European Journal of Chemistry 2015, 6(3), 342-349. doi:10.5155/eurjchem.6.3.342-349.1279
OPEN ACCESS

Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions


Mohamed Sobhi Motawea (1,*) , Mahmoud Ali Abdelaziz (2)

(1) Department of Chemistry, Faculty of Science, Benha University, Benha, Qalubya, 13518, Egypt
(2) Department of Chemistry, Faculty of Science, University of Tabuk, Tabuk, 7149, Saudi Arabia
(*) Corresponding Author

Received: 07 Jun 2015, Accepted: 05 Jul 2015, Published: 30 Sep 2015

Abstract


Two pyrazole derivatives, namely 2,4-diamino-5-(5-amino-3-hydroxy-1H-pyrazole-1-carbonyl)thiophene-3-carbonitrile (I) and 1-(2,4-diamino-5-(5-amino-3-hydroxy-1H-pyrazole-1-carbonyl)thiophen-3-yl)propan-1-one (II) were evaluated as a corrosion inhibitors for carbon steel in 1M hydrochloric acid by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy methods. Spectrophotometric and conductometric titration methods were also utilized to investigate the possibilities of chemical adsorption between the steel surface and the compounds under consideration. The results showed that the studied compounds inhibit the corrosion of steel in acidic solution at different temperatures. The adsorption followed the Langmuir isotherm. The thermodynamic and the activation parameters were also determined and discussed.


Keywords


Pyrazole; Steel surface; Carbon steel; Corrosion inhibitor; Langmuir isotherm; Pyrazole derivatives

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DOI: 10.5155/eurjchem.6.3.342-349.1279

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Citations

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[1]. Ambrish Singh, K.R. Ansari, Dheeraj Singh Chauhan, M.A. Quraishi, H. Lgaz, Ill-Min Chung
Comprehensive investigation of steel corrosion inhibition at macro/micro level by ecofriendly green corrosion inhibitor in 15% HCl medium
Journal of Colloid and Interface Science  560, 225, 2020
DOI: 10.1016/j.jcis.2019.10.040
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[2]. M. Abdallah, M. Sobhi, H.M. Altass
Corrosion inhibition of aluminum in hydrochloric acid by pyrazinamide derivatives
Journal of Molecular Liquids  223, 1143, 2016
DOI: 10.1016/j.molliq.2016.09.006
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References

[1]. Mohan, P.; Kalaignan, G.P. J. Mater. Sci. Technol. 2013, 29, 1096-1100.
http://dx.doi.org/10.1016/j.jmst.2013.07.006

[2]. Li, X.; Deng, S.; Fu, H.; Li, T. Electrochim. Acta 2009, 54, 4089-4098.
http://dx.doi.org/10.1016/j.electacta.2009.02.084

[3]. Abdallah, M.; Meghed, H.E.; Sobhi, M. Mater. Chem. Phys. 2009, 118, 111-117.
http://dx.doi.org/10.1016/j.matchemphys.2009.07.013

[4]. Abdallah, M.; Meghed, H.E.; Sobhi, M. Monats. Chem. 2010, 141, 1287-1298.
http://dx.doi.org/10.1007/s00706-010-0396-z

[5]. Amin, M. A.; Ibrahim, M. M. Corros. Sci. 2011, 53, 873-885.
http://dx.doi.org/10.1016/j.corsci.2010.10.022

[6]. Aouniti, A.; Hammouti, B.; Brighli, M.; Kertit, S.; Berhili, F.; ElKadiri, S.; Ramdani, A. J. Chim. Phys. 1996, 93, 1262-1271.

[7]. Abdallah, M.; El-Naggar, M. M. Mater. Chem. Phys. 2001, 71, 291-298.
http://dx.doi.org/10.1016/S0254-0584(01)00289-9

[8]. Gad Allah, A. G.; Tamous, H. M. J. Appl. Electrochem. 1990, 20, 488-493.
http://dx.doi.org/10.1007/BF01076061

[9]. Gad Allah, A. G.; Moustafa, H. J. Appl. Electrochem. 1992, 22, 644-648.
http://dx.doi.org/10.1007/BF01092613

[10]. Khaled, K. F.; Amin, M. A. Corros. Sci. 2009, 51(90), 1964-1975.
http://dx.doi.org/10.1016/j.corsci.2009.05.023

[11]. Abd El-Maksoud, S. A. Appl. Surf. Sci. 2003, 206, 129-136.
http://dx.doi.org/10.1016/S0169-4332(02)01188-1

[12]. Hassan, H. H.; Abdelghani, E.; Amina, M. A. Electrochim. Acta 2007, 52, 6359-6366.
http://dx.doi.org/10.1016/j.electacta.2007.04.046

[13]. Kertit, S.; Hammouti, B. Appl. Surf. Sci. 1996, 61, 59-66.
http://dx.doi.org/10.1016/0169-4332(95)00189-1

[14]. Khaled, K. F. Mater. Chem. Phys. 2008, 112, 290-300.
http://dx.doi.org/10.1016/j.matchemphys.2008.05.056

[15]. Chetouani, A.; Aounti, A.; Hammouti, B.; Benchat, N.; Benhadda, T.; Kertit, S. Corros. Sci. 2003, 45, 1675-1684.
http://dx.doi.org/10.1016/S0010-938X(03)00018-0

[16]. Wahdan, M. H. Mater. Chem. Phys. 1997, 49, 135-140.
http://dx.doi.org/10.1016/S0254-0584(96)01925-6

[17]. Mahendra, Y.; Rajesh, R. S.; Tarun, K. S.; Nidhi, T. J. Adhes. Sci. Technol. 2015, 29(16), 1690-1713.
http://dx.doi.org/10.1080/01694243.2015.1040979

[18]. Chetouani, A.; Hammouti, B.; Benhadda, T.; Daoudi, M. Appl. Surf. Sci. 2005, 249, 375-385.
http://dx.doi.org/10.1016/j.apsusc.2004.12.034

[19]. Abdel-Rehim, S. S.; Khaled, K. F.; Al-Mobarak, N. A. Arap. J. Chem. 2011, 4(3), 333-337.
http://dx.doi.org/10.1016/j.arabjc.2010.06.056

[20]. Mohareb, R. M.; El-Sayed, N. N.; Abdelaziz, M. A. Molecules 2012, 17, 8449-8463.
http://dx.doi.org/10.3390/molecules17078449

[21]. Sobhi, M. Prot. Met. Phys. Chem. 2014, 50(6), 825-832.
http://dx.doi.org/10.1134/S2070205114060227

[22]. Sobhi, M.; Abdallah, El-Sayed, R. J. Surf. Deterg. 2013, 16, 937-946.
http://dx.doi.org/10.1007/s11743-013-1468-y

[23]. Larabi, L.; Harek, Y.; Benali, O.; Ghalem, S. Prog. Org. Coat. 2005, 54, 256-262.
http://dx.doi.org/10.1016/j.porgcoat.2005.06.015

[24]. Sobhi, M.; Abdallah, M.; Khairou, K. S. Monatsh. Chem. 2012, 143, 1379-1387.
http://dx.doi.org/10.1007/s00706-011-0710-4

[25]. Yart, A.; Ultras, S.; Dal, H. Appl. Surf. Sci. 2006, 253, 919-925.
http://dx.doi.org/10.1016/j.apsusc.2006.01.026

[26]. Ashassi-Sorkhabi, H.; Ghatebsaz-Jeddi, N.; Hashemzadeh, F.; Jahani, H. Electrochim. Acta 2006, 51, 3848-3854.
http://dx.doi.org/10.1016/j.electacta.2005.11.002

[27]. Tsuru, T.; Haruyama, S.; Gijutu, B. J. Japan. Soc. Corros. Eng. 1978, 27, 573-579.

[28]. Zhang, S.; Tao, Z.; Li, W.; Hou, B. Appl. Surf. Sci. 2009, 255, 6757-6763.
http://dx.doi.org/10.1016/j.apsusc.2008.09.089

[29]. Lagrenee, M.; Mernari, B.; Bouanis, M.; Traisnel, M. Corros. Sci. 2002, 44, 573-588.
http://dx.doi.org/10.1016/S0010-938X(01)00075-0

[30]. Amin, A. S. Analysis 1995, 23, 415-417.

[31]. Kottaf, I. M.; Elving, P. I. Treatise on analytical chemistry (Part I), Interscience, New York, 1963.


How to cite


Motawea, M.; Abdelaziz, M. Eur. J. Chem. 2015, 6(3), 342-349. doi:10.5155/eurjchem.6.3.342-349.1279
Motawea, M.; Abdelaziz, M. Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions. Eur. J. Chem. 2015, 6(3), 342-349. doi:10.5155/eurjchem.6.3.342-349.1279
Motawea, M., & Abdelaziz, M. (2015). Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions. European Journal of Chemistry, 6(3), 342-349. doi:10.5155/eurjchem.6.3.342-349.1279
Motawea, Mohamed, & Mahmoud Ali Abdelaziz. "Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions." European Journal of Chemistry [Online], 6.3 (2015): 342-349. Web. 7 Dec. 2019
Motawea, Mohamed, AND Abdelaziz, Mahmoud. "Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions" European Journal of Chemistry [Online], Volume 6 Number 3 (30 September 2015)

DOI Link: https://doi.org/10.5155/eurjchem.6.3.342-349.1279

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