European Journal of Chemistry 2013, 4(2), 117-120 | doi: https://doi.org/10.5155/eurjchem.4.2.117-120.738 | Get rights and content






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Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Stanislav Pechev (3) , Tahar Mhiri (4) , Zakaria Elaoud (5)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(5) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(*) Corresponding Author

Received: 17 Jan 2013 | Accepted: 23 Jan 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

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Keywords


Single crystal; Copper(II) complex; Spectroscopic study; Tetrapropylammonium; Hexachlorodicuprate(II); Crystal structure analysis

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DOI: 10.5155/eurjchem.4.2.117-120.738

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[1]. A. Oueslati, M. Gargouri
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[3]. F. Lambarki, A. Ouasri, A. Rhandour, M. Saadi, L. El Ammari, L. Hajji
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[4]. Ikram Dhouib, Habib Feki, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
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The Supplementary Material for this article can be found online at: Supplementary files

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Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I., Guionneau, P., Pechev, S., Mhiri, T., & Elaoud, Z. (2013). Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. European Journal of Chemistry, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, Ikram, Philippe Guionneau, Stanislav Pechev, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6." European Journal of Chemistry [Online], 4.2 (2013): 117-120. Web. 29 Sep. 2020
Dhouib, Ikram, Guionneau, Philippe, Pechev, Stanislav, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

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DOI Link: https://doi.org/10.5155/eurjchem.4.2.117-120.738

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