European Journal of Chemistry

Synthesis, characterization and crystal structure of 1-(4-methylbenzoyl)-3-(4 aminosulfonylphenyl)thiourea

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Published: Jun 15, 2010
DOI: https://doi.org/10.5155/eurjchem.1.2.73-75.34
Keywords:
Thiourea, Sulfonyl thiourea, Single crystal X-ray diffraction
Section
Research Article
Issue
Vol. 1 No. 2 (2010): June 2010
Dates
Received 2010-04-04
Accepted 2010-04-09
Published 2010-06-15


Main Article Content

Aamer Saeed
Department of Chemistry, Quaid-I-Azam University, Islamabad, 45320, Pakistan
Amara Mumtaz
Department of Chemistry, Quaid-I-Azam University, Islamabad, 45320, Pakistan
Ulrich Florke
Department Chemie, Fakultät fur Naturwissenschaften, Universitat Paderborn, Warburgerstrasse 100, D-33098, Paderborn, Germany

Abstract

An efficient synthesis of the title compound, 1-(4-methylbenzoyl)-3-(4-aminosulfonyl phenyl)thiourea,  was carried out by reaction of 4-methylbenzoyl chloride with potassium thiocyanate in acetone to afford 4-methylbenzoyl isothiocyanate in situ followed by treatment with sulfanilamide. The structure was confirmed by spectroscopic data and elemental analyses. The molecular structure was determined from single crystal X-ray diffraction data. It crystallizes in the monoclinic space group P21/n with unit cell dimensions of a = 4.8116(9) Å, b = 17.150(3) Å, c = 18.677(3) Å, γ = 96.487(4) °, and V = 1531.4(5) Å3.

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How to Cite
(1)
Saeed, A.; Mumtaz, A.; Florke, U. Synthesis, Characterization and Crystal Structure of 1-(4-Methylbenzoyl)-3-(4 aminosulfonylphenyl)thiourea. Eur. J. Chem. 2010, 1, 73-75.

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