Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate,  bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)

Cheikh Ndoye; Gregory Excoffier; Gorgui Awa Seck; Ousmane Diouf; IbraIbrahima Elhadji Thiam; Mamadou Sidibe; Mohamed Gaye

doi:10.5155/eurjchem.13.2.196-205.2253

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Published: Jun 30, 2022

DOI: https://doi.org/10.5155/eurjchem.13.2.196-205.2253

Keywords:

Complex, Schiff base, Octahedral, Thiocyanate, X-ray diffraction, Square pyramidal

Section

Research Article

Issue

Vol. 13 No. 2 (2022): June 2022

Dates

Cheikh Ndoye

Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal

https://orcid.org/0000-0002-6799-4973

Gregory Excoffier

Spectropole, Fédération des Sciences Chimiques de Marseille, Aix-Marseille Université, Marseille, 13397, France

https://orcid.org/0000-0002-6273-1373

Gorgui Awa Seck

Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal

https://orcid.org/0000-0002-6523-9384

Ousmane Diouf

Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal

https://orcid.org/0000-0003-3475-9528

IbraIbrahima Elhadji Thiam

Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal

https://orcid.org/0000-0002-4595-8445

Mamadou Sidibe

Spectropole, Fédération des Sciences Chimiques de Marseille, Aix-Marseille Université, Marseille, 13397, France

https://orcid.org/0000-0002-5499-1087

Mohamed Gaye

Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal

https://orcid.org/0000-0001-8989-1548

Abstract

The reactions of Schiff base 1-(1-hydroxypropan-2-ylidene)thiosemicarbazide (H₂L), with salt of thiocyanate metal (II) (Co, Ni, or Zn), provided one dinuclear and two new mononuclear complexes, formulated respectively as {[Co(LH)₂]₂·[Co(NCS)₄] ·2(MeOH)} (1), {[Ni(H₂L)₂]·[(NCS)₂]} (2) and [Zn(H₂L)(NCS)₂] (3). These compounds have been studied and characterized by elemental analysis, infrared, and ultraviolet-visible (UV-vis) spectroscopies. The structures of the three complexes have been resolved by X-ray crystallography technique. The dinuclear complex 1 crystallizes in the orthorhombic space group Fdd2 with the following unit cell parameters a = 33.1524 (3) Å, b = 19.3780 (2) Å, c = 13.2533 (2) Å, V = 8514.28 (17) Å³, Z = 16, R₁ = 0.025 and wR₂ = 0.063, the mononuclear complex 2 crystallizes in the monoclinic space group P2₁/n with the following unit cell parameters a = 11.5752 (1) Å, b = 12.3253 (1) Å, c = 14.2257 (2) Å, β = 106.855 (1)°, V = 1942 (4) Å³, Z = 4, R₁ = 0.038 and wR₂ = 0.106 and the mononuclear complex 3 crystallizes in the monoclinic space group P2₁/c with the following unit cell parameters a = 6.1121 (2) Å, b = 26.8272 (7) Å, c = 8.0292 (2) Å, β = 99.876 (3)°, V = 1297.04 (6) Å³, Z = 4, R₁ = 0.026 and wR₂ = 0.057. The asymmetric unit of Complex 1 contains one cationic unit in which the ligand acts in its monodeprotonated form in tridentate fashion and one half of the anionic unit containing two thiocyanate co-ligands. In complexes 2 and 3, the ligand acts in its neutral form in a tridentate manner. In complex 2, two ligand molecules coordinate the Ni(II) center, and the thiocyanate moieties remains uncoordinated. In complex 3, the Zn(II) is coordinated by one ligand molecule and two thiocyanate groups through their nitrogen atoms. Numerous hydrogen bonds consolidated the structures of complexes 1, 2, and 3 in a three-dimensional network.

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Ndoye, C.; Excoffier, G.; Seck, G. A.; Diouf, O.; Thiam, I. E.; Sidibe, M.; Gaye, M. Crystal Structures of bis[1-(1-Hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) Methanol Solvate, bis{1-(1-Hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-Hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II). Eur. J. Chem. 2022, 13, 196-205.

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