Chem. 2007, 60, 1855-1866.
http://dx.doi.org/10.1080/00958970701203107

[5]. Nastase, S.; Tuna, F.; Maxim, C.; Muryn, C. A.; Avarvari, N.; Winpenny, R. E. P.; Andruh, M. Cryst. Growth Des. 2007, 7, 1825-1831.
http://dx.doi.org/10.1021/cg070332g

[6]. Sheldrick, G. M. SHELXS-97 a Program for Crystal Structure Determination, University of Gottingen, Germany. 1997.

[7]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 2, 837-838.
http://dx.doi.org/10.1107/S0021889899006020

[8]. DIAMOND - Visual Crystal Structure Information System CRYSTAL IMPACT, Postfach 1251, D-53002, Bonn.

[9]. Lin, J.; Xu, Y.; Shi, T.; Liu, D.; Chen, W. Acta Cryst. 2008, E64, o129-o129.

[10]. Kabak, M.; Elerman, Y.; Ãnaleroglu, C.; Mert, Y.; Durlu, T. N. Acta Cryst. 2000, C56, e66-e67.

[11]. Annan, T. A.; Chadha, R. K; Tuck, D. G. Acta Cryst. 1991, C47, 151-153.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Donia, Z.; Boughzala, H.; Driss, A. Eur. J. Chem. 2011, 2(3), 314-316. doi:10.5155/eurjchem.2.3.314-316.307
Donia, Z.; Boughzala, H.; Driss, A. Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate. Eur. J. Chem. 2011, 2(3), 314-316. doi:10.5155/eurjchem.2.3.314-316.307
Donia, Z., Boughzala, H., & Driss, A. (2011). Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate. European Journal of Chemistry, 2(3), 314-316. doi:10.5155/eurjchem.2.3.314-316.307
Donia, Zaouali, Hbib Boughzala, & Ahmed Driss. "Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate." European Journal of Chemistry [Online], 2.3 (2011): 314-316. Web. 23 Sep. 2020
Donia, Zaouali, Boughzala, Hbib, AND Driss, Ahmed. "Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate" European Journal of Chemistry [Online], Volume 2 Number 3 (30 September 2011)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.2.3.314-316.307

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