European Journal of Chemistry

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure

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Published: Sep 29, 2010
DOI: https://doi.org/10.5155/eurjchem.1.3.179-181.44
Keywords:
Proton transfer compound, X-ray crystal structure, 2, 4, 6-Triamino-1, 3, 5-triazine, Citric acid, π−π Stacking
Section
Research Article
Issue
Vol. 1 No. 3 (2010): September 2010
Dates
Received 2010-04-07
Accepted 2010-08-04
Published 2010-09-29


Main Article Content

Hossein Eshtiagh-Hosseini
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Milad Mahjoobizadeh
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Masoud Mirzaei
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Katharina Fromm
Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
Aurelien Crochet
Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland

Abstract

A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.

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Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.; Mirzaei, M.; Fromm, K.; Crochet, A. A New Three Dimensional Proton Transfer Compound Including Citric Acid and 2,4,6-Triamine-1,3,5-Triazine: Synthesis, Characterization and X-Ray Crystal Structure. Eur. J. Chem. 2010, 1, 179-181.

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Author Biography

Hossein Eshtiagh-Hosseini, Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran

Professor of inorganic chemistry
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Ferdowsi University of Mashhad, Mashhad, Iran
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