European Journal of Chemistry

Derivation of Gordy’s scale and computation of some useful descriptors of chemical reactivity



Main Article Content

Nazmul Islam

Abstract

A new atomic electronegativity scale is proposed by using the essence of electronegativity definitions of Gordy and Mulliken. The new computed atomic electronegativity data is found to satisfy all the sine qua non of a reasonable scale of atomic electronegativity. The electronegativity data is used to compute some useful descriptors of chemical reactivity. Comparative studies reveal that the new approach to derive the Gordy’s scale of electronegativity is a successful venture.

2_4_448_454_800


icon graph This Abstract was viewed 1351 times | icon graph Article PDF downloaded 653 times

How to Cite
(1)
Islam, N. Derivation of Gordy’s Scale and Computation of Some Useful Descriptors of Chemical Reactivity. Eur. J. Chem. 2011, 2, 448-454.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Berzelius, J. J. Annals. Philo. 1813, 2, 443-454.

[2]. Pauling, L. The Nature of the Chemical Bond. 3rd Edn. Cornell University: Ithaca. NY, 1960.

[3]. Pauling, L.; Yost, D. M. Proc. Nat. Acad. Sci. 1932, 18, 414-416.
http://dx.doi.org/10.1073/pnas.18.6.414

[4]. Sanderson, R. T. Science, 1951, 114, 670-672.
http://dx.doi.org/10.1126/science.114.2973.670
PMid:17770191

[5]. Coulson, C. A. Proc. R. Soc. London Ser. A. 1951, 207, 63-73.
http://dx.doi.org/10.1098/rspa.1951.0099

[6]. Ghosh, D. C.; Islam, N. Int. J. Quantum Chem. 2011, 111, 40-51.
http://dx.doi.org/10.1002/qua.22415

[7]. Allen, L. J. Am. Chem. Soc. 1992, 114, 1510-1511.
http://dx.doi.org/10.1021/ja00030a073

[8]. Fukui, K. Science 1982, 218, 747-754.
http://dx.doi.org/10.1126/science.218.4574.747
PMid:17771019

[9]. Ghosh, D. C. J. Indian Chem. Soc. 2003, 80, 527-533.

[10]. Ray, N. K.; Samuels, L.; Parr, R. G. J. Chem. Phys. 1979, 70, 3680-3684.

[11]. Kim, K. Bull. K. Chem. Soc. 1987, 8, 432-434.

[12]. Ghosh, D. C.; Chakraborty, T. J. Mol. Struct. Theochem. 2009, 906, 87-93.
http://dx.doi.org/10.1016/j.theochem.2009.04.007

[13]. Ghosh, D. C. J. Theoret. Comput. Chem. 2005, 4, 21-33.
http://dx.doi.org/10.1142/S0219633605001556

[14]. Ghosh, D. C.; Gupta. K. J. Theoret. Comput. Chem. 2006, 5, 895-911.
http://dx.doi.org/10.1142/S0219633606002726

[15]. Allen L. C.; Knight, E. T. J. Mol. Struct. Theochem. 1992, 261, 313-330.
http://dx.doi.org/10.1016/0166-1280(92)87083-C

[16]. Ayers, P. W. Faraday Discuss 2007, 135, 161-190.
http://dx.doi.org/10.1039/b606877d
PMid:17328428

[17]. Parr, R. G; Ayers, P. W.; Nalewajski, R. F. J. Phys. Chem. A 2005, 109, 3957-3959.
http://dx.doi.org/10.1021/jp0404596
PMid:16833715

[18]. Slater, J. C. Quantum Theory of Atomic Structure Vol-1, McGraw-Hill Book Company, 1960.

[19]. Moseley, H. G. J. Phil. Mag. 1913, 26, 1024-1032.

[20]. Gordy, W. Phys. Rev. 1946, 69, 604-607.
http://dx.doi.org/10.1103/PhysRev.69.604

[21]. Islam, N. J. Mol. Struct. Theochem. 2010, 947, 123-123.
http://dx.doi.org/10.1016/j.theochem.2010.01.039

[22]. Mulliken, R. S. J. Chem. Phys. 1934, 2, 782-794.

[23]. Parr, R. G.; Pearson, R. G. J. Am. Chem. Soc. 1983, 105, 7512-7516.
http://dx.doi.org/10.1021/ja00364a005

[24]. Feynman, R. P.; Leighton R. B.; Sands, M. The Feynman Lecture on Physics, Addison- Wesley: Mass., Vol-II, 1964.

[25]. Ghosh, D. C.; Biswas, R. Int. J. Mol. Sci. 2002, 3, 87-113.
http://dx.doi.org/10.3390/i3020087

[26]. Ghosh, D. C.; Islam, N. Int. J. Quantum Chem. 2009, 110, 1206-1214.

[27]. Reed, J. L. J. Chem. Edu. 1999, 76, 802-804.
http://dx.doi.org/10.1021/ed076p802

[28]. Ghosh, D. C.; Biswas, R.; Chakraborty, T.; Islam, N.; Rajak, S. K. J. Mol. Struct. Theochem. 2008, 865, 60-67.
http://dx.doi.org/10.1016/j.theochem.2008.06.020

[29]. Putz, M. V. Int. J. Quantum Chem. 2009, 109, 733-738.
http://dx.doi.org/10.1002/qua.21957

[30]. Ghosh; D. C.; Islam, N. Int. J. Quantum Chem. 2011, 111, 1942-1949.

[31]. Parr, R. G.; Borkman, R. F. J. Chem. Phys. 1968, 49, 1055-1058.

[32]. Nethercot, Jr. A. H. Chem. Phys. 1981, 59, 297-313.
http://dx.doi.org/10.1016/0301-0104(81)85173-7

[33]. Barbe, J. J. Chem. Educ. 1983, 60, 640-641.
http://dx.doi.org/10.1021/ed060p640

[34]. Murphy, L. R.; Meek, T. L.; Allred, A. L.; Allen, L. C. J. Phys. Chem. A 2000, 104, 5867-5871.
http://dx.doi.org/10.1021/jp000288e

[35]. Pearson, R. G. Proc. Natl. Acad. Sci. USA 1986, 83, 8440-8441.
http://dx.doi.org/10.1073/pnas.83.22.8440

[36]. Robles, J.; Bartolotti, L. J. J. Am. Chem. Soc. 1984, 106, 3723-3727.
http://dx.doi.org/10.1021/ja00325a003

[37]. Lovas, F. J.; Tiemann, E. J. Phys. Chem. Ref. Data 1974, 3, 609-770.
http://dx.doi.org/10.1063/1.3253146

[38]. Gyftopoulos, E. P.; Hatsopoulos, G. N. Proc. Natl. Acad. Sci. USA 1968, 60, 786-793.
http://dx.doi.org/10.1073/pnas.60.3.786

[39]. Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements, 2nd Edn. Elsevier, 2005.

[40]. Sanderson, R. T. J. Am. Chem. Soc. 1952, 74, 4792-4794.
http://dx.doi.org/10.1021/ja01139a020

[41]. Ghosh, D. C.; Bhattacharyya, S. Int. J. Quantum Chem. 2005, 105, 270-279.
http://dx.doi.org/10.1002/qua.20690

Supporting Agencies

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).