European Journal of Chemistry 2010, 1(3), 179-181 | doi: https://doi.org/10.5155/eurjchem.1.3.179-181.44 | Get rights and content

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A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure


Hossein Eshtiagh-Hosseini (1,*) , Milad Mahjoobizadeh (2) , Masoud Mirzaei (3) , Katharina Fromm (4) , Aurelien Crochet (5)

(1) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(2) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(3) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(4) Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
(5) Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
(*) Corresponding Author

Received: 07 Apr 2010 | Revised: 18 Jul 2010 | Accepted: 04 Aug 2010 | Published: 29 Sep 2010 | Issue Date: September 2010

Abstract


A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.

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Keywords


Proton transfer compound; X-ray crystal structure; 2,4,6-Triamino-1,3,5-triazine; Citric acid; π−π Stacking

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DOI: 10.5155/eurjchem.1.3.179-181.44

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Ferdowsi University of Mashhad, Mashhad, Iran

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How to cite


Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.; Mirzaei, M.; Fromm, K.; Crochet, A. Eur. J. Chem. 2010, 1(3), 179-181. doi:10.5155/eurjchem.1.3.179-181.44
Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.; Mirzaei, M.; Fromm, K.; Crochet, A. A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure. Eur. J. Chem. 2010, 1(3), 179-181. doi:10.5155/eurjchem.1.3.179-181.44
Eshtiagh-Hosseini, H., Mahjoobizadeh, M., Mirzaei, M., Fromm, K., & Crochet, A. (2010). A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure. European Journal of Chemistry, 1(3), 179-181. doi:10.5155/eurjchem.1.3.179-181.44
Eshtiagh-Hosseini, Hossein, Milad Mahjoobizadeh, Masoud Mirzaei, Katharina Fromm, & Aurelien Crochet. "A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure." European Journal of Chemistry [Online], 1.3 (2010): 179-181. Web. 18 Aug. 2022
Eshtiagh-Hosseini, Hossein, Mahjoobizadeh, Milad, Mirzaei, Masoud, Fromm, Katharina, AND Crochet, Aurelien. "A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure" European Journal of Chemistry [Online], Volume 1 Number 3 (29 September 2010)

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