European Journal of Chemistry 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738

Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Stanislav Pechev (3) , Tahar Mhiri (4) , Zakaria Elaoud (5)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(5) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(*) Corresponding Author

Received: 17 Jan 2013, Accepted: 23 Jan 2013, Published: 30 Jun 2013

Abstract


Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

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Keywords


Single crystal; Copper(II) complex; Spectroscopic study; Tetrapropylammonium; Hexachlorodicuprate(II); Crystal structure analysis

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DOI: 10.5155/eurjchem.4.2.117-120.738

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Citations

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[1]. A. Oueslati, M. Gargouri
Studies on structural, electrical, and transport properties of [(C3H7)4N]2Cu2Br6 compound
Journal of Alloys and Compounds  739, 1089, 2018
DOI: 10.1016/j.jallcom.2017.12.277
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[2]. Ikram Dhouib, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
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[3]. F. Lambarki, A. Ouasri, A. Rhandour, M. Saadi, L. El Ammari, L. Hajji
Structural, vibrational and electrical studies of tetramethylammonium trichloromercurate [(CH3)4N]HgCl3
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[4]. Ikram Dhouib, Habib Feki, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
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References

[1]. Braga, D.; Desiraju, G. R.; Miller, J. S.; Orpen, A. G.; Price, S. L. Cryst. Eng. Commun. 2002, 4, 500-509.
http://dx.doi.org/10.1039/b207466b

[2]. Desiraju, G. R. Angew. Chem. Int. Ed. Engl. 1995, 34, 2311-2327.
http://dx.doi.org/10.1002/anie.199523111

[3]. Desiraju, G. R. J. Mol. Struct. 2003, 656, 5-15.
http://dx.doi.org/10.1016/S0022-2860(03)00354-5

[4]. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1-12.
http://dx.doi.org/10.1002/9780470166499.ch1

[5]. Lacroix, P. G.; Clement, R.; Nakatani, K.; Delaire, J. A.; Zyss, J.; Ledoux, I. Science 1994, 263, 658-660.
http://dx.doi.org/10.1126/science.263.5147.658
PMid:17747659

[6]. De Zea Bermudez, V.; Carlos, L. D.; Duarte, M. C.; Silva, M. M.; Silva, C. J.; Smith, M. J.; Assunc¸ M.; Alcacer, L. J. Alloys Compd. 1998, 21, 275-277.

[7]. Carlos, L. D.; Sa Ferreira, R. A.; De Zea Bermudez, V.; Ribeiro, S. J. L. Adv. Funct. Mater. 2001, 11, 2111-115.
http://dx.doi.org/10.1002/1616-3028(200104)11:2<111::AID-ADFM111>3.0.CO;2-V

[8]. Kato, Y.; Ichii, D.; Ohashi, K.; Kunugita, H.; Ema, K.; Tanaka, K.; Takahashi, T.; Kondo, T. Solid State Commun. 2003, 128, 15-18.
http://dx.doi.org/10.1016/S0038-1098(03)00626-4

[9]. El-Korashy, A.; Brik, M. G. Solid State Commun. 2005, 135, 298-303.
http://dx.doi.org/10.1016/j.ssc.2005.05.010

[10]. Ben Rhaiem, A.; Hlel, F.; Guidara, K.; Gargouri, M. J. Alloys Compd. 2008, 463, 440-445.
http://dx.doi.org/10.1016/j.jallcom.2007.09.032

[11]. Cavellec, M. R.; Albinet, C.; Greneche, J. M.; Ferey, G. J. Mater. Chem. 2001, 11, 3166-3171.
http://dx.doi.org/10.1039/b104495h

[12]. Lach, G.; Laskowski, L.; Kityk, I. V.; Kapustianyk, V.; Rudyk, V.; Shchur, Y.; Tkaczyk, S.; Swiatek, J.; Piasecki, M. J. Non-Crystalline Solid. 2007, 353, 4353-4356.
http://dx.doi.org/10.1016/j.jnoncrysol.2007.01.081

[13]. Roman, P.; Sertucha, J.; Luque, A.; Lezama, L.; Rojo, T. Polyhedron 1996, 15, 1253-1262.
http://dx.doi.org/10.1016/0277-5387(95)00386-X

[14]. Angeloni, A.; Orpen, A. G. Chem. Commun. 2001, 26, 343-344
http://dx.doi.org/10.1039/b009515j

[15]. Guckian, K. M .; Schweitzer, B. A.; Ren, R. X. F.; Sheils, C. J.; Tahmassebi, D. C.; Kool, E. T. J. Am. Chem. Soc. 2000, 122, 2213-2222.
http://dx.doi.org/10.1021/ja9934854
PMid:20865137 PMCid:2943206

[16]. Janiak, C. J. Chem. Soc. Dalton Trans. 2000, 7, 3885-3896
http://dx.doi.org/10.1039/b003010o

[17]. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143-167.
http://dx.doi.org/10.1021/cr9900331
PMid:11749236

[18]. Hiroyuki, H.; Mashiyama, H.; Koshiji, N. Acta Cryst. B. 1989, 45, 467-473.
http://dx.doi.org/10.1107/S0108768189006981

[19]. Muller, E. A.; Cannon, R. J.; Sarjeant, A. N.; Ok, K. M.; Halasyamani, P. S.; Norquist, A. J. Cryst. Growth Des. 2005, 5, 1913-1917.
http://dx.doi.org/10.1021/cg050184z

[20]. Nonius, Kappa CCD Program Software, Nonius BV, Delft, The Netherlands, 1998.

[21]. Farrugia, L. J. J. Appl. Cystallogr. 1999, 32, 837-838.
http://dx.doi.org/10.1107/S0021889899006020

[22]. Sheldrick, G. M. SHELXS-97 Programs for Crystal Solution. University of Gottingen, Germany, 1997.
PMCid:20809

[23]. Sheldrick, G. M. SHELXL-97 Programs for Crystal Structure Refinement. University of Gottingen, Germany, 1997.
PMCid:20809

[24]. Herringer, S. N.; Turnbull, M. M.; Landee, C. P.; Wikaira, J. L. J. Coord. Chem. 2009, 62, 863-875.
http://dx.doi.org/10.1080/00958970802395604

[25]. Luque, A.; Sertucha, J.; Castillo, O.; Roman, P. New. J. Chem. 2001, 25, 1208-1214.
http://dx.doi.org/10.1039/b104085p

[26]. Luque, A.; Sertucha, J.; Lezama, L.; Rojo, T.; Roman, P. J. Chem. Soc. Dalton Trans. 1997, 5, 847-854.
http://dx.doi.org/10.1039/a606429i

[27]. Al-Far, A. R. H.; Haddad, S. F. Acta Cryst. E 2008, 64, 689-690.
http://dx.doi.org/10.1107/S1600536808010647
PMid:21202225 PMCid:2961314

[28]. Haddad, S. F.; AlDamen, M. A.; Willett, R. D. Inorg. Chim. Acta. 2006, 359, 424-432.
http://dx.doi.org/10.1016/j.ica.2005.05.039

[29]. Hafiz, A. A. Iran J. Chem. Soc. 2008, 5, 106-114.

[30]. Gosniowska, M.; Ciunik, Z.; Bator, G.; Jakubas, R.; Baran, J. J. Mol. Struct. 2000, 555, 243-255.
http://dx.doi.org/10.1016/S0022-2860(00)00607-4

[31]. Karbowiak, M.; Hanuza, J.; Janczak, J.; Drozdzynski, J. J. Alloys Compd. 1995, 225, 338-343.
http://dx.doi.org/10.1016/0925-8388(94)07117-9

[32]. Hedderich, H. G.; Blom, C. E. J. Chem. Phys. 1989, 90, 4660-4663.

[33]. Hedderich, H. G.; Blom, C. E. J. Mol. Spectrosc. 1990, 140, 103-106.
http://dx.doi.org/10.1016/0022-2852(90)90009-F

[34]. Kirkwood, A. D.; Bier, K. D.; Thompson, J. K.; Haslett, T. L.; Hubber, A. S.; Moskovits, M. J. Phys. Chem. 1991, 95, 2644-2652.
http://dx.doi.org/10.1021/j100160a006

[35]. Bellamy, L. J. The Infrared Spectra of Complex Molecules, 3rd ed., Vol. I and II, Chapman and Hall, London, 1975, 1980.


How to cite


Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I., Guionneau, P., Pechev, S., Mhiri, T., & Elaoud, Z. (2013). Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. European Journal of Chemistry, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, Ikram, Philippe Guionneau, Stanislav Pechev, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6." European Journal of Chemistry [Online], 4.2 (2013): 117-120. Web. 22 Nov. 2019
Dhouib, Ikram, Guionneau, Philippe, Pechev, Stanislav, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

DOI Link: https://doi.org/10.5155/eurjchem.4.2.117-120.738

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