Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide

Ahmed Imam Hanafy; Ali Mostafa Ali Hassan; Sayed Ahmed Shama; Hamdy Khamees Thabet; Hany Mohammad Zaky El-alfy

doi:10.5155/eurjchem.4.2.157-161.752

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Published: Jun 30, 2013

DOI: https://doi.org/10.5155/eurjchem.4.2.157-161.752

Keywords:

EPR, Hydrolysis, Nitrophenol, Sulfonamide, Methyloxazol, Phosphoester

Section

Research Article

Issue

Vol. 4 No. 2 (2013): June 2013

Dates

Received 2013-02-17
Accepted 2013-03-20
Published 2013-06-30

Ahmed Imam Hanafy

Chemistry Department, Faculty of Science, Taif University, 21985, Taif, Saudi Arabia

Ali Mostafa Ali Hassan

Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt

Sayed Ahmed Shama

Chemistry Department, Faculty of Science Benha University, 13518, Benha, Egypt

Hamdy Khamees Thabet

Chemistry Department, Faculty of Science and Arts, Northern Border University, 91911, Rafha, Saudi Arabia

Hany Mohammad Zaky El-alfy

Chemistry Department, Faculty of Science Benha University, 13518, Benha, Egypt

Abstract

The sulfonamide derivative, 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide (FDMB), was synthesized and characterized. Additionally, its Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes were prepared and their structures were investigated by elemental analysis, thermal analysis and (IR, electronic and EPR) spectroscopy. The mode of binding indicates that the ligand binds to the metal ion through carbonyl oxygen and OH phenolic with displacement of its proton. The Co(II) complex was applied for the hydrolysis of nerve agent-like compound, bis-(p-nitrophenyl) phosphate (BNPP). The results showed a significant rate enhancement of 2.5 million fold with respect to the auto-hydrolysis of BNPP under the same conditions.

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Hanafy, A. I.; Hassan, A. M. A.; Shama, S. A.; Thabet, H. K.; El-alfy, H. M. Z. Synthesis, Characterization and Catalytic Activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) Complexes of 4-(3-Formyl-4-hydroxyphenyl)diazenyl)-N-(4-Methyloxazol-2-Yl) Benzenesulfonamide. Eur. J. Chem. 2013, 4, 157-161.

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