#============================================================================== data_global loop_ _journal_name_full 'European Journal of Chemistry' _journal_coden_ASTM EJCUA9 _journal_volume 10 _journal_issue 4 _journal_year 2019 _journal_page_first 345 _journal_page_last 349 #=============================================================================== _audit_creation_date 'July 14 2019' _audit_update_record ; 2019-07-30 # Formatted by publCIF ; #=================================================================== # 1. SUBMISSION DETAILS _publ_contact_author # Name and address of author for correspondence ; Shahobiddin M. Adizov S.Yunusov Institute of the Chemistry of Plant Substances Academy of Sciences of Uzbekistan Mirzo Ulugbek Str., 77, Tashkent 100170, Uzbekistan ; _publ_contact_author_phone '+998 71 262-78-97' _publ_contact_author_fax '+998 71 120-64-75' _publ_contact_author_email adizovsh@gmail.com _publ_requested_journal ; Eur.J. Chem. ; _publ_requested_coeditor_name ? _publ_contact_letter ; Please consider this CIF submission for publication as a Regular Structure Eur.J. Chem. ; #====================================================================== # 4. TEXT # start Validation Reply Form _vrf_THETM01_1 ; PROBLEM: The value of sine(theta_max)/wavelength is less than 0.575 Calculated sin(theta_max)/wavelength = 0.5611 RESPONSE: In Stoe Stadi4 diffractometr Theta angle is max 60 degree. ; _vrf_STRVA01_1 ; PROBLEM: Flack test results are meaningless. From the CIF: _refine_ls_abs_structure_Flack 0.300 From the CIF: _refine_ls_abs_structure_Flack_su 0.800. RESPONSE:Although Flack parameter is meaningless for absolute configuration but it’s configuration can be established by close related molecules of known absolute configuration. ; # end Validation Reply Form data_I #======================================================================= _audit_creation_method 'SHELXL-2014/7' _shelx_SHELXL_version_number '2014/7' _chemical_name_systematic ? _chemical_name_common '10-Ac-akuammine' _chemical_melting_point 479.8 _chemical_formula_moiety 'C24 H28 N2 O5' _chemical_formula_sum 'C24 H28 N2 O5' _chemical_formula_weight 424.48 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _space_group_crystal_system orthorhombic _space_group_IT_number 19 _space_group_name_H-M_alt 'P 21 21 21' _space_group_name_Hall 'P 2ac 2ab' _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' _cell_length_a 7.349(3) _cell_length_b 16.099(5) _cell_length_c 17.323(5) _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 2049.5(12) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 25 _cell_measurement_theta_min 30 _cell_measurement_theta_max 5 _exptl_crystal_description prizm _exptl_crystal_colour colourless _exptl_crystal_density_meas none _exptl_crystal_density_method 'not measured' _exptl_crystal_density_diffrn 1.376 _exptl_crystal_F_000 904 _exptl_transmission_factor_min ? _exptl_transmission_factor_max ? _exptl_crystal_size_max 0.700 _exptl_crystal_size_mid 0.300 _exptl_crystal_size_min 0.200 _exptl_absorpt_coefficient_mu 0.789 _shelx_estimated_absorpt_T_min 0.608 _shelx_estimated_absorpt_T_max 0.858 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_absorpt_process_details ? _exptl_absorpt_special_details ? _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 1.54184 _diffrn_radiation_type CuK\a _diffrn_source ? _diffrn_measurement_device_type 'STOE STADI4 4-circle-diffractometer D092' _diffrn_measurement_method ; Scan width (omega) = 1.56 - 1.68, scan ratio 2theta:omega = 1.00 I(Net) and sigma(I) calculated according to Blessing (1987) ; _diffrn_detector_area_resol_mean 10.2576 _diffrn_reflns_number 1742 _diffrn_reflns_av_unetI/netI 0.0374 _diffrn_reflns_av_R_equivalents 0 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_k_max 18 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 3.748 _diffrn_reflns_theta_max 59.896 _diffrn_reflns_theta_full 59.896 _diffrn_measured_fraction_theta_max 0.986 _diffrn_measured_fraction_theta_full 0.986 _diffrn_reflns_Laue_measured_fraction_max 0.986 _diffrn_reflns_Laue_measured_fraction_full 0.986 _diffrn_reflns_point_group_measured_fraction_max 0.574 _diffrn_reflns_point_group_measured_fraction_full 0.574 _reflns_number_total 1742 _reflns_number_gt 1403 _reflns_threshold_expression 'I > 2\s(I)' _reflns_Friedel_coverage 0.000 _reflns_Friedel_fraction_max 0.000 _reflns_Friedel_fraction_full 0.000 _reflns_special_details ; Reflections were merged by SHELXL according to the crystal class for the calculation of statistics and refinement. _reflns_Friedel_fraction is defined as the number of unique Friedel pairs measured divided by the number that would be possible theoretically, ignoring centric projections and systematic absences. ; _computing_data_collection 'STADI4 (Stoe & Cie, 1997a)' _computing_cell_refinement STADI4 _computing_data_reduction 'X-RED (Stoe & Cie, 1997b)' _computing_structure_solution 'SHELXL-2014/7 (Sheldrick, 2014)' _computing_structure_refinement 'SHELXL-2014/7 (Sheldrick, 2014)' _computing_molecular_graphics 'XP V5.1 (Bruker AXS, 1998)' _computing_publication_material 'publCIF (Westrip, 2014)' _refine_special_details ? _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0743P)^2^+2.0267P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method 'SHELXL-2014/7 (Sheldrick 2014' _refine_ls_extinction_coef 0.0040(6) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_abs_structure_details ; No quotients, so Flack parameter determined by classical intensity fit ; _refine_ls_abs_structure_Flack 0.3(8) _chemical_absolute_configuration rm _refine_ls_number_reflns 1742 _refine_ls_number_parameters 286 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0841 _refine_ls_R_factor_gt 0.0608 _refine_ls_wR_factor_ref 0.1690 _refine_ls_wR_factor_gt 0.1438 _refine_ls_goodness_of_fit_ref 1.130 _refine_ls_restrained_S_all 1.130 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group O1 O 0.1049(8) 0.6852(3) 0.0300(3) 0.0699(16) Uani 1 1 d . . . . . O2 O 0.135(3) 0.8062(5) 0.0759(4) 0.259(10) Uani 1 1 d . . . . . O3 O 0.5276(6) 0.5079(3) 0.2756(2) 0.0480(11) Uani 1 1 d . . . . . O4 O 0.5135(7) 0.4370(3) 0.0213(3) 0.0599(13) Uani 1 1 d . . . . . O5 O 0.7863(6) 0.4754(3) 0.0640(3) 0.0571(14) Uani 1 1 d . . . . . N1 N 0.2132(7) 0.4888(3) 0.2865(3) 0.0459(13) Uani 1 1 d . . . . . C2 C 0.3782(9) 0.4484(4) 0.2623(3) 0.0416(15) Uani 1 1 d . . . . . C3 C 0.4336(10) 0.3648(4) 0.2969(4) 0.0516(18) Uani 1 1 d . . . . . H3A H 0.4146 0.3655 0.3529 0.062 Uiso 1 1 calc R U . . . N4 N 0.3294(8) 0.2944(3) 0.2615(3) 0.0508(15) Uani 1 1 d . . . . . C5 C 0.1792(9) 0.3213(4) 0.2135(4) 0.0496(17) Uani 1 1 d . . . . . H5A H 0.0946 0.3530 0.2447 0.060 Uiso 1 1 calc R U . . . H5B H 0.1153 0.2728 0.1943 0.060 Uiso 1 1 calc R U . . . C6 C 0.2397(9) 0.3737(3) 0.1459(4) 0.0410(15) Uani 1 1 d . . . . . H6A H 0.1342 0.3969 0.1201 0.049 Uiso 1 1 calc R U . . . H6B H 0.3053 0.3395 0.1092 0.049 Uiso 1 1 calc R U . . . C7 C 0.3637(8) 0.4446(3) 0.1745(3) 0.0330(13) Uani 1 1 d . . . . . C8 C 0.2672(9) 0.5266(3) 0.1615(3) 0.0375(14) Uani 1 1 d . . . . . C9 C 0.2402(9) 0.5732(3) 0.0961(4) 0.0435(15) Uani 1 1 d . . . . . H9A H 0.2949 0.5585 0.0496 0.052 Uiso 1 1 calc R U . . . C10 C 0.1292(11) 0.6427(4) 0.1011(4) 0.0501(17) Uani 1 1 d . . . . . C11 C 0.0427(10) 0.6646(4) 0.1676(4) 0.0547(18) Uani 1 1 d . . . . . H11A H -0.0318 0.7112 0.1689 0.066 Uiso 1 1 calc R U . . . C12 C 0.0671(9) 0.6164(4) 0.2333(4) 0.0500(17) Uani 1 1 d . . . . . H12A H 0.0101 0.6307 0.2794 0.060 Uiso 1 1 calc R U . . . C13 C 0.1764(9) 0.5475(4) 0.2293(4) 0.0436(15) Uani 1 1 d . . . . . C14 C 0.6360(10) 0.3552(5) 0.2790(4) 0.0533(18) Uani 1 1 d . . . . . H14A H 0.6806 0.3027 0.2990 0.064 Uiso 1 1 calc R U . . . H14B H 0.7047 0.3998 0.3028 0.064 Uiso 1 1 calc R U . . . C15 C 0.6583(9) 0.3580(4) 0.1909(3) 0.0440(16) Uani 1 1 d . . . . . H15A H 0.7887 0.3591 0.1790 0.053 Uiso 1 1 calc R U . . . C16 C 0.5691(8) 0.4392(4) 0.1571(3) 0.0329(13) Uani 1 1 d . . . . . C17 C 0.6143(9) 0.4495(4) 0.0743(4) 0.0420(15) Uani 1 1 d . . . . . C18 C 0.7805(13) 0.2576(5) 0.0453(4) 0.078(3) Uani 1 1 d . . . . . H18A H 0.8582 0.2107 0.0362 0.117 Uiso 1 1 calc R U . . . H18B H 0.8514 0.3028 0.0654 0.117 Uiso 1 1 calc R U . . . H18C H 0.7245 0.2742 -0.0023 0.117 Uiso 1 1 calc R U . . . C19 C 0.6394(11) 0.2350(4) 0.1011(4) 0.060(2) Uani 1 1 d . . . . . H19 H 0.5822 0.1844 0.0918 0.071 Uiso 1 1 calc R U . . . C20 C 0.5808(9) 0.2752(4) 0.1628(4) 0.0481(17) Uani 1 1 d . . . . . C21 C 0.4465(11) 0.2370(4) 0.2183(4) 0.061(2) Uani 1 1 d . . . . . H21A H 0.3689 0.1994 0.1895 0.073 Uiso 1 1 calc R U . . . H21B H 0.5140 0.2038 0.2553 0.073 Uiso 1 1 calc R U . . . C22 C 0.6397(9) 0.5107(4) 0.2072(3) 0.0455(16) Uani 1 1 d . . . . . H22A H 0.7669 0.5026 0.2201 0.055 Uiso 1 1 calc R U . . . H22B H 0.6262 0.5634 0.1808 0.055 Uiso 1 1 calc R U . . . C23 C 0.1822(12) 0.5074(5) 0.3668(4) 0.067(2) Uani 1 1 d . . . . . H23A H 0.1891 0.4571 0.3964 0.100 Uiso 1 1 calc R U . . . H23B H 0.0637 0.5317 0.3728 0.100 Uiso 1 1 calc R U . . . H23C H 0.2730 0.5457 0.3846 0.100 Uiso 1 1 calc R U . . . C24 C 0.1144(14) 0.7955(5) -0.0553(4) 0.072(2) Uani 1 1 d . . . . . H24A H 0.2038 0.7672 -0.0860 0.108 Uiso 1 1 calc R U . . . H24B H 0.1395 0.8541 -0.0554 0.108 Uiso 1 1 calc R U . . . H24C H -0.0044 0.7858 -0.0764 0.108 Uiso 1 1 calc R U . . . C25 C 0.1210(14) 0.7651(5) 0.0219(5) 0.082(3) Uani 1 1 d . . . . . C26 C 0.8454(12) 0.4875(6) -0.0145(4) 0.079(3) Uani 1 1 d . . . . . H26A H 0.9732 0.4997 -0.0151 0.118 Uiso 1 1 calc R U . . . H26B H 0.7794 0.5330 -0.0369 0.118 Uiso 1 1 calc R U . . . H26C H 0.8228 0.4379 -0.0437 0.118 Uiso 1 1 calc R U . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O1 0.097(4) 0.045(3) 0.068(3) 0.011(2) -0.008(3) 0.017(3) O2 0.59(3) 0.093(5) 0.090(5) 0.013(4) -0.102(11) -0.116(11) O3 0.050(3) 0.049(2) 0.046(2) -0.010(2) -0.002(2) -0.012(2) O4 0.057(3) 0.084(3) 0.039(2) 0.003(3) -0.003(3) -0.004(3) O5 0.047(3) 0.071(3) 0.053(3) -0.002(2) 0.011(2) -0.011(3) N1 0.051(3) 0.049(3) 0.038(3) -0.002(3) 0.011(3) 0.002(3) C2 0.047(4) 0.041(3) 0.037(3) 0.002(3) 0.003(3) -0.003(3) C3 0.066(5) 0.046(4) 0.043(4) 0.009(3) 0.001(3) 0.006(4) N4 0.054(4) 0.038(3) 0.060(3) 0.008(3) 0.000(3) -0.005(3) C5 0.046(4) 0.041(3) 0.062(4) 0.010(3) 0.002(4) -0.011(3) C6 0.037(3) 0.036(3) 0.050(4) 0.003(3) -0.005(3) -0.004(3) C7 0.034(3) 0.028(3) 0.036(3) 0.002(2) 0.000(3) -0.002(3) C8 0.039(3) 0.031(3) 0.042(3) 0.000(3) 0.004(3) 0.001(3) C9 0.045(4) 0.034(3) 0.052(4) 0.004(3) 0.001(3) 0.003(3) C10 0.059(4) 0.038(3) 0.054(4) 0.004(3) -0.008(4) 0.013(4) C11 0.055(4) 0.042(4) 0.067(5) -0.006(4) -0.002(4) 0.007(3) C12 0.050(4) 0.046(4) 0.054(4) -0.010(3) 0.008(3) 0.006(3) C13 0.046(4) 0.037(3) 0.048(4) -0.005(3) 0.000(3) -0.005(3) C14 0.054(4) 0.056(4) 0.050(4) 0.007(4) -0.018(4) 0.006(4) C15 0.041(4) 0.041(3) 0.049(4) 0.004(3) -0.007(3) 0.004(3) C16 0.031(3) 0.034(3) 0.034(3) -0.001(3) 0.000(3) -0.001(3) C17 0.039(3) 0.037(3) 0.050(4) 0.006(3) 0.007(3) -0.001(3) C18 0.077(6) 0.078(5) 0.079(6) -0.032(5) 0.009(5) 0.009(5) C19 0.060(5) 0.045(4) 0.073(5) -0.012(4) -0.003(4) 0.014(4) C20 0.045(4) 0.040(3) 0.059(4) 0.006(3) -0.005(3) 0.008(3) C21 0.069(5) 0.040(3) 0.073(5) 0.011(4) 0.004(4) 0.003(4) C22 0.042(3) 0.045(3) 0.050(4) -0.002(3) -0.008(3) -0.006(3) C23 0.081(6) 0.074(5) 0.046(4) 0.002(4) 0.015(4) 0.009(5) C24 0.096(6) 0.056(4) 0.065(5) 0.018(4) 0.000(5) 0.010(5) C25 0.118(8) 0.069(6) 0.061(5) 0.000(5) -0.038(6) -0.030(6) C26 0.074(6) 0.099(6) 0.063(5) 0.002(5) 0.028(5) -0.012(5) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag O1 C25 1.300(9) . ? O1 C10 1.420(8) . ? O2 C25 1.150(9) . ? O3 C22 1.444(7) . ? O3 C2 1.475(8) . ? O4 C17 1.196(7) . ? O5 C17 1.343(8) . ? O5 C26 1.441(8) . ? N1 C13 1.395(8) . ? N1 C2 1.438(8) . ? N1 C23 1.442(8) . ? C2 C7 1.525(8) . ? C2 C3 1.529(9) . ? C3 N4 1.500(9) . ? C3 C14 1.527(10) . ? C3 H3A 0.9800 . ? N4 C5 1.447(8) . ? N4 C21 1.468(9) . ? C5 C6 1.511(8) . ? C5 H5A 0.9700 . ? C5 H5B 0.9700 . ? C6 C7 1.541(8) . ? C6 H6A 0.9700 . ? C6 H6B 0.9700 . ? C7 C8 1.516(8) . ? C7 C16 1.541(8) . ? C8 C9 1.373(8) . ? C8 C13 1.392(8) . ? C9 C10 1.388(9) . ? C9 H9A 0.9300 . ? C10 C11 1.361(9) . ? C11 C12 1.390(9) . ? C11 H11A 0.9300 . ? C12 C13 1.372(9) . ? C12 H12A 0.9300 . ? C14 C15 1.537(9) . ? C14 H14A 0.9700 . ? C14 H14B 0.9700 . ? C15 C20 1.529(9) . ? C15 C16 1.575(8) . ? C15 H15A 0.9800 . ? C16 C17 1.483(8) . ? C16 C22 1.532(8) . ? C18 C19 1.464(11) . ? C18 H18A 0.9600 . ? C18 H18B 0.9600 . ? C18 H18C 0.9600 . ? C19 C20 1.321(9) . ? C19 H19 0.9300 . ? C20 C21 1.510(9) . ? C21 H21A 0.9700 . ? C21 H21B 0.9700 . ? C22 H22A 0.9700 . ? C22 H22B 0.9700 . ? C23 H23A 0.9600 . ? C23 H23B 0.9600 . ? C23 H23C 0.9600 . ? C24 C25 1.424(10) . ? C24 H24A 0.9600 . ? C24 H24B 0.9600 . ? C24 H24C 0.9600 . ? C26 H26A 0.9600 . ? C26 H26B 0.9600 . ? C26 H26C 0.9600 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C25 O1 C10 124.0(6) . . ? C22 O3 C2 108.4(4) . . ? C17 O5 C26 116.8(6) . . ? C13 N1 C2 105.3(5) . . ? C13 N1 C23 120.9(6) . . ? C2 N1 C23 120.6(6) . . ? N1 C2 O3 106.8(4) . . ? N1 C2 C7 104.5(5) . . ? O3 C2 C7 103.6(5) . . ? N1 C2 C3 120.6(5) . . ? O3 C2 C3 108.2(5) . . ? C7 C2 C3 111.9(5) . . ? N4 C3 C14 109.7(6) . . ? N4 C3 C2 111.6(5) . . ? C14 C3 C2 105.6(6) . . ? N4 C3 H3A 109.9 . . ? C14 C3 H3A 109.9 . . ? C2 C3 H3A 109.9 . . ? C5 N4 C21 110.1(5) . . ? C5 N4 C3 113.5(5) . . ? C21 N4 C3 112.7(6) . . ? N4 C5 C6 112.8(5) . . ? N4 C5 H5A 109.0 . . ? C6 C5 H5A 109.0 . . ? N4 C5 H5B 109.0 . . ? C6 C5 H5B 109.0 . . ? H5A C5 H5B 107.8 . . ? C5 C6 C7 109.8(5) . . ? C5 C6 H6A 109.7 . . ? C7 C6 H6A 109.7 . . ? C5 C6 H6B 109.7 . . ? C7 C6 H6B 109.7 . . ? H6A C6 H6B 108.2 . . ? C8 C7 C2 98.4(5) . . ? C8 C7 C6 108.6(5) . . ? C2 C7 C6 113.1(5) . . ? C8 C7 C16 118.5(5) . . ? C2 C7 C16 97.4(5) . . ? C6 C7 C16 118.3(5) . . ? C9 C8 C13 119.7(6) . . ? C9 C8 C7 131.8(6) . . ? C13 C8 C7 108.0(5) . . ? C8 C9 C10 118.3(6) . . ? C8 C9 H9A 120.9 . . ? C10 C9 H9A 120.9 . . ? C11 C10 C9 122.4(6) . . ? C11 C10 O1 123.3(6) . . ? C9 C10 O1 114.1(6) . . ? C10 C11 C12 119.2(6) . . ? C10 C11 H11A 120.4 . . ? C12 C11 H11A 120.4 . . ? C13 C12 C11 119.0(6) . . ? C13 C12 H12A 120.5 . . ? C11 C12 H12A 120.5 . . ? C12 C13 C8 121.3(6) . . ? C12 C13 N1 128.7(6) . . ? C8 C13 N1 110.0(5) . . ? C3 C14 C15 107.6(6) . . ? C3 C14 H14A 110.2 . . ? C15 C14 H14A 110.2 . . ? C3 C14 H14B 110.2 . . ? C15 C14 H14B 110.2 . . ? H14A C14 H14B 108.5 . . ? C20 C15 C14 104.5(6) . . ? C20 C15 C16 116.8(5) . . ? C14 C15 C16 110.4(5) . . ? C20 C15 H15A 108.3 . . ? C14 C15 H15A 108.3 . . ? C16 C15 H15A 108.3 . . ? C17 C16 C22 112.9(5) . . ? C17 C16 C7 113.7(5) . . ? C22 C16 C7 100.3(5) . . ? C17 C16 C15 111.0(5) . . ? C22 C16 C15 105.8(5) . . ? C7 C16 C15 112.4(5) . . ? O4 C17 O5 122.3(6) . . ? O4 C17 C16 125.7(6) . . ? O5 C17 C16 111.9(6) . . ? C19 C18 H18A 109.5 . . ? C19 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? C19 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? C20 C19 C18 130.0(7) . . ? C20 C19 H19 115.0 . . ? C18 C19 H19 115.0 . . ? C19 C20 C21 121.9(6) . . ? C19 C20 C15 124.3(6) . . ? C21 C20 C15 113.4(6) . . ? N4 C21 C20 116.8(5) . . ? N4 C21 H21A 108.1 . . ? C20 C21 H21A 108.1 . . ? N4 C21 H21B 108.1 . . ? C20 C21 H21B 108.1 . . ? H21A C21 H21B 107.3 . . ? O3 C22 C16 104.4(5) . . ? O3 C22 H22A 110.9 . . ? C16 C22 H22A 110.9 . . ? O3 C22 H22B 110.9 . . ? C16 C22 H22B 110.9 . . ? H22A C22 H22B 108.9 . . ? N1 C23 H23A 109.5 . . ? N1 C23 H23B 109.5 . . ? H23A C23 H23B 109.5 . . ? N1 C23 H23C 109.5 . . ? H23A C23 H23C 109.5 . . ? H23B C23 H23C 109.5 . . ? C25 C24 H24A 109.5 . . ? C25 C24 H24B 109.5 . . ? H24A C24 H24B 109.5 . . ? C25 C24 H24C 109.5 . . ? H24A C24 H24C 109.5 . . ? H24B C24 H24C 109.5 . . ? O2 C25 O1 119.3(8) . . ? O2 C25 C24 124.6(8) . . ? O1 C25 C24 116.0(7) . . ? O5 C26 H26A 109.5 . . ? O5 C26 H26B 109.5 . . ? H26A C26 H26B 109.5 . . ? O5 C26 H26C 109.5 . . ? H26A C26 H26C 109.5 . . ? H26B C26 H26C 109.5 . . ? _refine_diff_density_max 0.194 _refine_diff_density_min -0.304 _refine_diff_density_rms 0.054 _shelx_res_file ; 1.res created by SHELXL-2014/7 TITL AR1 in P2(1)2(1)2(1) CELL 1.54184 7.349 16.099 17.323 90 90 90 ZERR 4 0.003 0.005 0.005 0 0 0 LATT -1 SYMM 0.5-X,-Y,0.5+Z SYMM -X,0.5+Y,0.5-Z SYMM 0.5+X,0.5-Y,-Z SFAC C H N O UNIT 96 112 8 20 L.S. 8 PLAN 20 SIZE 0.2 0.3 0.7 BOND $H fmap 2 acta REM J:/FATTAH/2012/VINCA/O-Aclakuammine/AR1.hkl WGHT 0.074300 2.026700 EXTI 0.003972 FVAR 0.78019 0.45186 O1 4 0.104864 0.685201 0.030049 11.00000 0.09672 0.04472 = 0.06837 0.01140 -0.00820 0.01665 O2 4 0.135252 0.806216 0.075850 11.00000 0.59212 0.09336 = 0.09018 0.01345 -0.10165 -0.11616 O3 4 0.527640 0.507892 0.275644 11.00000 0.04975 0.04862 = 0.04567 -0.00955 -0.00193 -0.01165 O4 4 0.513462 0.436972 0.021343 11.00000 0.05706 0.08386 = 0.03887 0.00338 -0.00305 -0.00392 O5 4 0.786307 0.475393 0.064035 11.00000 0.04670 0.07117 = 0.05338 -0.00247 0.01093 -0.01125 N1 3 0.213230 0.488812 0.286452 11.00000 0.05102 0.04869 = 0.03809 -0.00228 0.01133 0.00223 C2 1 0.378198 0.448421 0.262282 11.00000 0.04731 0.04102 = 0.03659 0.00175 0.00329 -0.00273 C3 1 0.433594 0.364829 0.296904 11.00000 0.06561 0.04562 = 0.04345 0.00901 0.00109 0.00613 AFIX 13 H3A 2 0.414599 0.365500 0.352896 11.00000 -1.20000 AFIX 0 N4 3 0.329363 0.294410 0.261469 11.00000 0.05432 0.03798 = 0.05998 0.00846 -0.00009 -0.00512 C5 1 0.179208 0.321262 0.213514 11.00000 0.04560 0.04129 = 0.06202 0.01033 0.00201 -0.01113 AFIX 23 H5A 2 0.094602 0.353031 0.244747 11.00000 -1.20000 H5B 2 0.115315 0.272780 0.194263 11.00000 -1.20000 AFIX 0 C6 1 0.239712 0.373737 0.145937 11.00000 0.03747 0.03553 = 0.05003 0.00278 -0.00534 -0.00434 AFIX 23 H6A 2 0.134174 0.396873 0.120082 11.00000 -1.20000 H6B 2 0.305277 0.339519 0.109187 11.00000 -1.20000 AFIX 0 C7 1 0.363747 0.444555 0.174535 11.00000 0.03444 0.02815 = 0.03646 0.00224 -0.00003 -0.00180 C8 1 0.267169 0.526588 0.161467 11.00000 0.03869 0.03129 = 0.04244 0.00009 0.00420 0.00122 C9 1 0.240206 0.573182 0.096079 11.00000 0.04472 0.03370 = 0.05198 0.00378 0.00069 0.00319 AFIX 43 H9A 2 0.294940 0.558545 0.049625 11.00000 -1.20000 AFIX 0 C10 1 0.129155 0.642687 0.101112 11.00000 0.05877 0.03757 = 0.05407 0.00445 -0.00761 0.01252 C11 1 0.042727 0.664583 0.167551 11.00000 0.05522 0.04167 = 0.06733 -0.00565 -0.00159 0.00687 AFIX 43 H11A 2 -0.031792 0.711250 0.168926 11.00000 -1.20000 AFIX 0 C12 1 0.067098 0.616417 0.233306 11.00000 0.04996 0.04610 = 0.05400 -0.01009 0.00830 0.00577 AFIX 43 H12A 2 0.010125 0.630703 0.279368 11.00000 -1.20000 AFIX 0 C13 1 0.176407 0.547495 0.229286 11.00000 0.04558 0.03706 = 0.04812 -0.00547 -0.00018 -0.00530 C14 1 0.636020 0.355192 0.279010 11.00000 0.05402 0.05590 = 0.04991 0.00742 -0.01800 0.00645 AFIX 23 H14A 2 0.680644 0.302744 0.299042 11.00000 -1.20000 H14B 2 0.704674 0.399829 0.302806 11.00000 -1.20000 AFIX 0 C15 1 0.658336 0.357998 0.190851 11.00000 0.04140 0.04115 = 0.04946 0.00446 -0.00664 0.00430 AFIX 13 H15A 2 0.788687 0.359124 0.178965 11.00000 -1.20000 AFIX 0 C16 1 0.569109 0.439197 0.157119 11.00000 0.03076 0.03396 = 0.03399 -0.00067 -0.00028 -0.00129 C17 1 0.614316 0.449520 0.074263 11.00000 0.03882 0.03673 = 0.05031 0.00604 0.00713 -0.00091 C18 1 0.780523 0.257619 0.045293 11.00000 0.07668 0.07751 = 0.07922 -0.03166 0.00874 0.00860 AFIX 137 H18A 2 0.858192 0.210680 0.036207 11.00000 -1.50000 H18B 2 0.851394 0.302803 0.065389 11.00000 -1.50000 H18C 2 0.724489 0.274224 -0.002329 11.00000 -1.50000 AFIX 0 C19 1 0.639408 0.234964 0.101145 11.00000 0.06033 0.04506 = 0.07317 -0.01167 -0.00329 0.01386 AFIX 43 H19 2 0.582207 0.184431 0.091775 11.00000 -1.20000 AFIX 0 C20 1 0.580785 0.275209 0.162789 11.00000 0.04504 0.04007 = 0.05913 0.00645 -0.00454 0.00844 C21 1 0.446456 0.236975 0.218327 11.00000 0.06898 0.03988 = 0.07310 0.01147 0.00409 0.00270 AFIX 23 H21A 2 0.368857 0.199392 0.189487 11.00000 -1.20000 H21B 2 0.513961 0.203814 0.255280 11.00000 -1.20000 AFIX 0 C22 1 0.639668 0.510678 0.207205 11.00000 0.04184 0.04464 = 0.04998 -0.00229 -0.00828 -0.00602 AFIX 23 H22A 2 0.766892 0.502619 0.220102 11.00000 -1.20000 H22B 2 0.626203 0.563449 0.180792 11.00000 -1.20000 AFIX 0 C23 1 0.182167 0.507380 0.366787 11.00000 0.08074 0.07422 = 0.04584 0.00168 0.01518 0.00881 AFIX 137 H23A 2 0.189051 0.457101 0.396438 11.00000 -1.50000 H23B 2 0.063747 0.531699 0.372826 11.00000 -1.50000 H23C 2 0.273016 0.545705 0.384594 11.00000 -1.50000 AFIX 0 C24 1 0.114400 0.795541 -0.055273 11.00000 0.09576 0.05603 = 0.06461 0.01812 -0.00014 0.01006 AFIX 137 H24A 2 0.203757 0.767218 -0.085954 11.00000 -1.50000 H24B 2 0.139458 0.854064 -0.055432 11.00000 -1.50000 H24C 2 -0.004429 0.785823 -0.076446 11.00000 -1.50000 AFIX 0 C25 1 0.120951 0.765146 0.021903 11.00000 0.11780 0.06861 = 0.06068 -0.00025 -0.03813 -0.02989 C26 1 0.845383 0.487516 -0.014496 11.00000 0.07427 0.09878 = 0.06283 0.00211 0.02783 -0.01157 AFIX 137 H26A 2 0.973237 0.499725 -0.015130 11.00000 -1.50000 H26B 2 0.779442 0.532979 -0.036933 11.00000 -1.50000 H26C 2 0.822819 0.437918 -0.043735 11.00000 -1.50000 AFIX 0 HKLF 4 REM AR1 in P2(1)2(1)2(1) REM R1 = 0.0608 for 1403 Fo > 4sig(Fo) and 0.0841 for all 1742 data REM 286 parameters refined using 0 restraints END WGHT 0.0676 2.3387 REM Highest difference peak 0.194, deepest hole -0.304, 1-sigma level 0.054 Q1 1 0.4662 0.4406 0.1618 11.00000 0.05 0.19 Q2 1 0.3867 0.3650 0.0814 11.00000 0.05 0.19 Q3 1 0.6037 0.5562 0.2013 11.00000 0.05 0.17 Q4 1 0.7149 0.4002 0.3799 11.00000 0.05 0.17 Q5 1 0.0901 0.7282 0.0962 11.00000 0.05 0.17 Q6 1 0.7933 0.6242 -0.0197 11.00000 0.05 0.17 Q7 1 0.3982 0.4062 0.2731 11.00000 0.05 0.16 Q8 1 0.3674 0.4437 0.2149 11.00000 0.05 0.16 Q9 1 -0.0881 0.7023 0.2399 11.00000 0.05 0.16 Q10 1 0.3285 0.4905 0.1541 11.00000 0.05 0.16 Q11 1 -0.0711 0.6376 0.0051 11.00000 0.05 0.16 Q12 1 0.0226 0.6279 -0.0194 11.00000 0.05 0.16 Q13 1 -0.0447 0.6512 -0.0205 11.00000 0.05 0.15 Q14 1 0.5875 0.3029 0.1744 11.00000 0.05 0.15 Q15 1 0.2068 0.7241 0.1102 11.00000 0.05 0.15 Q16 1 0.2981 0.4780 0.0272 11.00000 0.05 0.15 Q17 1 0.2308 0.2374 0.1898 11.00000 0.05 0.15 Q18 1 0.5966 0.4198 -0.0194 11.00000 0.05 0.15 Q19 1 0.0054 0.7439 -0.1397 11.00000 0.05 0.15 Q20 1 0.7054 0.2545 0.3433 11.00000 0.05 0.15 ; _shelx_res_checksum 60041 _shelx_hkl_file ; 1 0 0 -0.08 1.74 0 2 0 0 1911.48 14.59 0 3 0 0 -0.61 2.64 0 5 0 0 35.22 5.04 0 6 0 0 -1.61 3.99 0 7 0 0 -3.80 4.33 0 8 0 0 -45.18 6.10 0 0 1 0 4.71 0.91 0 1 1 0 2219.86 11.47 0 2 1 0 2648.72 17.28 0 3 1 0 872.59 12.62 0 4 1 0 120.88 6.33 0 5 1 0 10.45 4.23 0 6 1 0 -0.45 4.73 0 7 1 0 28.93 6.29 0 8 1 0 2.65 3.66 0 0 2 0 1523.52 8.91 0 1 2 0 9844.74 31.99 0 2 2 0 1164.44 11.99 0 3 2 0 16.97 3.12 0 4 2 0 933.42 16.27 0 5 2 0 214.92 9.81 0 6 2 0 11.55 5.49 0 7 2 0 14.40 5.82 0 8 2 0 29.16 5.20 0 0 3 0 -1.23 2.09 0 1 3 0 144.04 4.16 0 2 3 0 8.47 2.40 0 3 3 0 1377.70 16.75 0 4 3 0 19.78 3.44 0 5 3 0 126.10 7.81 0 6 3 0 27.20 5.77 0 7 3 0 19.42 5.71 0 8 3 0 -2.84 3.89 0 0 4 0 9999.00 37.76 0 1 4 0 1298.47 12.37 0 2 4 0 1072.11 13.06 0 3 4 0 20.42 3.29 0 4 4 0 38.88 4.68 0 5 4 0 30.72 5.13 0 6 4 0 32.22 6.27 0 7 4 0 21.04 5.66 0 8 4 0 -5.95 3.46 0 0 5 0 7.62 2.60 0 1 5 0 166.65 5.47 0 2 5 0 152.95 5.77 0 3 5 0 292.12 8.89 0 4 5 0 1553.83 22.77 0 5 5 0 170.86 9.67 0 6 5 0 28.71 5.85 0 7 5 0 45.18 6.18 0 0 6 0 2205.88 19.18 0 1 6 0 173.29 5.97 0 2 6 0 273.90 7.89 0 3 6 0 14.62 3.57 0 4 6 0 5.95 3.63 0 5 6 0 30.61 5.74 0 6 6 0 132.72 9.56 0 7 6 0 -4.83 4.67 0 0 7 0 -3.22 2.60 0 1 7 0 7.47 2.76 0 2 7 0 696.68 13.29 0 3 7 0 227.84 8.76 0 4 7 0 88.41 7.00 0 5 7 0 707.23 19.31 0 6 7 0 36.15 6.74 0 7 7 0 6.82 4.82 0 0 8 0 43.60 4.07 0 1 8 0 473.95 11.20 0 2 8 0 136.99 6.86 0 3 8 0 17.42 4.46 0 4 8 0 174.35 9.55 0 5 8 0 209.90 11.13 0 6 8 0 0.61 4.68 0 0 9 0 3.33 3.15 0 1 9 0 245.37 9.09 0 2 9 0 2.87 3.27 0 3 9 0 102.69 7.38 0 4 9 0 79.27 6.84 0 5 9 0 11.83 5.49 0 6 9 0 43.98 6.83 0 7 9 0 4.14 3.70 0 0 10 0 352.51 11.26 0 1 10 0 210.16 9.37 0 2 10 0 44.00 5.26 0 3 10 0 -2.28 4.10 0 4 10 0 138.03 9.18 0 5 10 0 31.72 6.14 0 6 10 0 -2.37 4.50 0 0 11 0 8.49 3.62 0 1 11 0 9.77 4.09 0 2 11 0 262.44 11.28 0 3 11 0 0.89 4.28 0 4 11 0 -15.61 4.47 0 5 11 0 17.09 5.39 0 6 11 0 -3.19 4.87 0 0 12 0 86.26 7.34 0 1 12 0 731.19 18.62 0 2 12 0 19.83 5.25 0 3 12 0 160.19 9.89 0 4 12 0 110.86 8.69 0 5 12 0 7.70 4.80 0 6 12 0 18.27 4.09 0 0 13 0 2.41 4.53 0 1 13 0 119.86 8.90 0 2 13 0 -2.41 4.83 0 3 13 0 95.49 8.91 0 5 13 0 3.57 4.43 0 0 14 0 220.03 11.90 0 1 14 0 524.40 17.52 0 2 14 0 -5.37 4.12 0 3 14 0 145.01 9.99 0 4 14 0 21.81 4.53 0 5 14 0 6.07 3.48 0 0 15 0 5.23 4.70 0 1 15 0 11.54 4.71 0 2 15 0 20.89 5.48 0 3 15 0 21.79 4.85 0 4 15 0 11.44 3.97 0 0 16 0 295.98 13.26 0 1 16 0 18.81 5.18 0 2 16 0 16.84 4.46 0 3 16 0 9.49 4.40 0 0 17 0 2.44 4.47 0 1 17 0 25.74 5.05 0 2 17 0 7.78 3.95 0 0 18 0 8.23 4.09 0 0 0 1 7.47 0.89 0 1 0 1 5879.28 22.24 0 2 0 1 3798.81 21.25 0 3 0 1 14.27 2.87 0 4 0 1 1319.10 19.51 0 5 0 1 495.05 14.61 0 8 0 1 6.81 4.06 0 0 1 1 306.15 3.33 0 1 1 1 414.58 5.36 0 2 1 1 3385.42 20.11 0 3 1 1 404.33 8.83 0 4 1 1 186.46 7.54 0 5 1 1 19.18 4.41 0 6 1 1 74.67 7.67 0 7 1 1 28.98 5.93 0 8 1 1 3.60 4.57 0 0 2 1 3374.80 14.61 0 1 2 1 944.94 8.59 0 2 2 1 4209.91 23.11 0 3 2 1 754.22 12.04 0 4 2 1 465.91 11.73 0 5 2 1 133.38 8.09 0 6 2 1 15.48 4.88 0 7 2 1 65.54 7.25 0 8 2 1 0.65 3.96 0 0 3 1 1086.55 9.40 0 1 3 1 1135.39 10.49 0 2 3 1 806.90 10.76 0 3 3 1 20.36 3.26 0 4 3 1 32.60 4.08 0 5 3 1 93.26 7.09 0 6 3 1 63.28 7.16 0 7 3 1 53.55 7.21 0 8 3 1 0.03 4.02 0 0 4 1 250.39 5.52 0 1 4 1 3611.95 21.08 0 2 4 1 1760.66 16.84 0 3 4 1 624.45 11.94 0 4 4 1 219.83 8.83 0 5 4 1 122.25 8.16 0 6 4 1 192.55 11.49 0 7 4 1 -0.51 4.50 0 8 4 1 13.40 4.41 0 0 5 1 4426.84 25.00 0 1 5 1 109.40 4.66 0 2 5 1 1114.88 14.36 0 3 5 1 771.83 13.93 0 4 5 1 136.27 7.34 0 5 5 1 264.75 11.39 0 6 5 1 18.40 5.34 0 7 5 1 10.33 4.96 0 0 6 1 0.74 2.70 0 1 6 1 576.67 10.23 0 2 6 1 136.85 5.81 0 3 6 1 245.94 8.68 0 4 6 1 203.44 9.25 0 5 6 1 137.83 9.00 0 6 6 1 7.25 5.42 0 7 6 1 39.68 6.32 0 0 7 1 154.58 6.19 0 1 7 1 1378.56 17.27 0 2 7 1 974.53 15.65 0 3 7 1 104.45 6.59 0 4 7 1 324.35 11.85 0 5 7 1 215.06 10.81 0 6 7 1 61.27 7.48 0 7 7 1 10.17 4.62 0 0 8 1 16.25 3.44 0 1 8 1 588.33 12.42 0 2 8 1 331.51 10.06 0 3 8 1 135.49 7.43 0 4 8 1 61.52 6.29 0 5 8 1 57.86 6.69 0 6 8 1 29.91 6.23 0 7 8 1 8.57 4.47 0 0 9 1 820.81 15.56 0 1 9 1 278.54 9.62 0 2 9 1 307.73 10.50 0 3 9 1 36.00 5.56 0 4 9 1 47.13 6.30 0 5 9 1 202.32 11.59 0 6 9 1 -1.09 4.60 0 7 9 1 1.09 3.93 0 0 10 1 15.67 3.80 0 1 10 1 118.70 7.27 0 2 10 1 122.65 7.81 0 3 10 1 91.61 7.26 0 4 10 1 16.26 5.29 0 5 10 1 69.10 7.64 0 6 10 1 11.28 4.75 0 0 11 1 65.44 6.35 0 1 11 1 176.84 9.27 0 2 11 1 62.43 6.49 0 3 11 1 -1.82 4.34 0 4 11 1 9.93 5.66 0 5 11 1 37.61 6.51 0 6 11 1 1.25 4.03 0 0 12 1 297.88 12.17 0 1 12 1 15.22 5.01 0 2 12 1 163.39 9.52 0 3 12 1 89.17 8.54 0 4 12 1 92.01 7.87 0 5 12 1 6.92 4.59 0 6 12 1 -2.36 3.94 0 0 13 1 -8.07 4.55 0 1 13 1 0.83 4.42 0 2 13 1 212.27 11.26 0 3 13 1 6.08 5.27 0 4 13 1 -5.78 4.61 0 5 13 1 8.33 4.63 0 0 14 1 442.37 16.07 0 1 14 1 252.15 12.72 0 2 14 1 -9.19 4.81 0 4 14 1 6.58 4.17 0 5 14 1 18.49 4.09 0 0 15 1 20.96 5.45 0 1 15 1 50.61 6.56 0 2 15 1 20.86 5.22 0 3 15 1 16.38 4.52 0 4 15 1 23.88 4.84 0 0 16 1 10.37 4.62 0 1 16 1 37.27 5.78 0 2 16 1 10.25 4.52 0 3 16 1 28.35 5.12 0 0 17 1 8.83 5.08 0 1 17 1 12.41 4.38 0 2 17 1 17.20 4.28 0 0 18 1 2.85 3.88 0 0 0 2 5636.64 28.39 0 1 0 2 34.88 2.49 0 2 0 2 159.97 4.92 0 3 0 2 452.30 9.41 0 4 0 2 94.22 5.71 0 5 0 2 96.42 7.11 0 6 0 2 33.22 5.54 0 7 0 2 -0.22 4.48 0 8 0 2 33.00 6.34 0 0 1 2 6414.78 32.18 0 1 1 2 6790.37 25.87 0 2 1 2 1329.46 12.94 0 3 1 2 73.89 4.46 0 4 1 2 168.26 7.38 0 5 1 2 128.20 7.95 0 6 1 2 114.94 9.00 0 7 1 2 9.98 5.12 0 8 1 2 28.15 5.41 0 0 2 2 1943.57 11.73 0 1 2 2 1584.96 11.82 0 2 2 2 224.50 5.91 0 3 2 2 586.82 10.97 0 4 2 2 133.00 6.86 0 5 2 2 47.25 5.53 0 6 2 2 20.14 5.66 0 7 2 2 4.78 4.91 0 8 2 2 25.75 4.80 0 0 3 2 453.74 6.57 0 1 3 2 1084.07 10.76 0 2 3 2 1389.28 14.36 0 3 3 2 174.84 6.52 0 4 3 2 140.45 7.15 0 5 3 2 153.08 8.80 0 6 3 2 52.38 7.00 0 7 3 2 49.40 6.96 0 8 3 2 6.79 3.67 0 0 4 2 557.22 8.21 0 1 4 2 3346.71 20.92 0 2 4 2 237.41 6.72 0 3 4 2 422.66 10.07 0 4 4 2 336.15 10.74 0 5 4 2 26.12 5.09 0 6 4 2 10.83 5.37 0 7 4 2 32.33 6.37 0 0 5 2 360.28 7.47 0 1 5 2 2007.72 17.65 0 2 5 2 1348.45 16.09 0 3 5 2 1447.25 19.18 0 4 5 2 108.05 6.94 0 5 5 2 183.98 10.05 0 6 5 2 201.53 11.63 0 7 5 2 4.22 4.18 0 0 6 2 1535.75 16.41 0 1 6 2 166.48 6.02 0 2 6 2 83.32 4.94 0 3 6 2 1384.83 19.92 0 4 6 2 352.55 11.92 0 5 6 2 6.82 4.46 0 6 6 2 58.16 7.48 0 7 6 2 7.32 4.41 0 0 7 2 285.11 8.04 0 1 7 2 438.86 10.02 0 2 7 2 278.69 8.75 0 3 7 2 219.64 8.67 0 4 7 2 33.99 4.79 0 5 7 2 389.11 14.66 0 6 7 2 63.39 8.00 0 7 7 2 14.16 4.30 0 0 8 2 1312.38 18.25 0 1 8 2 421.77 10.84 0 2 8 2 829.52 15.71 0 3 8 2 77.49 6.23 0 4 8 2 133.88 8.70 0 5 8 2 45.73 6.61 0 6 8 2 36.64 6.34 0 7 8 2 23.60 4.75 0 0 9 2 1082.38 18.04 0 1 9 2 1.73 3.34 0 2 9 2 21.18 4.24 0 3 9 2 185.20 9.28 0 4 9 2 293.84 12.31 0 5 9 2 38.87 6.49 0 6 9 2 23.61 5.44 0 7 9 2 47.44 5.88 0 0 10 2 8.01 3.71 0 1 10 2 193.73 9.01 0 2 10 2 6.60 3.66 0 3 10 2 108.53 8.00 0 4 10 2 226.79 11.71 0 5 10 2 24.49 5.49 0 6 10 2 11.39 5.05 0 0 11 2 422.31 13.67 0 1 11 2 290.28 11.49 0 2 11 2 19.94 4.67 0 3 11 2 147.01 9.27 0 4 11 2 -12.12 4.71 0 5 11 2 2.22 4.39 0 6 11 2 7.31 3.97 0 0 12 2 55.27 6.42 0 1 12 2 155.98 9.16 0 2 12 2 53.56 6.41 0 3 12 2 311.91 13.51 0 4 12 2 115.01 9.23 0 5 12 2 12.43 5.02 0 6 12 2 13.27 3.74 0 0 13 2 6.24 4.96 0 1 13 2 213.57 11.62 0 2 13 2 122.83 9.26 0 3 13 2 116.58 9.17 0 4 13 2 73.12 7.60 0 5 13 2 6.67 4.11 0 0 14 2 91.00 8.31 0 1 14 2 88.83 8.35 0 2 14 2 9.49 5.45 0 3 14 2 51.55 6.66 0 4 14 2 14.69 5.45 0 5 14 2 6.79 3.66 0 0 15 2 25.26 5.18 0 1 15 2 30.99 6.06 0 2 15 2 57.78 6.98 0 3 15 2 -0.54 3.98 0 4 15 2 23.97 4.74 0 0 16 2 5.79 4.29 0 1 16 2 13.07 4.38 0 2 16 2 3.68 4.43 0 3 16 2 -0.63 3.79 0 0 17 2 0.36 3.89 0 1 17 2 10.22 4.92 0 2 17 2 51.26 5.47 0 0 0 3 -2.38 2.07 0 1 0 3 1834.53 12.85 0 2 0 3 515.13 8.55 0 3 0 3 298.20 8.02 0 4 0 3 5.29 3.06 0 5 0 3 1.01 3.48 0 6 0 3 21.75 5.08 0 7 0 3 -7.11 5.15 0 8 0 3 0.22 3.92 0 0 1 3 1379.89 10.26 0 1 1 3 3781.97 19.25 0 2 1 3 48.49 3.36 0 3 1 3 2105.35 20.69 0 4 1 3 549.31 12.81 0 5 1 3 13.76 4.45 0 6 1 3 234.77 12.01 0 7 1 3 -1.26 4.65 0 8 1 3 5.52 4.02 0 0 2 3 1109.36 9.95 0 1 2 3 55.70 3.24 0 2 2 3 496.19 8.66 0 3 2 3 369.16 8.98 0 4 2 3 412.42 11.47 0 5 2 3 52.16 6.01 0 6 2 3 93.23 8.19 0 7 2 3 22.03 5.69 0 8 2 3 2.03 4.32 0 0 3 3 2576.84 16.71 0 1 3 3 1641.04 14.02 0 2 3 3 510.05 9.20 0 3 3 3 1080.28 15.53 0 4 3 3 33.90 4.31 0 5 3 3 54.36 5.64 0 6 3 3 81.24 7.87 0 7 3 3 82.10 8.12 0 8 3 3 -0.66 3.71 0 0 4 3 2877.10 19.41 0 1 4 3 333.49 7.13 0 2 4 3 173.30 6.02 0 3 4 3 598.05 12.37 0 4 4 3 371.22 11.33 0 5 4 3 117.00 8.01 0 6 4 3 171.32 10.86 0 7 4 3 25.01 5.63 0 0 5 3 29.66 3.25 0 1 5 3 2813.99 21.73 0 2 5 3 1835.19 19.36 0 3 5 3 244.44 8.42 0 4 5 3 416.47 12.44 0 5 5 3 32.89 5.33 0 6 5 3 69.96 8.21 0 7 5 3 61.81 7.07 0 0 6 3 103.80 5.06 0 1 6 3 1062.82 14.53 0 2 6 3 78.78 4.97 0 3 6 3 172.65 7.80 0 4 6 3 12.12 3.73 0 5 6 3 191.78 10.50 0 6 6 3 38.78 6.57 0 7 6 3 76.11 7.34 0 0 7 3 233.31 7.71 0 1 7 3 705.45 12.88 0 2 7 3 556.34 12.28 0 3 7 3 313.17 10.51 0 4 7 3 112.62 7.57 0 5 7 3 150.62 9.68 0 6 7 3 4.18 4.53 0 7 7 3 30.61 5.88 0 0 8 3 10.60 3.34 0 1 8 3 195.38 7.77 0 2 8 3 252.90 9.09 0 3 8 3 130.08 7.55 0 4 8 3 22.97 5.04 0 5 8 3 53.28 7.34 0 6 8 3 76.54 8.21 0 7 8 3 21.37 4.46 0 0 9 3 322.34 10.37 0 1 9 3 0.46 3.11 0 2 9 3 207.93 9.13 0 3 9 3 34.92 5.04 0 4 9 3 227.10 11.16 0 5 9 3 109.72 8.96 0 6 9 3 34.70 6.02 0 7 9 3 8.90 3.95 0 0 10 3 207.10 9.33 0 1 10 3 99.23 7.20 0 2 10 3 79.08 6.40 0 3 10 3 100.99 7.95 0 4 10 3 106.03 8.34 0 5 10 3 33.58 6.16 0 6 10 3 53.42 6.91 0 0 11 3 35.04 5.05 0 1 11 3 31.47 5.42 0 2 11 3 115.62 8.02 0 3 11 3 75.40 7.66 0 4 11 3 35.77 6.60 0 5 11 3 18.19 5.30 0 6 11 3 6.93 4.05 0 0 12 3 147.92 9.26 0 1 12 3 97.26 7.84 0 2 12 3 -15.24 4.13 0 3 12 3 264.79 12.61 0 4 12 3 3.58 4.90 0 5 12 3 4.32 4.67 0 6 12 3 9.21 4.13 0 0 13 3 99.25 8.33 0 1 13 3 60.68 7.29 0 2 13 3 180.78 10.64 0 3 13 3 96.00 8.57 0 4 13 3 10.71 4.86 0 5 13 3 0.00 3.74 0 0 14 3 12.95 5.35 0 1 14 3 81.64 8.08 0 2 14 3 24.80 6.61 0 3 14 3 56.51 6.81 0 4 14 3 0.19 4.42 0 5 14 3 16.64 4.25 0 0 15 3 113.25 8.95 0 1 15 3 7.25 5.24 0 2 15 3 123.45 9.01 0 3 15 3 64.13 6.83 0 4 15 3 -0.38 3.40 0 0 16 3 178.40 10.32 0 1 16 3 17.92 5.29 0 2 16 3 23.47 5.12 0 3 16 3 7.90 4.69 0 0 17 3 -1.21 3.90 0 1 17 3 44.19 5.73 0 2 17 3 25.25 4.74 0 0 0 4 5598.85 24.58 0 1 0 4 237.36 5.52 0 2 0 4 917.24 11.88 0 3 0 4 167.39 6.57 0 4 0 4 95.89 6.07 0 5 0 4 27.16 4.95 0 6 0 4 285.27 13.11 0 7 0 4 12.92 4.65 0 8 0 4 9.61 4.19 0 0 1 4 286.46 5.66 0 1 1 4 777.07 9.41 0 2 1 4 1271.41 14.18 0 3 1 4 426.63 9.90 0 4 1 4 281.94 9.60 0 5 1 4 31.30 5.29 0 6 1 4 18.74 5.46 0 7 1 4 20.28 5.45 0 8 1 4 5.90 4.04 0 0 2 4 19.93 2.92 0 1 2 4 508.42 8.11 0 2 2 4 1165.25 13.77 0 3 2 4 31.47 3.69 0 4 2 4 30.17 4.15 0 5 2 4 15.76 4.68 0 6 2 4 65.67 7.58 0 7 2 4 7.44 5.06 0 8 2 4 7.91 4.07 0 0 3 4 339.30 6.81 0 1 3 4 444.64 8.16 0 2 3 4 183.68 6.09 0 3 3 4 287.40 8.60 0 4 3 4 684.14 15.07 0 5 3 4 17.88 5.23 0 6 3 4 7.10 5.01 0 7 3 4 25.41 6.03 0 0 4 4 1308.86 13.89 0 1 4 4 286.05 7.03 0 2 4 4 1913.51 19.38 0 3 4 4 137.53 6.41 0 4 4 4 112.45 6.90 0 5 4 4 63.94 6.50 0 6 4 4 131.15 9.57 0 7 4 4 2.37 4.58 0 0 5 4 37.35 3.46 0 1 5 4 338.88 8.11 0 2 5 4 2083.67 21.44 0 3 5 4 314.87 9.81 0 4 5 4 42.61 5.12 0 5 5 4 16.35 4.94 0 6 5 4 51.05 6.68 0 7 5 4 50.15 6.75 0 0 6 4 384.68 9.07 0 1 6 4 178.83 6.59 0 2 6 4 43.25 4.11 0 3 6 4 163.73 7.78 0 4 6 4 48.39 5.92 0 5 6 4 210.34 11.01 0 6 6 4 67.35 7.52 0 7 6 4 41.35 6.31 0 0 7 4 47.07 4.28 0 1 7 4 840.55 14.60 0 2 7 4 74.77 5.45 0 3 7 4 160.73 8.01 0 4 7 4 11.93 4.74 0 5 7 4 85.21 8.27 0 6 7 4 35.77 6.58 0 7 7 4 12.19 4.42 0 0 8 4 1.47 2.83 0 1 8 4 53.78 4.87 0 2 8 4 301.24 10.19 0 3 8 4 76.54 6.49 0 4 8 4 65.92 6.55 0 5 8 4 282.26 13.22 0 6 8 4 58.23 7.22 0 7 8 4 19.85 4.45 0 0 9 4 81.04 6.07 0 1 9 4 276.22 10.19 0 2 9 4 -2.30 3.13 0 3 9 4 49.80 5.73 0 4 9 4 47.11 6.41 0 5 9 4 195.09 11.09 0 6 9 4 37.98 6.38 0 0 10 4 149.18 8.22 0 1 10 4 289.63 11.22 0 2 10 4 72.03 6.37 0 3 10 4 42.71 5.88 0 4 10 4 10.08 5.08 0 5 10 4 47.22 6.38 0 6 10 4 27.60 5.45 0 0 11 4 19.91 4.78 0 1 11 4 33.06 5.28 0 2 11 4 126.75 8.44 0 3 11 4 14.15 5.05 0 4 11 4 16.42 5.09 0 5 11 4 -3.43 4.33 0 6 11 4 8.10 4.03 0 0 12 4 5.13 4.50 0 1 12 4 58.17 6.85 0 2 12 4 2.83 4.61 0 3 12 4 13.95 6.11 0 4 12 4 48.73 6.74 0 5 12 4 59.11 6.63 0 0 13 4 -7.15 4.73 0 1 13 4 273.66 13.08 0 2 13 4 27.39 6.01 0 3 13 4 164.18 10.30 0 4 13 4 141.45 9.52 0 5 13 4 31.62 5.24 0 0 14 4 8.61 5.06 0 1 14 4 478.75 16.95 0 2 14 4 21.12 5.13 0 3 14 4 42.20 6.39 0 4 14 4 3.90 4.16 0 0 15 4 69.51 7.69 0 1 15 4 24.98 5.49 0 2 15 4 64.77 7.12 0 3 15 4 15.34 4.62 0 4 15 4 1.35 3.36 0 0 16 4 43.46 6.08 0 1 16 4 15.92 5.08 0 2 16 4 30.00 5.76 0 3 16 4 10.22 3.74 0 0 17 4 32.17 5.32 0 1 17 4 35.96 5.26 0 2 17 4 10.23 3.72 0 0 0 5 1.87 2.34 0 1 0 5 147.56 5.00 0 2 0 5 2.86 2.74 0 3 0 5 402.34 9.93 0 4 0 5 4.30 3.03 0 5 0 5 6.62 3.94 0 6 0 5 20.51 5.83 0 7 0 5 214.52 11.91 0 0 1 5 3.74 2.36 0 1 1 5 456.15 8.12 0 2 1 5 171.78 5.91 0 3 1 5 227.74 7.71 0 4 1 5 115.57 6.77 0 5 1 5 37.13 5.30 0 6 1 5 21.20 5.29 0 7 1 5 35.22 5.88 0 0 2 5 47.96 3.43 0 1 2 5 416.25 8.05 0 2 2 5 18.41 2.96 0 3 2 5 370.21 9.78 0 4 2 5 10.13 3.48 0 5 2 5 168.53 9.47 0 6 2 5 75.56 7.99 0 7 2 5 80.67 8.11 0 0 3 5 0.80 2.44 0 1 3 5 482.54 8.97 0 2 3 5 4.52 2.53 0 3 3 5 78.93 5.32 0 4 3 5 2.62 3.48 0 5 3 5 21.89 5.36 0 6 3 5 80.44 7.96 0 7 3 5 50.65 6.94 0 0 4 5 5.04 2.63 0 1 4 5 610.45 10.60 0 2 4 5 127.12 5.85 0 3 4 5 203.28 8.09 0 4 4 5 95.59 6.98 0 5 4 5 31.80 5.60 0 6 4 5 121.97 9.58 0 7 4 5 58.42 7.55 0 0 5 5 7.30 2.73 0 1 5 5 583.11 11.06 0 2 5 5 1061.49 16.02 0 3 5 5 158.42 7.53 0 4 5 5 374.13 12.38 0 5 5 5 107.42 8.55 0 6 5 5 81.71 8.17 0 7 5 5 34.77 6.08 0 0 6 5 703.84 12.76 0 1 6 5 262.09 8.17 0 2 6 5 838.57 15.12 0 3 6 5 9.54 3.87 0 4 6 5 258.21 10.71 0 5 6 5 0.89 4.51 0 6 6 5 10.23 5.48 0 7 6 5 -5.35 3.98 0 0 7 5 55.74 4.71 0 1 7 5 328.27 9.70 0 2 7 5 192.28 8.05 0 3 7 5 458.82 13.31 0 4 7 5 38.65 5.37 0 5 7 5 69.55 7.29 0 6 7 5 25.67 5.90 0 7 7 5 -11.68 3.42 0 0 8 5 502.42 12.58 0 1 8 5 32.48 4.25 0 2 8 5 31.45 4.61 0 3 8 5 96.91 7.33 0 4 8 5 9.41 4.67 0 5 8 5 59.46 7.36 0 6 8 5 90.50 8.55 0 7 8 5 3.68 3.52 0 0 9 5 448.58 12.80 0 1 9 5 53.71 5.72 0 2 9 5 140.09 8.22 0 3 9 5 312.04 12.33 0 4 9 5 233.49 11.55 0 5 9 5 33.28 6.57 0 6 9 5 43.26 6.43 0 0 10 5 2.51 3.55 0 1 10 5 234.84 10.10 0 2 10 5 283.92 11.60 0 3 10 5 116.77 8.47 0 4 10 5 9.83 4.77 0 5 10 5 76.97 7.28 0 0 11 5 252.24 11.19 0 1 11 5 108.95 8.35 0 2 11 5 91.43 7.61 0 3 11 5 44.97 7.14 0 4 11 5 40.67 6.55 0 5 11 5 66.61 7.10 0 6 11 5 5.69 4.09 0 0 12 5 16.56 5.13 0 1 12 5 48.04 6.72 0 2 12 5 114.04 9.17 0 3 12 5 43.57 6.54 0 4 12 5 26.55 6.16 0 5 12 5 0.47 4.18 0 0 13 5 57.64 7.37 0 1 13 5 88.11 7.94 0 2 13 5 69.47 7.68 0 3 13 5 174.50 10.91 0 4 13 5 4.15 4.82 0 5 13 5 8.18 3.70 0 0 14 5 117.46 9.92 0 1 14 5 36.62 6.46 0 2 14 5 65.29 7.76 0 3 14 5 12.50 5.09 0 4 14 5 14.52 4.48 0 0 15 5 4.14 5.22 0 2 15 5 8.81 4.86 0 3 15 5 6.37 4.34 0 4 15 5 3.97 3.56 0 0 16 5 11.78 4.68 0 1 16 5 9.45 4.57 0 2 16 5 26.02 4.74 0 3 16 5 -1.54 3.43 0 0 17 5 1.77 3.99 0 1 17 5 6.46 3.64 0 0 0 6 514.41 9.08 0 1 0 6 139.44 5.19 0 2 0 6 440.37 9.56 0 3 0 6 1002.14 16.27 0 4 0 6 76.26 6.17 0 5 0 6 38.76 5.61 0 6 0 6 23.06 5.60 0 7 0 6 68.03 7.38 0 0 1 6 57.59 3.79 0 1 1 6 5.65 2.55 0 2 1 6 339.77 8.57 0 3 1 6 583.94 12.55 0 4 1 6 130.05 7.46 0 5 1 6 26.05 5.34 0 6 1 6 117.94 9.37 0 7 1 6 14.11 5.34 0 0 2 6 76.57 4.30 0 1 2 6 820.12 12.01 0 2 2 6 1.38 2.42 0 3 2 6 307.01 9.40 0 4 2 6 15.25 3.94 0 5 2 6 3.90 4.65 0 6 2 6 45.11 7.03 0 7 2 6 36.47 6.64 0 0 3 6 11.36 3.11 0 1 3 6 210.44 6.64 0 2 3 6 118.92 5.63 0 3 3 6 108.71 6.16 0 4 3 6 3.43 4.21 0 5 3 6 104.17 7.93 0 6 3 6 31.79 6.66 0 7 3 6 -2.33 4.65 0 0 4 6 174.09 6.42 0 1 4 6 216.95 7.15 0 2 4 6 86.61 5.33 0 3 4 6 359.77 10.84 0 4 4 6 306.39 11.38 0 5 4 6 80.97 7.78 0 6 4 6 40.32 6.72 0 7 4 6 22.21 5.11 0 0 5 6 237.58 7.61 0 1 5 6 524.40 11.17 0 2 5 6 282.77 8.99 0 3 5 6 36.38 4.68 0 4 5 6 252.58 10.71 0 5 5 6 174.82 10.68 0 6 5 6 241.48 12.44 0 7 5 6 25.11 5.00 0 0 6 6 -7.04 3.04 0 1 6 6 524.44 11.94 0 2 6 6 231.62 8.59 0 3 6 6 150.75 7.92 0 4 6 6 23.19 5.27 0 5 6 6 14.07 5.08 0 6 6 6 4.94 5.33 0 7 6 6 14.37 4.39 0 0 7 6 416.68 11.23 0 1 7 6 282.03 9.61 0 2 7 6 110.79 6.90 0 3 7 6 22.15 4.18 0 4 7 6 118.53 8.67 0 5 7 6 234.03 11.96 0 6 7 6 4.82 5.15 0 7 7 6 9.48 3.95 0 0 8 6 5.56 3.21 0 1 8 6 331.56 10.88 0 2 8 6 620.29 15.24 0 3 8 6 184.70 9.56 0 4 8 6 17.98 5.19 0 5 8 6 36.72 7.09 0 6 8 6 -0.88 4.45 0 0 9 6 388.86 12.60 0 1 9 6 14.98 4.06 0 2 9 6 27.33 4.92 0 3 9 6 192.55 10.07 0 4 9 6 65.55 7.30 0 5 9 6 83.60 8.28 0 6 9 6 18.61 5.27 0 0 10 6 87.95 7.22 0 1 10 6 71.51 6.73 0 2 10 6 63.97 6.94 0 3 10 6 -5.71 4.16 0 4 10 6 266.06 12.79 0 5 10 6 24.66 5.61 0 6 10 6 18.11 4.76 0 0 11 6 61.51 6.72 0 1 11 6 32.26 5.90 0 2 11 6 119.73 8.79 0 3 11 6 169.42 10.47 0 4 11 6 66.05 7.88 0 5 11 6 3.20 4.94 0 6 11 6 15.19 4.15 0 0 12 6 60.49 6.97 0 1 12 6 17.77 5.70 0 2 12 6 191.31 11.00 0 3 12 6 107.97 8.87 0 4 12 6 81.66 7.76 0 5 12 6 2.01 3.91 0 0 13 6 125.03 9.42 0 1 13 6 185.01 10.99 0 2 13 6 124.21 9.11 0 3 13 6 17.16 5.73 0 4 13 6 -4.94 3.77 0 5 13 6 10.53 3.71 0 0 14 6 1.60 4.61 0 1 14 6 95.77 8.61 0 2 14 6 47.54 6.26 0 3 14 6 2.17 4.73 0 4 14 6 16.62 4.77 0 0 15 6 10.32 5.56 0 1 15 6 20.94 6.25 0 2 15 6 24.92 5.56 0 3 15 6 20.44 4.47 0 0 16 6 4.33 4.29 0 1 16 6 -5.46 4.00 0 2 16 6 10.47 4.42 0 0 17 6 11.54 3.68 0 1 17 6 -3.56 3.56 0 0 0 7 -4.01 2.44 0 1 0 7 278.85 7.67 0 2 0 7 671.00 12.54 0 3 0 7 14.80 3.39 0 4 0 7 190.34 9.11 0 5 0 7 -9.11 3.84 0 6 0 7 279.56 13.24 0 7 0 7 8.71 4.55 0 0 1 7 655.76 11.22 0 1 1 7 1069.38 14.42 0 2 1 7 13.22 3.09 0 3 1 7 86.40 5.81 0 4 1 7 42.66 5.36 0 5 1 7 143.45 9.33 0 6 1 7 60.43 7.52 0 7 1 7 40.20 6.13 0 0 2 7 601.64 11.00 0 1 2 7 1200.50 15.62 0 2 2 7 217.25 7.66 0 3 2 7 550.99 12.99 0 4 2 7 31.71 4.79 0 5 2 7 91.90 7.93 0 6 2 7 178.48 10.88 0 7 2 7 1.92 4.50 0 0 3 7 1284.39 16.43 0 1 3 7 538.80 10.96 0 2 3 7 378.02 10.18 0 3 3 7 297.60 10.23 0 4 3 7 38.20 5.23 0 5 3 7 121.79 9.26 0 6 3 7 26.73 5.96 0 7 3 7 12.38 5.18 0 0 4 7 1516.08 18.54 0 1 4 7 1502.67 18.84 0 2 4 7 90.05 5.65 0 3 4 7 38.61 4.79 0 4 4 7 180.43 9.47 0 5 4 7 55.04 6.56 0 6 4 7 188.63 11.36 0 7 4 7 11.95 4.48 0 0 5 7 7.47 3.09 0 1 5 7 17.65 3.72 0 2 5 7 728.62 14.86 0 3 5 7 16.04 4.19 0 4 5 7 30.14 4.96 0 5 5 7 189.62 11.00 0 6 5 7 70.82 7.73 0 7 5 7 6.18 4.46 0 0 6 7 78.65 5.40 0 1 6 7 141.38 6.95 0 2 6 7 218.00 8.92 0 3 6 7 361.16 12.20 0 4 6 7 103.10 8.20 0 5 6 7 101.53 8.50 0 6 6 7 17.44 4.96 0 7 6 7 11.71 4.64 0 0 7 7 -2.00 2.95 0 1 7 7 50.04 5.03 0 2 7 7 320.01 11.07 0 3 7 7 75.50 6.65 0 4 7 7 160.23 9.85 0 5 7 7 59.74 7.78 0 6 7 7 16.62 5.72 0 0 8 7 54.79 5.74 0 1 8 7 72.86 6.17 0 2 8 7 83.92 6.67 0 3 8 7 34.88 6.08 0 4 8 7 76.93 7.57 0 5 8 7 30.16 6.22 0 6 8 7 62.06 7.01 0 0 9 7 73.42 6.59 0 1 9 7 27.91 5.40 0 2 9 7 9.33 3.98 0 3 9 7 245.06 11.51 0 4 9 7 224.55 11.76 0 5 9 7 87.69 7.97 0 6 9 7 33.25 5.26 0 0 10 7 241.65 11.08 0 1 10 7 232.14 11.05 0 2 10 7 78.71 7.60 0 3 10 7 7.71 4.66 0 4 10 7 53.91 7.02 0 5 10 7 38.35 6.71 0 6 10 7 14.54 3.96 0 0 11 7 96.99 8.74 0 1 11 7 190.01 10.65 0 2 11 7 73.60 7.36 0 3 11 7 115.95 9.34 0 4 11 7 30.34 6.30 0 5 11 7 26.65 5.37 0 0 12 7 734.75 20.42 0 1 12 7 128.24 9.68 0 2 12 7 88.95 8.08 0 3 12 7 6.56 5.41 0 5 12 7 26.56 4.81 0 0 13 7 497.57 17.16 0 1 13 7 77.81 8.44 0 2 13 7 -0.21 5.13 0 3 13 7 20.27 5.67 0 4 13 7 23.74 4.66 0 0 14 7 18.83 5.12 0 1 14 7 78.22 7.99 0 2 14 7 12.74 4.58 0 3 14 7 8.22 4.78 0 4 14 7 9.94 4.11 0 0 15 7 16.09 4.63 0 1 15 7 1.03 4.66 0 2 15 7 12.69 4.68 0 3 15 7 26.95 4.97 0 0 16 7 -0.56 3.70 0 1 16 7 11.66 4.14 0 2 16 7 16.70 4.18 0 0 0 8 295.88 8.38 0 1 0 8 171.41 6.69 0 2 0 8 139.22 6.68 0 3 0 8 166.60 7.86 0 4 0 8 0.62 3.55 0 5 0 8 129.04 8.89 0 6 0 8 37.59 6.06 0 7 0 8 71.69 7.17 0 0 1 8 1586.97 19.03 0 1 1 8 1519.18 18.72 0 2 1 8 512.43 11.89 0 3 1 8 1.31 3.64 0 4 1 8 369.21 12.86 0 5 1 8 55.29 6.46 0 6 1 8 41.47 6.49 0 7 1 8 1.18 4.44 0 0 2 8 160.24 6.72 0 1 2 8 543.77 11.49 0 2 2 8 260.85 8.84 0 3 2 8 167.03 8.04 0 4 2 8 3.36 4.20 0 5 2 8 37.65 6.14 0 6 2 8 -0.95 4.93 0 7 2 8 41.46 5.73 0 0 3 8 202.82 7.43 0 1 3 8 201.88 7.50 0 2 3 8 50.85 4.65 0 3 3 8 204.60 8.78 0 4 3 8 285.69 11.52 0 5 3 8 -7.05 5.02 0 6 3 8 20.13 4.86 0 7 3 8 23.34 5.01 0 0 4 8 15.82 3.72 0 1 4 8 622.50 13.10 0 2 4 8 426.64 11.76 0 3 4 8 99.48 6.93 0 4 4 8 63.12 6.35 0 5 4 8 325.54 13.84 0 6 4 8 270.22 13.40 0 7 4 8 26.17 5.70 0 0 5 8 866.82 15.98 0 1 5 8 237.69 8.82 0 2 5 8 54.90 5.17 0 3 5 8 49.61 5.52 0 4 5 8 91.61 7.59 0 5 5 8 104.02 8.91 0 6 5 8 45.12 6.43 0 7 5 8 3.26 3.86 0 0 6 8 83.79 5.86 0 1 6 8 328.61 10.70 0 2 6 8 73.54 5.94 0 3 6 8 184.62 9.61 0 4 6 8 21.13 4.57 0 5 6 8 377.67 14.97 0 6 6 8 45.74 6.48 0 0 7 8 101.69 6.91 0 1 7 8 229.81 9.66 0 2 7 8 124.19 7.94 0 3 7 8 71.61 6.70 0 4 7 8 349.51 14.08 0 5 7 8 7.13 5.20 0 6 7 8 9.07 5.41 0 0 8 8 41.99 5.63 0 1 8 8 188.25 9.25 0 2 8 8 17.54 4.41 0 3 8 8 336.93 13.25 0 4 8 8 185.76 10.97 0 5 8 8 18.56 5.37 0 6 8 8 6.19 4.07 0 0 9 8 13.06 4.52 0 1 9 8 142.33 8.70 0 2 9 8 236.75 11.20 0 3 9 8 13.38 5.15 0 4 9 8 74.36 7.65 0 5 9 8 48.03 6.27 0 6 9 8 6.41 4.55 0 0 10 8 22.82 5.55 0 1 10 8 57.05 6.76 0 2 10 8 340.63 13.63 0 3 10 8 35.77 6.17 0 4 10 8 17.41 5.56 0 5 10 8 16.61 5.14 0 0 11 8 18.90 6.16 0 1 11 8 147.44 9.83 0 2 11 8 16.73 5.49 0 3 11 8 53.53 6.98 0 4 11 8 -0.90 4.38 0 5 11 8 7.06 4.23 0 0 12 8 12.90 5.19 0 1 12 8 57.02 7.37 0 2 12 8 110.53 9.25 0 3 12 8 100.13 8.55 0 4 12 8 25.14 5.07 0 5 12 8 12.12 4.21 0 0 13 8 9.07 5.38 0 1 13 8 50.17 7.22 0 2 13 8 124.60 9.02 0 3 13 8 41.14 6.11 0 4 13 8 15.49 4.58 0 0 14 8 -7.77 4.35 0 1 14 8 30.40 6.00 0 3 14 8 26.13 5.00 0 0 15 8 0.54 4.32 0 1 15 8 18.81 4.89 0 2 15 8 9.48 3.89 0 3 15 8 -0.32 3.33 0 0 16 8 1.63 3.71 0 1 16 8 -0.72 3.37 0 0 0 9 6.32 2.95 0 1 0 9 23.23 3.62 0 2 0 9 38.08 4.64 0 3 0 9 204.99 9.06 0 4 0 9 613.99 16.76 0 5 0 9 216.18 11.50 0 6 0 9 21.48 6.16 0 7 0 9 -4.16 3.88 0 0 1 9 145.89 6.87 0 1 1 9 1103.89 17.28 0 2 1 9 129.18 7.09 0 3 1 9 183.39 8.92 0 4 1 9 91.59 7.33 0 5 1 9 115.11 8.81 0 6 1 9 80.21 8.02 0 7 1 9 6.33 4.20 0 0 2 9 52.39 5.04 0 1 2 9 141.31 6.94 0 2 2 9 29.52 4.04 0 3 2 9 50.79 5.83 0 4 2 9 144.86 8.97 0 5 2 9 3.47 4.87 0 6 2 9 6.00 4.56 0 7 2 9 13.84 4.64 0 0 3 9 1360.71 19.86 0 1 3 9 131.83 6.80 0 2 3 9 14.67 3.73 0 3 3 9 467.03 13.66 0 4 3 9 308.36 12.56 0 5 3 9 9.93 4.65 0 6 3 9 20.66 5.48 0 7 3 9 31.30 5.58 0 0 4 9 169.01 7.76 0 1 4 9 56.85 5.16 0 2 4 9 180.17 8.38 0 3 4 9 24.79 4.72 0 4 4 9 295.77 12.78 0 5 4 9 38.13 6.36 0 6 4 9 7.59 5.30 0 7 4 9 34.11 5.33 0 0 5 9 196.23 8.60 0 1 5 9 153.22 7.73 0 2 5 9 105.23 6.97 0 3 5 9 17.55 4.91 0 4 5 9 14.04 4.90 0 5 5 9 -12.93 4.57 0 6 5 9 13.82 4.63 0 0 6 9 -8.05 3.19 0 1 6 9 19.51 4.20 0 2 6 9 277.11 10.84 0 3 6 9 37.17 5.48 0 4 6 9 24.59 5.64 0 5 6 9 144.41 9.54 0 6 6 9 -0.77 4.29 0 0 7 9 6.70 3.88 0 1 7 9 45.62 5.62 0 2 7 9 17.56 4.72 0 3 7 9 215.57 10.93 0 4 7 9 112.52 9.20 0 5 7 9 -3.77 4.57 0 6 7 9 10.45 5.01 0 0 8 9 485.09 14.86 0 1 8 9 278.29 11.65 0 2 8 9 50.46 6.64 0 3 8 9 45.51 6.44 0 4 8 9 79.82 8.15 0 5 8 9 61.09 6.89 0 6 8 9 14.18 4.14 0 0 9 9 209.13 10.63 0 1 9 9 17.43 5.52 0 2 9 9 31.35 6.43 0 3 9 9 430.53 15.72 0 4 9 9 46.88 7.37 0 5 9 9 14.19 5.58 0 6 9 9 -6.40 3.32 0 0 10 9 0.99 4.36 0 1 10 9 15.61 5.31 0 2 10 9 67.70 6.98 0 3 10 9 124.48 9.20 0 4 10 9 95.02 8.59 0 5 10 9 -13.61 4.60 0 0 11 9 6.48 5.30 0 1 11 9 186.40 10.97 0 2 11 9 91.46 8.55 0 3 11 9 75.05 7.80 0 4 11 9 12.47 5.12 0 5 11 9 55.53 5.93 0 0 12 9 394.69 15.41 0 1 12 9 31.71 5.65 0 2 12 9 11.98 5.29 0 3 12 9 50.61 6.19 0 4 12 9 4.46 4.56 0 0 13 9 362.29 14.63 0 1 13 9 94.03 8.45 0 2 13 9 44.95 6.60 0 3 13 9 31.30 5.54 0 4 13 9 23.87 4.49 0 0 14 9 12.67 4.99 0 2 14 9 33.47 5.29 0 3 14 9 5.11 3.77 0 0 15 9 10.92 4.31 0 1 15 9 13.94 4.67 0 2 15 9 6.68 3.78 0 0 16 9 -4.94 3.44 0 0 0 10 14.37 3.79 0 1 0 10 132.33 6.96 0 2 0 10 12.22 3.77 0 3 0 10 423.00 13.40 0 4 0 10 88.83 7.66 0 5 0 10 6.52 4.92 0 7 0 10 7.68 3.70 0 0 1 10 1728.51 23.17 0 1 1 10 9.75 3.72 0 2 1 10 294.33 10.58 0 3 1 10 111.38 7.75 0 4 1 10 126.10 8.65 0 5 1 10 90.13 8.37 0 6 1 10 -6.93 4.48 0 7 1 10 5.22 3.70 0 0 2 10 -2.33 3.59 0 1 2 10 104.86 6.56 0 2 2 10 52.04 5.29 0 3 2 10 34.49 5.37 0 4 2 10 5.41 4.36 0 5 2 10 18.87 5.44 0 6 2 10 -3.88 4.89 0 7 2 10 24.87 4.94 0 0 3 10 975.93 18.14 0 1 3 10 0.65 3.40 0 2 3 10 186.72 8.81 0 3 3 10 198.26 9.83 0 4 3 10 26.87 5.46 0 5 3 10 322.64 14.08 0 6 3 10 23.95 5.49 0 0 4 10 137.53 7.46 0 1 4 10 122.53 7.24 0 2 4 10 43.70 5.37 0 3 4 10 136.38 8.43 0 4 4 10 -5.82 4.53 0 5 4 10 95.77 8.97 0 6 4 10 9.84 4.84 0 0 5 10 577.70 15.13 0 1 5 10 124.88 7.68 0 2 5 10 22.77 4.39 0 3 5 10 42.54 5.95 0 4 5 10 136.49 9.47 0 5 5 10 275.78 12.72 0 6 5 10 5.56 4.11 0 0 6 10 67.03 6.70 0 1 6 10 395.73 13.28 0 2 6 10 36.85 5.65 0 3 6 10 139.75 9.14 0 4 6 10 81.00 7.97 0 5 6 10 50.57 6.83 0 6 6 10 1.94 3.82 0 0 7 10 181.64 9.57 0 1 7 10 164.67 9.46 0 2 7 10 19.77 5.27 0 3 7 10 5.05 4.32 0 4 7 10 223.28 11.95 0 0 8 10 204.19 10.65 0 1 8 10 40.84 5.76 0 2 8 10 98.29 8.05 0 3 8 10 67.82 7.41 0 4 8 10 235.70 12.10 0 5 8 10 18.87 5.37 0 6 8 10 11.88 4.66 0 0 9 10 92.59 8.32 0 1 9 10 36.45 5.92 0 2 9 10 40.00 6.32 0 3 9 10 16.91 5.42 0 4 9 10 55.45 7.38 0 5 9 10 65.71 6.39 0 0 10 10 12.84 5.39 0 1 10 10 111.63 8.84 0 2 10 10 -8.44 5.23 0 3 10 10 15.93 5.32 0 4 10 10 48.03 6.03 0 5 10 10 27.51 4.97 0 0 11 10 186.72 11.29 0 1 11 10 35.44 6.57 0 2 11 10 24.50 5.84 0 3 11 10 130.92 9.26 0 0 12 10 171.03 11.21 0 1 12 10 -3.06 4.98 0 2 12 10 59.29 7.13 0 3 12 10 19.94 5.36 0 4 12 10 16.19 4.29 0 0 13 10 219.51 11.72 0 2 13 10 43.99 5.70 0 3 13 10 27.98 5.20 0 0 14 10 58.15 6.92 0 1 14 10 31.18 5.36 0 2 14 10 18.22 4.35 0 3 14 10 -5.48 3.68 0 0 15 10 9.16 3.75 0 1 15 10 -3.15 3.12 0 0 0 11 2.91 3.90 0 1 0 11 12.75 3.74 0 2 0 11 0.64 3.78 0 3 0 11 220.30 10.59 0 4 0 11 9.23 4.35 0 5 0 11 123.45 9.36 0 6 0 11 40.91 6.42 0 0 1 11 70.00 5.90 0 1 1 11 315.31 11.15 0 2 1 11 281.70 11.11 0 3 1 11 -2.55 3.92 0 4 1 11 577.89 17.40 0 5 1 11 116.67 8.82 0 6 1 11 10.30 4.92 0 0 2 11 19.08 4.15 0 1 2 11 104.94 7.08 0 2 2 11 118.39 7.58 0 3 2 11 64.92 6.75 0 4 2 11 45.17 6.69 0 5 2 11 18.10 5.26 0 6 2 11 71.18 7.38 0 0 3 11 33.81 5.13 0 1 3 11 35.46 5.30 0 2 3 11 24.71 4.89 0 3 3 11 191.03 10.41 0 4 3 11 60.63 7.31 0 5 3 11 15.93 5.27 0 6 3 11 54.57 6.78 0 0 4 11 39.95 5.41 0 1 4 11 119.91 7.72 0 2 4 11 16.50 4.39 0 3 4 11 50.70 6.18 0 4 4 11 86.21 8.12 0 5 4 11 43.22 6.44 0 0 5 11 19.87 4.84 0 1 5 11 150.07 8.79 0 2 5 11 223.98 10.71 0 3 5 11 57.13 6.78 0 4 5 11 162.38 10.41 0 5 5 11 13.75 4.86 0 6 5 11 39.70 5.53 0 0 6 11 458.25 14.65 0 1 6 11 370.88 13.48 0 2 6 11 33.46 5.70 0 3 6 11 22.41 5.33 0 4 6 11 240.59 12.18 0 5 6 11 92.33 8.14 0 6 6 11 -0.76 3.80 0 0 7 11 102.00 8.19 0 1 7 11 233.82 11.25 0 2 7 11 172.73 10.10 0 3 7 11 219.98 11.57 0 4 7 11 35.61 6.46 0 5 7 11 -5.81 4.15 0 6 7 11 14.98 4.09 0 0 8 11 19.18 5.25 0 1 8 11 178.33 10.35 0 2 8 11 308.77 13.64 0 3 8 11 151.23 10.12 0 4 8 11 96.91 8.07 0 5 8 11 55.01 6.69 0 0 9 11 14.04 5.25 0 1 9 11 78.80 8.05 0 2 9 11 20.85 5.61 0 3 9 11 269.24 12.78 0 4 9 11 23.67 5.53 0 5 9 11 26.09 5.17 0 0 10 11 5.64 4.75 0 1 10 11 -0.53 4.61 0 2 10 11 20.43 5.68 0 3 10 11 8.87 4.60 0 4 10 11 -2.89 4.07 0 5 10 11 24.19 4.72 0 0 11 11 6.73 5.57 0 1 11 11 72.39 7.99 0 2 11 11 106.86 8.59 0 3 11 11 131.73 9.00 0 4 11 11 4.55 3.75 0 0 12 11 16.53 4.78 0 1 12 11 19.01 5.82 0 2 12 11 64.06 7.35 0 3 12 11 -4.09 3.81 0 4 12 11 6.51 3.34 0 2 13 11 10.27 4.15 0 3 13 11 45.53 6.22 0 0 14 11 23.45 5.12 0 1 14 11 14.18 4.01 0 2 14 11 18.41 4.59 0 0 0 12 -0.37 3.92 0 1 0 12 168.83 8.89 0 2 0 12 13.70 4.46 0 3 0 12 14.25 5.02 0 4 0 12 14.11 5.79 0 5 0 12 84.16 7.82 0 6 0 12 9.62 4.31 0 0 1 12 68.10 6.61 0 1 1 12 208.58 9.85 0 2 1 12 181.56 9.56 0 3 1 12 302.84 12.70 0 4 1 12 84.18 8.16 0 5 1 12 7.58 4.47 0 6 1 12 63.31 6.43 0 0 2 12 4.42 3.97 0 1 2 12 100.78 7.81 0 2 2 12 -3.02 4.21 0 3 2 12 50.15 6.63 0 4 2 12 32.30 5.48 0 5 2 12 -1.80 4.27 0 6 2 12 14.15 5.03 0 0 3 12 43.71 5.77 0 1 3 12 -6.69 3.69 0 2 3 12 237.82 11.30 0 3 3 12 26.44 5.62 0 4 3 12 66.04 7.20 0 5 3 12 11.59 5.24 0 6 3 12 2.02 4.17 0 0 4 12 18.59 4.79 0 1 4 12 383.07 13.61 0 2 4 12 -2.07 5.13 0 3 4 12 17.60 4.99 0 4 4 12 63.64 7.30 0 5 4 12 75.19 7.16 0 6 4 12 35.14 5.32 0 0 5 12 24.24 4.86 0 1 5 12 46.19 5.94 0 2 5 12 86.30 7.96 0 3 5 12 29.97 6.09 0 4 5 12 18.92 5.45 0 5 5 12 11.35 4.78 0 6 5 12 3.73 3.55 0 0 6 12 308.29 12.71 0 1 6 12 185.60 10.39 0 2 6 12 140.50 9.54 0 3 6 12 63.64 7.38 0 4 6 12 67.86 7.29 0 5 6 12 28.07 5.28 0 0 7 12 10.68 5.01 0 1 7 12 63.04 7.26 0 2 7 12 48.91 6.91 0 3 7 12 47.88 7.27 0 5 7 12 4.42 3.79 0 0 8 12 407.70 15.61 0 1 8 12 62.33 7.95 0 2 8 12 5.67 4.51 0 3 8 12 98.99 8.41 0 4 8 12 51.23 6.66 0 5 8 12 6.63 4.99 0 0 9 12 75.19 7.74 0 1 9 12 0.09 4.75 0 2 9 12 -12.99 4.90 0 3 9 12 109.11 8.72 0 4 9 12 13.89 5.12 0 5 9 12 -3.43 3.46 0 0 10 12 121.74 9.28 0 1 10 12 24.95 5.57 0 2 10 12 45.83 6.43 0 3 10 12 16.71 5.28 0 4 10 12 8.82 4.08 0 0 11 12 68.59 7.55 0 2 11 12 -3.74 4.17 0 3 11 12 26.05 5.08 0 4 11 12 -2.07 3.47 0 0 12 12 99.88 8.24 0 1 12 12 38.55 6.12 0 2 12 12 30.86 5.06 0 3 12 12 42.08 5.90 0 0 13 12 71.89 7.30 0 1 13 12 12.99 4.46 0 2 13 12 -3.54 3.47 0 0 14 12 -3.75 3.56 0 1 14 12 -1.42 3.78 0 0 0 13 8.64 4.10 0 1 0 13 -4.85 3.81 0 2 0 13 7.39 4.91 0 3 0 13 144.11 9.57 0 4 0 13 8.49 4.65 0 5 0 13 207.53 10.82 0 6 0 13 8.60 3.61 0 0 1 13 25.16 4.83 0 1 1 13 187.26 10.05 0 2 1 13 124.09 8.71 0 3 1 13 151.90 9.67 0 4 1 13 43.07 7.08 0 5 1 13 58.33 7.06 0 0 2 13 104.34 8.14 0 1 2 13 157.62 9.19 0 2 2 13 88.35 7.80 0 3 2 13 41.58 6.76 0 4 2 13 25.97 5.32 0 5 2 13 10.16 4.51 0 6 2 13 38.76 5.56 0 0 3 13 -0.63 4.03 0 1 3 13 54.55 6.42 0 2 3 13 65.06 7.03 0 3 3 13 151.14 9.85 0 4 3 13 22.68 5.55 0 5 3 13 95.99 7.60 0 0 4 13 106.08 8.36 0 1 4 13 341.81 13.69 0 2 4 13 124.06 9.23 0 3 4 13 204.70 11.08 0 4 4 13 38.92 6.68 0 5 4 13 5.88 4.73 0 0 5 13 3.20 4.40 0 1 5 13 38.41 6.16 0 2 5 13 216.50 11.81 0 3 5 13 0.51 5.25 0 4 5 13 32.74 5.91 0 5 5 13 19.04 5.13 0 0 6 13 222.66 11.52 0 1 6 13 493.96 16.63 0 2 6 13 261.80 12.83 0 3 6 13 77.65 7.89 0 4 6 13 64.32 7.12 0 5 6 13 54.28 6.23 0 0 7 13 -1.89 5.10 0 1 7 13 84.20 8.55 0 2 7 13 47.89 7.20 0 3 7 13 6.65 5.31 0 4 7 13 0.46 4.96 0 5 7 13 -2.04 3.55 0 0 8 13 163.49 10.54 0 1 8 13 98.42 8.79 0 2 8 13 191.95 11.34 0 3 8 13 40.14 6.50 0 4 8 13 2.45 4.15 0 0 9 13 -3.84 4.64 0 1 9 13 8.18 5.51 0 2 9 13 39.67 6.40 0 3 9 13 35.56 5.77 0 4 9 13 0.53 3.85 0 0 10 13 -2.08 4.60 0 1 10 13 18.88 5.21 0 2 10 13 11.04 5.12 0 3 10 13 17.94 4.82 0 4 10 13 10.17 3.78 0 0 11 13 4.62 4.54 0 1 11 13 12.39 4.41 0 2 11 13 2.69 4.29 0 3 11 13 23.24 5.00 0 0 12 13 54.71 6.39 0 1 12 13 18.64 4.61 0 2 12 13 37.16 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