

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure
Hossein Eshtiagh-Hosseini (1,*)





(1) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(2) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(3) Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
(4) Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
(5) Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
(*) Corresponding Author
Received: 07 Apr 2010 | Revised: 18 Jul 2010 | Accepted: 04 Aug 2010 | Published: 29 Sep 2010 | Issue Date: September 2010
Abstract
A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.
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DOI: 10.5155/eurjchem.1.3.179-181.44
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Ferdowsi University of Mashhad, Mashhad, Iran
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DOI Link: https://doi.org/10.5155/eurjchem.1.3.179-181.44


















European Journal of Chemistry 2010, 1(3), 179-181 | doi: https://doi.org/10.5155/eurjchem.1.3.179-181.44 | Get rights and content
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