European Journal of Chemistry

Alum [KAl(SO4)2•12H2O] catalyzed microwave assisted synthesis of 5-arylidine-2-(methylthio)-thiazolone derivatives in water



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Santosh Jadhav
Mahesh Shioorkar
Omprakash Chavan
Aniket Sarkate
Devanand Shinde
Rajendra Pardeshi

Abstract

An efficient and environmentally benign method has been developed for the synthesis of 5-arylidine-2-(methylthio)-thiazolones derivatives using Alum [KAl(SO4)2·12H2O] catalyst and triethyl amine in water under microwave irradiation. This green transformation generated one C-S and one C-C bond, condensation and S-methylation. Notable advantages for the present protocol include, short reaction time, cleaner reaction profile and easy isolation of product by microwave irradiation technique using green catalyst and solvent.


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Jadhav, S.; Shioorkar, M.; Chavan, O.; Sarkate, A.; Shinde, D.; Pardeshi, R. Alum [KAl(SO4)2•12H2O] Catalyzed Microwave Assisted Synthesis of 5-Arylidine-2-(methylthio)-Thiazolone Derivatives in Water. Eur. J. Chem. 2015, 6, 410-416.

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Principal and Head, Department of Chemistry, Sant Ramdas College, Ghansawangi, Dist. Jalna affiliated to Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431004 (MS), India
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