Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide
Ahmed Abd-Elhamied El-Asmy (1,*)



(1) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(2) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(3) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(*) Corresponding Author
Received: 03 Nov 2015, Accepted: 29 Nov 2015, Published: 31 Mar 2016
Abstract
Single crystal of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)succinohydrazide (SHBH) was grown by slow evaporation method. Its, Co(II), Ni(II), Cu(II), Zn(II), Co(II)/Zn(II), Ni(II)/Zn(II) and Cu(II)/Zn(II) complexes have been prepared and characterized by elemental analysis, UV-Vis, IR, NMR, MS spectra, thermal and magnetic measurements. The data confirm the formation of tri- and tetra-metallic complexes (homo- and hetero-nuclear). The ligand behaves as a tetranegative hexadentate in the Co(II)/Zn(II) complex; hexanegative hexadentate in the Co(II) complex and hexanegative octadentate in the tetrametallic complexes. A square-planar for [Co3(SHBH-6H)(H2O)6], [Cu4(SHBH-H)(H2O)4(OAc)2]⋅3H2O, [Ni3Zn(SHBH-6H)(H2O)6Cl2]⋅H2O and [Cu3Zn(SHBH-6H)(H2O)6Cl2] and tetrahedral for [Ni4(SHBH-H)(H2O)4(OAc)2]⋅6H2O, [Zn3(SHBH-4H)-(H2O)4Cl2]⋅2H2O and [Co2Zn(SHBH-6H) (H2O)6Cl2]⋅2H2O were suggested based on the magnetic and spectral data. The TGA data confirm hydrated and coordinated water as well as the final product. The mass spectra depict their molecular ion peaks and the isotopic species of each complex. It is found that the homometallic complexes are highly stable than the heterometallic complexes. The calculated energies for [Co2Zn(SHBH-4H)(H2O)4Cl2].2H2O are higher than [Co3(SHBH-6H)-(H2O)6] indicating that the three Co stabilized the complex.
Keywords
DOI: 10.5155/eurjchem.7.1.81-90.1356
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Citations
[1]. Ahmed Abdel-Hameed El-Asmy, Bakir Jeragh, Mayada Samir Ali
Chelation activity of N'1,N'6-bis((E)-3,4-dihydroxybenzylidene)adipohydrazide towards some transition metal ions
European Journal of Chemistry 7(3), 283, 2016
DOI: 10.5155/eurjchem.7.3.283-289.1461

References
[1]. Golcu, A.; Tumer, M.; Demirelli, H.; Wheatley, R. A. Inorg. Chim. Acta 2005, 358, 1797-1804.
http://dx.doi.org/10.1016/j.ica.2004.11.026
[2]. Ranford, J. D.; Vittal, J. J.; Wang, Y. M. Inorg. Chem. 1998, 37, 1226-1231.
http://dx.doi.org/10.1021/ic970805g
[3]. Jing-Lin, W.; Ya-Qin, Z.; Bin-Sheng, Y. Inorg. Chim. Acta 2014, 409, 484-496.
http://dx.doi.org/10.1016/j.ica.2013.09.001
[4]. Agarwal, R. K.; Singh, L.; Sharma, D. K.; Singh, R. Turk. J. Chem. 2005, 29, 309-316.
[5]. Suvarapu, L. N.; Seo, Y. K.; Baek, S. O.; Ammireddy, V. R. E-J. Chem. 2012, 9(3), 1288-1304.
[6]. El-Metwally, N. M.; El-Asmy, A. A.; Abu-Hussen, A. A. Int. J. Pure Appl. Chem. 2006, 1, 75-81.
[7]. Adams, H.; Clunas, S.; Fenton, D. E. Inorg. Chem. Commun. 2002, 15, 1063-1150.
http://dx.doi.org/10.1016/S1387-7003(02)00639-1
[8]. Jeragh, B.; Ali, M. S.; El-Asmy, A. A. Spectrochim. Acta A 2015, 145, 295-301.
http://dx.doi.org/10.1016/j.saa.2015.03.021
[9]. Borthakur, R.; Kumar, A.; Lal, R. A. J. Ind. Chem. Soc. 2014, 91(3), 407-423.
[10]. Monfareda, H. H.; Lalami, N. A.; Pazio, A.; Wozniak, K. Inorg. Chim. Acta 2013, 406, 241-250.
http://dx.doi.org/10.1016/j.ica.2013.04.044
[11]. El-Sayed, A. E. M.; Al-Fulaij, O. A.; Elaasar, A.; El-Defrawy, M. M.; El-Asmy, A. A. Spectrochim. Acta A 2015, 135, 211-218.
http://dx.doi.org/10.1016/j.saa.2014.07.006
[12]. Jeragh, B.; El-Asmy, A. A. Spectrochim. Acta A 2014, 129, 307-313.
http://dx.doi.org/10.1016/j.saa.2014.02.195
[13]. El-Asmy, A. A.; Al-Abdeen, A. Z.; Abo El-Maaty, W. M.; Mostafa, M. M. Spectrochim. Acta A 2010, 75, 1516-1524.
http://dx.doi.org/10.1016/j.saa.2010.02.009
[14]. Jeragh, B.; El-Asmy, A. A. Spectrochim. Acta A 2014, 130, 546-552.
http://dx.doi.org/10.1016/j.saa.2014.04.013
[15]. Becke, A. D.; J. Chem. Phys. 1993, 98, 5648-5652.
http://dx.doi.org/10.1063/1.464913
[16]. Gumus, I.; Solmaz, U. A.; Celik, O.; Binzet, G. Eur. J. Chem. 2015, 6(3), 237-241.
http://dx.doi.org/10.5155/eurjchem.6.3.237-241.1265
[17]. Tudose, R.; Mosoarca, E. M.; Simulescu, V.; Sasca, V.; Linert, W.; Costisor, O. J. Coord. Chem. 2010, 63, 4358-4366.
http://dx.doi.org/10.1080/00958972.2010.539683
[18]. El-Metwally, N. M.; El-Shazly, R. M.; Gabr, I. M.; El-Asmy, A. A. Spectrochim. Acta A 2005, 61, 1113-1119.
http://dx.doi.org/10.1016/j.saa.2004.06.027
[19]. Amer, S.; El-Wakiel, N.; El-Ghamry, H. J. Mol. Strut. 2013, 1049, 326-335.
http://dx.doi.org/10.1016/j.molstruc.2013.06.059
[20]. Hassanien, M. M.; Gabr, I. M.; Abdel-Rhman, M. H.; El-Asmy, A. A. Spectrochim. Acta A 2008, 73, 71-78.
[21]. Meghdadi, S.; Amirnasr, M.; Mereiter, K.; Motaharipour, S.; Nasehi, M.; Bagheri, M.; Abbasi, S. J. Coord. Chem. 2015, 68, 4055-4069.
http://dx.doi.org/10.1080/00958972.2015.1085977
[22]. Nejo, A. A.; Kolawola, G. A.; Nejo, A. O. J. Coord. Chem. 2010, 63, 4398-4410.
http://dx.doi.org/10.1080/00958972.2010.532871
[23]. El-Shazly, R. M.; Al-Hazmi, G. A. A.; Ghazy, S. E.; El-Shahawi, M. S.; El-Asmy, A. A. J. Coord. Chem. 2006, 59, 846-859.
http://dx.doi.org/10.1080/00958970500412099
[24]. Keypour, H.; Shayesteh, M.; Golbedaghi, R. Trans. Metal Chem. 2013, 38, 611-616.
http://dx.doi.org/10.1007/s11243-013-9728-2
[25]. Nejo, A. A.; Kolawola, G. A.; Dumbele, M. C.; Opoku, A. R. J. Coord. Chem. 2010, 63, 4367-4379.
http://dx.doi.org/10.1080/00958972.2010.539684
[26]. Al-Fulaij, O.; Jeragh, B.; El-Sayed, A.; El-Defrawy, M.; El-Asmy, A. Spectrochim. Acta A 2015, 136, 1834-1841.
http://dx.doi.org/10.1016/j.saa.2014.10.093
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