Design, synthesis and characterization of MOF-199 and ZIF-8: Applications in the adsorption of phenols derivatives in aqueous solution

Liliana Giraldo; Marlon Bastidas-Barranco; Pablo Húmpola; Juan Carlos Moreno-Piraján

doi:10.5155/eurjchem.8.3.293-304.1603

PDF

Published: Sep 30, 2017

DOI: https://doi.org/10.5155/eurjchem.8.3.293-304.1603

Keywords:

ZIF-8, Phenols, MOF-199, Microporous, Metal-organic framework, Adsorption characteristics

Section

Research Article

Issue

Vol. 8 No. 3 (2017): September 2017

Dates

Received 2017-06-28
Accepted 2017-08-05
Published 2017-09-30

Liliana Giraldo

Facultad de Ciencias, Universidad Nacional de Colombia, Bogotá, 11001000, Colombia

Marlon Bastidas-Barranco

Facultad de Ingeniería, Grupo DestaCar, Universidad de la Guajira, Guajira, 440001, Colombia

Pablo Húmpola

Facultad de Bioquímica y Cs. Biológicas, Universidad Nacional del Litoral, Santa Fe, 3000, Argentina

Juan Carlos Moreno-Piraján

Facultad de Ciencias, Grupo de Investigación en Sólidos Porosos y Calorimetría, Universidad de los Andes, Bogotá, 11001000, Colombia

Abstract

In this work, the adsorption characteristics of metal-organic frameworks (MOFs: MOF-199 and ZIF-8) with two different types of structure were analyzed. MOF-199 consists of copper-based metal clusters while the ZIF-8 consists of organic molecules interlaced with zinc atoms and these have octahedral morphology and typical rhombic dodecahedron shape, respectively. The results of phenol (Ph) and p-nitro phenol (PNP) adsorption capacity from aqueous solution show that MOF-199 has a higher adsorption capacity: Ph 79.55% and PNP 89.3%, while for ZIF-8 the adsorption capacity was Ph 65.5% and PNP 77.0%. Adsorption of phenols was fit to Langmuir, Sips and Redlich-Peterson models and kinetics by pseudo-second order. Gibbs free energy (ΔG°) shows that adsorption processes studied are spontaneous.

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Giraldo, L.; Bastidas-Barranco, M.; Húmpola, P.; Moreno-Piraján, J. C. Design, Synthesis and Characterization of MOF-199 and ZIF-8: Applications in the Adsorption of Phenols Derivatives in Aqueous Solution. Eur. J. Chem. 2017, 8, 293-304.

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Supporting Agencies

Grant Basic Sciences by the University of the Andes through the Faculty of Science and the Vice-rectory of Research, and the Bank of the Republic of Colombia for their funding and the Convention 3580.

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