European Journal of Chemistry

Synthesis, physicochemical, thermal, fluorescence and catalytic activity studies of novel Mn(II), Co(II), Ni(II) and Cu(II) complexes with tridentate (ONS) Schiff base ligand

Article Sidebar

PDF
Published: Mar 31, 2017
DOI: https://doi.org/10.5155/eurjchem.8.1.85-95.1513
Keywords:
ONS donor sites, Catalytic activity, Thermal analysis, Schiff base ligand, Metals complexes, Fluorescence spectra, 2-((1-(Thiophen-2-yl)ethylidene)amino)phenol
Section
Research Article
Issue
Vol. 8 No. 1 (2017): March 2017
Dates
Received 2016-12-02
Accepted 2017-01-21
Published 2017-03-31


Main Article Content

Manara Ahmed Ayoub
Chemistry Department, Faculty of Women for Arts, Science and Education, Ain-Shams University, Cairo, 11757, Egypt
Eman Hamed Abd-Elnasser
Chemistry Department, Faculty of Women for Arts, Science and Education, Ain-Shams University, Cairo, 11757, Egypt
Mona Abdel-Aziz Ahmed
Chemistry Department, Faculty of Women for Arts, Science and Education, Ain-Shams University, Cairo, 11757, Egypt
Marium Girgis Rizk
Chemistry Department, Faculty of Women for Arts, Science and Education, Ain-Shams University, Cairo, 11757, Egypt

Abstract

Syntheses and physicochemical studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with tridentate Schiff base ligand (E)-2-((1-(thiophen-2-yl)ethylidene)amino)phenol (HL)(ATS) were characterized by elemental analysis, FT-IR, Mass, 1H NMR, UV-Vis, magnetic moment, thermal analysis (TG and DTG) techniques, molar conductance and fluorescence spectra. The IR spectra showed that complexes were coordinated in metal ions via the imine N, O and S atoms. Magnetic and UV-Vis spectra, indicated that the geometrical structure of Mn(II), Co(II) and Ni(II) complexes are an octahedral while Cu(II) is a tetrahedral. The kinetic thermodynamic parameters such as E*, DH*, DS* and DG* were determined for each thermal degradation stage of TG curves of the metal(II) complexes using Coat-Redfern method. Fluorescence studies indicated that the Schiff base ligand HL(ATS), and its metal(II) complexes can serve as potential photoactive materials as indicated from their characteristic fluorescence properties and study the effect of solvent and pH on it. The catalytic activities of metal(II) complexes were studied using H2O2 solution.


icon graph This Abstract was viewed 1649 times | icon graph Article PDF downloaded 739 times

How to Cite
(1)
Ayoub, M. A.; Abd-Elnasser, E. H.; Ahmed, M. A.-A.; Rizk, M. G. Synthesis, Physicochemical, Thermal, Fluorescence and Catalytic Activity Studies of Novel Mn(II), Co(II), Ni(II) and Cu(II) Complexes With Tridentate (ONS) Schiff Base Ligand. Eur. J. Chem. 2017, 8, 85-95.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Singh, K.; Barwa, M. S.; Tyagi, P. Eur. J. Med. Chem. 2007, 42, 394-402.
https://doi.org/10.1016/j.ejmech.2006.10.016

[2]. Dhahagani, K.; Mathan Kumar, S.; Chakkaravarthi, G., Anitha, K.; Rajesh, J.; Ramu, A.; Rajagopal, G. Spectrochim. Acta A 2014, 117, 87-94.
https://doi.org/10.1016/j.saa.2013.07.101

[3]. Refat, M. S.; El-Sayed, M. Y.; Adam, A. M. J. Mol. Struct. 2013, 1038, 62-72.
https://doi.org/10.1016/j.molstruc.2013.01.059

[4]. Padmaja, M.; Pragathi, J.; Anupama, B.; Gyana, K. C. E-J. Chem. 2012, 9, 2145-2154.

[5]. Ramadan, A. M.; Ibrahim, M. M.; Shaban, S. Y. J. Mol. Struct. 2011, 1006, 348-355.
https://doi.org/10.1016/j.molstruc.2011.09.031

[6]. Viswanathamurthi, P.; Natarajan, K. Synth. React. Met. Org. 2006, 36, 415-418.
https://doi.org/10.1080/15533170600732619

[7]. Yildiz, M.; Dulger, B.; Koyuncu, S. Y. J. Indian Chem. Soc. 2004, 81, 7-12.

[8]. Lakowicz, J. R. Principles of fluorescence spectroscopy, 3th edition, New York, Springer, 2006.
https://doi.org/10.1007/978-0-387-46312-4

[9]. Sharma, A.; Schulman, A. G. Introduction to fluorescence spectroscopy, New York, John Wiley & Sons, Inc. 1999.

[10]. Basak, S.; Sen, S.; Banerjee, S.; Mitra, S.; Rosair, G.; Rodriguez, M. T. G. Polyhedron 2007, 26, 5104-5112.
https://doi.org/10.1016/j.poly.2007.07.025

[11]. Omyma, A. M. A.; Samir, M. E.; Doaa, A. A.; Doaa A. N. Spectrochim. Acta A 2015, 144, 99-106.
https://doi.org/10.1016/j.saa.2015.02.078

[12]. Ali, O. A. M. Spectrochim. Acta A 2014, 121, 188-195.
https://doi.org/10.1016/j.saa.2013.10.015

[13]. Gupta, K. C.; Abdulkadir, H. K. J. Macromol. Sci. A 2007, 45, 53-64.
https://doi.org/10.1080/10601320701683256

[14]. Pouralimardan, O.; Chamayou, A. C.; Janiak, C.; Hosseini-Monfared, H. Inorg. Chim. Acta 2007, 360, 1599-1608.
https://doi.org/10.1016/j.ica.2006.08.056

[15]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edition, Wiley Interscience, New York, 1997.

[16]. Spinu, C.; Pleniceanu, M.; Tigae, C. Turk. J. Chem. 2008, 32, 487-493.

[17]. Lever, A. B. P. Inorganic electronic spectroscopy, 2nd edition, Elsevier, New York, 1984.

[18]. Chandra, S.; Gupta, K. Transition Met. Chem. 2002, 27, 329-332.
https://doi.org/10.1023/A:1014898706298

[19]. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 4th edition, Wiley, New York, 1980.

[20]. Coats, A. W.; Redfern, J. P. Nature 1964, 20, 68-69.
https://doi.org/10.1038/201068a0

[21]. Taakeyama, T.; Quinn, F. X. Thermal Analysis, Fundamentals and Applications to Polymer Science, John Wiley& Sons, Chichester, 1994.

[22]. Frost, A. A.; Pearson, R. G. Kinetic and Mechanisms, 2nd edition, Wiley, New York, 1961.

[23]. Majumder, A.; Rosair, G. M.; Mallick, A.; Chattopadhyay, N.; Mitra, S. Polyhedron 2006, 25, 1753-1762.
https://doi.org/10.1016/j.poly.2005.11.029

[24]. Liu, Q. X. Polyhedron 2009, 28, 917-922.
https://doi.org/10.1016/j.poly.2009.01.017

[25]. Omyma, A. M. A.; Samir, M. E.; Maha, R. A.; Abeer, S. S. S. Spectrochim. Acta A 2015, 136, 654-660.

Supporting Agencies

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).