Synthesis, characterization and crystal structure of a novel tetranuclear Co(II) cubane cluster

Hong Chen; Jianchun Wu; Mingguo Liu

doi:10.5155/eurjchem.10.3.256-262.1906

PDF CIF FILE

Published: Sep 30, 2019

DOI: https://doi.org/10.5155/eurjchem.10.3.256-262.1906

Keywords:

Crystal structure, DFT calculations, 2-Methylquinolin-8-ol, Transition-metal clusters, Tetranuclear Co(II) cubane, Hydrogen bonding interactions

Section

Research Article

Issue

Vol. 10 No. 3 (2019): September 2019

Dates

Received 2019-06-14
Accepted 2019-07-12
Published 2019-09-30

Hong Chen

Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, P. R. China

http://orcid.org/0000-0002-8415-7333

Jianchun Wu

Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, P. R. China

http://orcid.org/0000-0002-8227-4640

Mingguo Liu

Hubei Key Laboratory of Natural Products Research and Development, College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, P. R. China

http://orcid.org/0000-0003-2686-3034

Abstract

A new tetranuclear Co(II) cubane cluster 1, [Co₄(L1)₄(L2)₄]·4CH₃CH₂OH (HL1 = 2-Methylquinolin-8-ol, HL2 = t-Bu-COOH), has been synthesized and characterized by X-ray single crystal diffraction, FT-IR, TG/DSC, and elementary analysis. The data reveals that it has a very interesting structural motif consisting of a [Co₄O₄] core in the form of a cube with the Co and O occupying opposite corners. In the crystal structure of complex 1, the molecules are linked by intramolecular C−H···O hydrogen bonding interactions and Van der Waals forces, forming a three-dimensional network structure. Crystal data for complex 1: C₆₀H₆₈Co₄N₄O₁₂, triclinic, space group P-1 (no. 2), with a = 12.0644(4), b = 12.0996(3), c = 20.2858(7) Å, α = 92.005(3)^o, β = 92.182(3)°, γ = 97.943(3)°, Z = 2, V = 2928.25(16) Å³, T = 293 K, μ(MoKα) = 1.178 mm^-1, D_calc = 1.444 g/cm³, 16737 reflections measured (3.00° ≤ θ ≤ 28.53°), 9010 unique (R_int = 0.024, R_sigma = 0.0574) which were used in all calculations. The final R₁ was 0.039 (I≥2σ(I)) and wR₂ was 0.090 (all data).

This Abstract was viewed 1540 times |

Article PDF downloaded 704 times

Article CIF FILE downloaded 0 times

How to Cite

(1)

Chen, H.; Wu, J.; Liu, M. Synthesis, Characterization and Crystal Structure of a Novel Tetranuclear Co(II) Cubane Cluster. Eur. J. Chem. 2019, 10, 256-262.

Links for Article

Crossref - Scopus - Google - European PMC

References

[1]. Fujita, D.; Ueda, Y.; Sato, S.; Mizuno, N.; Kumasaka, T.; Fujita, M. Nature 2016, 540, 563-566.
https://doi.org/10.1038/nature20771

[2]. Brown, C. J.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. Chem. Rev. 2015, 115, 3012-3035.
https://doi.org/10.1021/cr4001226

[3]. McConnell, A. J.; Wood, C. S.; Neelakandan, P. P.; Nitschke, J. R. Chem. Rev. 2015, 115, 7729-7793.
https://doi.org/10.1021/cr500632f

[4]. Saha, M. L.; Yan, X.; Stang, P. J. Acc. Chem. Res. 2016, 49, 2527-2539.
https://doi.org/10.1021/acs.accounts.6b00416

[5]. Ballester, P.; Fujita, M.; Rebek, Jr. J. Chem. Soc. Rev. 2015, 44, 392-393.
https://doi.org/10.1039/C4CS90101K

[6]. Cook, T. R.; Stang, P. J. Chem. Rev. 2015, 115, 7001-7045.
https://doi.org/10.1021/cr5005666

[7]. Smulders, M. M. J.; Riddell, I. A.; Browne, C.; Nitschke, J. R. Chem. Soc. Rev. 2013, 42, 1728-1754.
https://doi.org/10.1039/C2CS35254K

[8]. Han, M.; Engelhard, D. M.; Clever, G. H. Chem. Soc. Rev. 2014, 43, 1848-1860.
https://doi.org/10.1039/C3CS60473J

[9]. Saalfrank, R. W.; Maid, H.; Scheurer, A. Angew. Chem. Int. Ed. 2008, 47, 8794-8824.
https://doi.org/10.1002/anie.200702075

[10]. Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Angew. Chem. Int. Ed. 2009, 48, 3418-3438.
https://doi.org/10.1002/anie.200805340

[11]. Breiner, B.; Clegg, J. K.; Nitschke, J. R. Chem. Sci. 2011, 2, 51-56.
https://doi.org/10.1039/C0SC00329H

[12]. Galan, A.; Ballester, P. Chem. Soc. Rev. 2016, 45, 1720-1737.
https://doi.org/10.1039/C5CS00861A

[13]. Koblenz, T. S.; Wassenaar, J.; Reek J. N. H. Chem. Soc. Rev. 2008, 37, 247-262.
https://doi.org/10.1039/B614961H

[14]. Georgieva, I.; Trendafilova, N.; Dodoff, N.; Kovacheva. D. Spectrochim. Acta A 2017, 176, 58-66.
https://doi.org/10.1016/j.saa.2017.01.008

[15]. Song, J.; Duan, B. F.; Lu, J. F.; Wu, R.; Du. Q. C. J. Mol. Struct. 2019, 1195, 252-258.
https://doi.org/10.1016/j.molstruc.2019.05.030

[16]. Akhtar, M.; Alharthi, A. I.; Alotaibi, M. A.; Trendafilova, N. Polyhedron 2017, 122, 105-115.
https://doi.org/10.1016/j.poly.2016.11.017

[17]. Chen, H.; Liu, M. G. J. Mol. Struct. 2019, 1180, 31-40.

[18]. Jeon, I. R.; Clérac, R. Dalton Trans. 2012, 41, 9565-9686.
https://doi.org/10.1039/c2dt30906h

[19]. Sato, Y.; Ohkoshi, S.; Arai, K.; Tozawa, M.; Hashimoto, K. J. Am. Chem. Soc. 2003, 125, 14590-14595.
https://doi.org/10.1021/ja030375v

[20]. Liu, C. M.; Zhang, D. Q.; Zhu, D. B. Chem. Commun. 2008, 368-370.
https://doi.org/10.1039/B715080F

[21]. Hao, Z. M.; Zhang, X. M. Dalton Trans. 2011, 40, 2092-2098.
https://doi.org/10.1039/c0dt00979b

[22]. Das, A.; Klinke, F. J.; Demeshko, S.; Meyer, S.; Dechert, S.; Meyer, F. Inorg. Chem. 2012, 51, 8141-8149.
https://doi.org/10.1021/ic300535d

[23]. Murrie, M.; Teat, S. J.; Stoeckli-Evans, H.; Gudel, H. U. Angew. Chem., Int. Ed. 2003, 42, 4653-4656.
https://doi.org/10.1002/anie.200351753

[24]. Song, Y. M.; Luo, F.; Luo, M. B.; Liao, Z. W.; Sun, G. M.; Tian, X. Z.; Zhu, Y.; Yuan, Z. J.; Liu, S. J.; Xu, W. Y.; Feng, X. F. Chem. Commun. 2012, 48, 1006-1008.
https://doi.org/10.1039/C2CC17080A

[25]. Zeng, M. H.; Yin, Z.; Liu, Z. H.; Xu, H. B.; Feng, Y. C.; Hu, Y. Q.; Chang, L. X.; Zhang, Y. X.; Huang, J.; Kurmoo, M. Angew. Chem., Int. Ed. 2016, 55, 11407-11411.
https://doi.org/10.1002/anie.201604813

[26]. Shi, X. C.; Chen, Z. Y.; Wang, Y. J.; Guo, Z. J.; Wang, X. Y. Dalton Trans. 2018, 47, 5049-5054.
https://doi.org/10.1039/C8DT00794B

[27]. Hannon, M. J. Chem. Soc. Rev. 2007, 36, 280-295.
https://doi.org/10.1039/B606046N

[28]. Hannon, M. J. Pure Appl. Chem. 2007, 79, 2243-2261.
https://doi.org/10.1351/pac200779122243

[29]. Passard, G.; Ullman, A. M.; Brodsky, C. N.; Nocera, D. G. J. Am. Chem. Soc. 2016, 138, 2925-2928.
https://doi.org/10.1021/jacs.5b12828

[30]. Becker, H. G. O.; Berger, W.; Domschke, G.; Fanghanel, E.; Faust, J.; Fischer, M.; Gentz, F.; Gewald, K.; Gluch, R.; Mayer, R.; Müller, K.; Pavel, D.; Schmidt, H.; Schollberg, K.; Schwetlick, K.; Seiler, E.; Zeppenfeld, G. Organikum, 19th ed.; Johann Ambrosius Barth Verlag GmbH: Leipzig, Berlin, Heidelberg, 1993.

[31]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[32]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[33]. K. Brandenburg, DIAMOND Version 3.0, Crystal Impact GbR, Bonn, Germany, 2014.

[34]. Kresse, G.; Hafner, J. Phys. Rev. B 1993, 47, 558-561.
https://doi.org/10.1103/PhysRevB.47.558

[35]. Kresse, G.; Hafner, J. Phys. Rev. B 1994, 49, 14251-14269.
https://doi.org/10.1103/PhysRevB.49.14251

[36]. Kresse, G.; Furthmüller, J. Phys. Rev. B 1996, 54, 11169-11186.
https://doi.org/10.1103/PhysRevB.54.11169

[37]. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868.
https://doi.org/10.1103/PhysRevLett.77.3865

[38]. Kresse, G.; Joubert, D. Phys. Rev. B 1999, 59, 1758-1775.
https://doi.org/10.1103/PhysRevB.59.1758

[39]. Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.; Humphreys, C. J.; Sutton, A. P. Phys. Rev. B 1998, 57, 1505-1509.
https://doi.org/10.1103/PhysRevB.57.1505

[40]. Klinke, F. J.; Das, A.; Demeshko, S.; Dechert, S.; Meyer, F. Inorg. Chem. 2014, 53, 2976-2982.
https://doi.org/10.1021/ic4027656

[41]. Ma, X. F.; Wang, Z.; Chen, X. L.; Kurmoo, M.; Zeng, M. H. Inorg. Chem. 2017, 56, 15178-15186.
https://doi.org/10.1021/acs.inorgchem.7b02530

[42]. Chen, X. L.; Xu, H. B.; Shi, X. X.; Zhang, Y. X.; Yang, T.; Kurmoo, M.; Zeng, M. H. Inorg. Chem. 2017, 56, 14069-14076.
https://doi.org/10.1021/acs.inorgchem.7b02210

Supporting Agencies

The Analytical & Testing Center of China Three Gorges University, Yichang, China and The Institute of Nuclear Science and Technology, Sichuan University, Chengdu, China.

Most read articles by the same author(s)

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)

Downloads

Metrics