European Journal of Chemistry 2015, 6(2), 107-116. doi:10.5155/eurjchem.6.2.107-116.1162

Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate


Adel Abbas Ahmed Emara (1,*) , Ali Mahmoud Taha (2) , Mahmood Mohamed Mashaly (3) , Omima Mohamed Ibrahim Adly (4)

(1) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(2) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(3) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(4) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(*) Corresponding Author

Received: 26 Sep 2014, Accepted: 31 Oct 2014, Published: 30 Jun 2015

Abstract


New series of copper(II), nickel(II), cobalt(II), zinc(II), cadmium(II), iron(III) and oxovanadium(IV) complexes of hydrazone, H3L, ligand derived from the condensation of S-methyldithiocarbazate and 4,6-diacetylresorcinol, in the molar ratio 1:1, has been synthesized. All the metal complexes are dimmers. The structures of the ligand and its transition metal complexes were characterized by elemental analyses, spectral (Infrared, electronic, Mass, 1H NMR and ESR) data and magnetic susceptibility, molar conductivity measurements and thermal gravimetric analysis. The structure of the ligand is dibasic tridentate with ONS sites. The bonding sites, in all cases, are the azomethine nitrogen, phenolic oxygen and thiol sulfur atoms, as illustrated from the spectral data. The metal complexes exhibit different geometrical arrangements such as square planar, tetrahedral, square pyramidal and octahedral arrangements. Kinetic parameters (DG, DH, DS and DE) of the metal complexes were calculated from the thermal behaviour of the metal complexes using Coats-Redfern method. The ligand and its metal complexes were screened for its antimicrobial activity against Staphylococcus aureus and Staphylococcus pyogenes as Gram-positive bacteria, Pseudomonas phaseolicola and Pseudomonas fluorescens as Gram-negative bacteria and the fungi Fusarium oxysporum and Aspergillus fumigatus.


Keywords


Tridentate ligand; Kinetic parameters; 4,6-Diacetylresorcinol; Coats-Redfern method; Antimicrobial activities; S-Methyldithiocarbazate

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DOI: 10.5155/eurjchem.6.2.107-116.1162

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[1]. Mannar R. Maurya, Lata Rana, Fernando Avecilla
Phloroglucinol and resorcinol based mononuclear dioxidomolybdenum(VI) complexes: Synthesis, structural characterization and catalytic epoxidation
Polyhedron  126, 60, 2017
DOI: 10.1016/j.poly.2017.01.006
/


[2]. Magdy Shebl
Coordination behavior of new bis(tridentate ONO, ONS and ONN) donor hydrazones towards some transition metal ions: Synthesis, spectral, thermal, antimicrobial and antitumor studies
Journal of Molecular Structure  1128, 79, 2017
DOI: 10.1016/j.molstruc.2016.08.056
/


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How to cite


Emara, A.; Taha, A.; Mashaly, M.; Adly, O. Eur. J. Chem. 2015, 6(2), 107-116. doi:10.5155/eurjchem.6.2.107-116.1162
Emara, A.; Taha, A.; Mashaly, M.; Adly, O. Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate. Eur. J. Chem. 2015, 6(2), 107-116. doi:10.5155/eurjchem.6.2.107-116.1162
Emara, A., Taha, A., Mashaly, M., & Adly, O. (2015). Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate. European Journal of Chemistry, 6(2), 107-116. doi:10.5155/eurjchem.6.2.107-116.1162
Emara, Adel, Ali Mahmoud Taha, Mahmood Mohamed Mashaly, & Omima Mohamed Ibrahim Adly. "Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate." European Journal of Chemistry [Online], 6.2 (2015): 107-116. Web. 6 Dec. 2019
Emara, Adel, Taha, Ali, Mashaly, Mahmood, AND Adly, Omima. "Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate" European Journal of Chemistry [Online], Volume 6 Number 2 (30 June 2015)

DOI Link: https://doi.org/10.5155/eurjchem.6.2.107-116.1162

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