European Journal of Chemistry 2012, 3(1), 37-39 | doi: https://doi.org/10.5155/eurjchem.3.1.37-39.591 | Get rights and content






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Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex


Gun Binzet (1,*) , Ulrich Flörke (2) , Nevzat Külcü (3) , Hakan Arslan (4)

(1) Science Education, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author

Received: 31 Jan 2012 | Accepted: 06 Feb 2012 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract


We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3.  In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

3_1_37_39_800


Keywords


Thiourea; Benzamide; Nickel complex; Benzoylthiourea; Crystal structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.3.1.37-39.591

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Funding information


Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).

Citations

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[2]. B. Schmitt, T.I.A. Gerber, E. Hosten, R. Betz
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[3]. Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
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[4]. Rodrigo S. Correa, Katia M. Oliveira, Hiram Pérez, Ana M. Plutín, Raúl Ramos, Raúl Mocelo, Eduardo E. Castellano, Alzir A. Batista
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[5]. Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
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[6]. K.H. Kumar Naik, B. Ashok, Nagaraja Naik, Jameel Ahmed S. Mulla, Avinash Prakasha
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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. Eur. J. Chem. 2012, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, G., Flörke, U., Külcü, N., & Arslan, H. (2012). Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex. European Journal of Chemistry, 3(1), 37-39. doi:10.5155/eurjchem.3.1.37-39.591
Binzet, Gun, Ulrich Flörke, Nevzat Külcü, & Hakan Arslan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex." European Journal of Chemistry [Online], 3.1 (2012): 37-39. Web. 23 Sep. 2020
Binzet, Gun, Flörke, Ulrich, Külcü, Nevzat, AND Arslan, Hakan. "Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

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DOI Link: https://doi.org/10.5155/eurjchem.3.1.37-39.591

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