European Journal of Chemistry 2012, 3(2), 211-213 | doi: https://doi.org/10.5155/eurjchem.3.2.211-213.594 | Get rights and content






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Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex


Gun Binzet (1,*) , Ulrich Flörke (2) , Nevzat Külcü (3) , Hakan Arslan (4)

(1) Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33169, Turkey
(2) Department of Chemistry, University of Paderborn, Paderborn, D-33098, Germany
(3) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author

Received: 06 Feb 2012 | Accepted: 13 Feb 2012 | Published: 30 Jun 2012 | Issue Date: June 2012

Abstract


The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o , Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.


Keywords


Thiourea; Benzamide; Copper complex; Benzoylthiourea; Crystal structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.3.2.211-213.594

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Funding information


Mersin University Research Fund, Mersin, Turkey (Project No: BAP-FBE-KB(GB)-2006-1).

Citations

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex. Eur. J. Chem. 2012, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, G., Flörke, U., Külcü, N., & Arslan, H. (2012). Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex. European Journal of Chemistry, 3(2), 211-213. doi:10.5155/eurjchem.3.2.211-213.594
Binzet, Gun, Ulrich Flörke, Nevzat Külcü, & Hakan Arslan. "Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex." European Journal of Chemistry [Online], 3.2 (2012): 211-213. Web. 17 Feb. 2020
Binzet, Gun, Flörke, Ulrich, Külcü, Nevzat, AND Arslan, Hakan. "Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex" European Journal of Chemistry [Online], Volume 3 Number 2 (30 June 2012)

DOI Link: https://doi.org/10.5155/eurjchem.3.2.211-213.594

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