European Journal of Chemistry 2015, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228

Study on the host-guest interactions during caffeine encapsulation into zeolite


Zvezdelina Lyubenova Yaneva (1) , Manuela Stoyanova Staleva (2) , Nedyalka Valkanova Georgieva (3,*)

(1) Chemistry Unit, Department of Pharmacology, Animal Physiology and Physiological Chemistry, Faculty of Veterinary Medicine, Trakia University, Students Campus, 6000 Stara Zagora, Bulgaria
(2) University “Prof. d-r Assen Zlatarov”, 1 Prof. Yakim Yakimov Str., 8000 Bourgas, Bulgaria
(3) Chemistry Unit, Department of Pharmacology, Animal Physiology and Physiological Chemistry, Faculty of Veterinary Medicine, Trakia University, Students Campus, 6000 Stara Zagora, Bulgaria
(*) Corresponding Author

Received: 26 Nov 2014, Accepted: 10 Jan 2015, Published: 30 Jun 2015

Abstract


The objective of this study was to investigate the equilibrium and kinetics behavior, sorption mechanism and host-guest interactions during caffeine (CAF) encapsulation in natural zeolite. The chemical, spectral and morphological properties of the newly obtained drug-carrier system were analyzed. Zeolite surface chemistry and morphology were characterized by determination of pH of zero charge, FT-IR and digital microscopy analyses. Equilibrium and kinetic sorption experiments and modeling were conducted to assess zeolite potential. Satisfactory extend of CAF encapsulation in the zeolite matrix (E 36.4%) was obtained. The probable host-quest interactions include Van der Waals interactions, H-bonds and chemical interactions between CAF functional groups and zeolite silanol groups, as well as parallel intraparticle diffusion of drug molecules in the mesopores of the mineral particles. The analyses of the experimental results indicated that natural zeolite could be successfully applied for encapsulating CAF.


Keywords


Caffeine; Kinetics; Sorption; Equilibrium; Drug-delivery; Natural zeolite

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.6.2.169-173.1228

Article Metrics


This Abstract was viewed 567 times | PDF Article downloaded 279 times

Citations

/


[1]. Yu-Ta Chung, Chih-Kai Wang, Kai-Sung Wang, Sin-Yi Huang, Shih-Hsien Chang
Facile modification of graphite sheet by novel electrochemical exfoliation/oxidant method and its adsorption of caffeine from water
Journal of the Taiwan Institute of Chemical Engineers  80, 747, 2017
DOI: 10.1016/j.jtice.2017.09.012
/


[2]. Zvezdelina Yaneva, Nedyalka Georgieva, Manuela Staleva
Development of d,l-α-tocopherol acetate/zeolite carrier system: equilibrium study
Monatshefte für Chemie - Chemical Monthly  147(7), 1167, 2016
DOI: 10.1007/s00706-016-1714-x
/


References

[1]. Rimoli, M. G.; Rabaioli, M. R.; Melisi, D.; Curcio, A.; Mondello, S.; Mirabelli, R.; Abignente, E. J. Biomed. Mater. Res. A 2008, 87(1), 156-164.
http://dx.doi.org/10.1002/jbm.a.31763

[2]. Joshi, G. V.; Kevadiya, B. D.; Patel, H. A.; Bajaj, H. C.; Jasra, R. V. Int. J. Pharm. 2009, 374, 53-57.
http://dx.doi.org/10.1016/j.ijpharm.2009.03.004

[3]. Hadizadeh, F.; Khodaverdi, E.; Shandiz, R. H. Iran Int. Zeolite Conf. 2nd IIZC, April 29-30, 2010, Tehran.

[4]. Rahardjo, A. K.; Susanto, M. J. J.; Kurniawan, A.; Indraswati, N.; Ismadji, S. J. Hazard. Mater. 2011, 190, 1001-1008.
http://dx.doi.org/10.1016/j.jhazmat.2011.04.052

[5]. Budyanto, S.; Soedjono, S.; Irawaty, W.; Indraswati, N. J. Environ. Prot. Sci. 2008, 2, 72-80.

[6]. Barbooti, M. M.; Al-Bassam, K. S.; Qasim, B. H. Iraqi J. Sci. 2012, 53(3), 479-486.

[7]. Chang, P. H.; Yua, T. L.; Munkhbayer, S.; Kuo, T. H.; Hung, Y. C.; Jean, J. S.; Lin, K. H. J. Hazard. Mater. 2009, 165, 148-155.
http://dx.doi.org/10.1016/j.jhazmat.2008.09.113

[8]. Allen, S. J.; Ivanova, E.; Koumanova, B. Chem. Eng. J. 2009, 152, 389-395.
http://dx.doi.org/10.1016/j.cej.2009.04.063

[9]. Hameed, B. H. J. Hazard. Mater. 2010, 162, 939-994.
http://dx.doi.org/10.1016/j.jhazmat.2008.05.120

[10]. Yaneva, Z.; Georgieva, N. Macedonian J. Chem. Chemical Eng. 2013, 32(1), 133-149.

[11]. Koumanova, B.; Peeva-Antova, P. J. Hazard. Mater. 2002, 90(3), 229-234.
http://dx.doi.org/10.1016/S0304-3894(01)00365-X

[12]. Agyemang-Yeboah, F.; Oppon, S. Y. Topical Series in Health Science 1 (TSHS-1), Kerala, India, 27-37, 2013.

[13]. Hammud, H.; Chahine, M.; Hamaoui, B.; Younes, H. Eur. J. Chem. 2013, 4(4), 425-433.
http://dx.doi.org/10.5155/eurjchem.4.4.425-433.776

[14]. Lu, J.; Wu, M.; Yang, X.; Dong, Z.; Ye, J.; Borthakur, D.; Sun, Q.; Liang, Y. J. Food Eng. 2010, 97, 555-562.
http://dx.doi.org/10.1016/j.jfoodeng.2009.11.018

[15]. Lagergren, S. Kungliga Svenska Vetenskapsakademiens. Handlingar 1898, 24, 1-39.

[16]. Ho, Y. S.; McKay, G. Adsorp. Sci. Tech. 1998, 16, 243-255.

[17]. Chien, S. H.; Clayton, W. R. Soil Sci. Soc. Am. J. 1980, 44, 265-268.
http://dx.doi.org/10.2136/sssaj1980.03615995004400020013x

[18]. Haerifar, M.; Azizian, S. J. Phys. Chem. C 2012, 116, 13111-13119.
http://dx.doi.org/10.1021/jp301261h

[19]. Mansouri, N.; Rikhtegar, N.; Panahi, H. A.; Atabi, F.; Shahraki, B. K. Env. Prot. Eng. 2013, 39(1), 139-152.

[20]. Stuart, B. Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, West Sussex PO19 8SQ, England, 2004.

[21]. Verma, R.; Kumar, L. J. Chem. Pharm. Res. 2010, 2(4), 194-198.

[22]. Tomeckova, V.; Rehakova, M.; Mojzisova, G.; Magura, J.; Wadsten, T.; Zelenakova, K. Micropor. Mesopor. Mat. 2012, 147, 59-67.
http://dx.doi.org/10.1016/j.micromeso.2011.05.031

[23]. Amorim, R.; Vilacca, N.; Martinho, O.; Reis, R. M.; Sardo, M.; Rocha, J. J. Phys. Chem. C 2012, 116, 25642-25650.
http://dx.doi.org/10.1021/jp3093868

[24]. Banerjee, S.; Verma, P. K.; Mitra, R. K.; Basu, G.; Pal, S. K. J. Fluoresc. 2012, 22, 753-769.
http://dx.doi.org/10.1007/s10895-011-1011-3

[25]. Yakovishin, L. A.; Borisenko, N. I.; Vetrova, E. V.; Rudnev, M. I.; Grishikovets, V. I. Chem. Plant Raw Mat. 2010, 3, 7-70.

[26]. Yakovishin, L. A.; Borisenko, N. I.; Vetrova, E. V.; Rudnev, M. I.; Grishikovets, V. I. Russian J. Bioorg. Chem. 2011, 37(7), 858-861.
http://dx.doi.org/10.1134/S1068162011070260

[27]. Son, S. Y.; Bui, M.; Racette, R. C.; Williams, J. E. Chemical Sci. J. 2013, 2013, 96, 1-3.


How to cite


Yaneva, Z.; Staleva, M.; Georgieva, N. Eur. J. Chem. 2015, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Z.; Staleva, M.; Georgieva, N. Study on the host-guest interactions during caffeine encapsulation into zeolite. Eur. J. Chem. 2015, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Z., Staleva, M., & Georgieva, N. (2015). Study on the host-guest interactions during caffeine encapsulation into zeolite. European Journal of Chemistry, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Zvezdelina, Manuela Stoyanova Staleva, & Nedyalka Valkanova Georgieva. "Study on the host-guest interactions during caffeine encapsulation into zeolite." European Journal of Chemistry [Online], 6.2 (2015): 169-173. Web. 20 Aug. 2019
Yaneva, Zvezdelina, Staleva, Manuela, AND Georgieva, Nedyalka. "Study on the host-guest interactions during caffeine encapsulation into zeolite" European Journal of Chemistry [Online], Volume 6 Number 2 (30 June 2015)

DOI Link: https://doi.org/10.5155/eurjchem.6.2.169-173.1228

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2019  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.