European Journal of Chemistry 2016, 7(2), 195-200. doi:10.5155/eurjchem.7.2.195-200.1409

Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions


Adil Ali Al-Fregi (1,*) , Mayada Abdulaa Adnan (2)

(1) Department of Chemistry, College of Science, University of Basra, 61001, Basrah, Iraq
(2) Department of Chemistry, College of Science, University of Misan, 61001, Misan, Iraq
(*) Corresponding Author

Received: 09 Feb 2016, Accepted: 12 Mar 2016, Published: 30 Jun 2016

Abstract


Reaction of 2-amino-5-nitrophenylmercuric chloride with 3-nitro benzaldehyde gave 2-(3-nitrobenzylideneamino)-5-nitrophenylmercuric chloride (1). Reaction of the mercurated Schiff bases 1 with tellurium tetrabromide in 2:1 mole ratio gave the tellurated Schiff bases, bis[2-(3-nitrobenzylidineamino)-5-nitrophenyl] tellurium dibromide (2). Reduction of compound 2 by hydrazine hydrate gave the corresponding telluride, bis[2-(3-nitro benzylideneamino)-5-nitrophenyl]telluride (3). Complexation reactions of equilibrium mole ratios compound 3 with MnCl2.4H2O, CoCl2.6H2O and NiCl2.6H2O gave the corresponding complexes, i.e compounds 4-6, respectively. All the prepared compounds were characterized by elemental analysis, conductivity measurements and 1H and 13C NMR, FT-IR and UV-visible spectroscopic data. These data suggested that the compound 3 coordinate with metal ions as tridentate ligand. The molar conductivity study indicated compounds 1-3 are neutral and behave as non-electrolytes in DMSO solvent at room temperature while compounds 4-6 behave as 1:1 electrolytes in the same conditions. The molar ratio method was used to determine metal-ligand ratio, which was found as 1:1, metal: ligand. The thermal analysis of compounds 2 and 3 were also investigated and discussed.


Keywords


Tellurides; Schiff base; Complexes; Thermal analysis; Mercurated Schiff base; Complexation reactions

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DOI: 10.5155/eurjchem.7.2.195-200.1409

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[1]. Adil Ali Al-Fregi, Ahmed Laith Al-Fadhly, Bushra Kamel Al-Salami
Synthesis, characterization and biological activity study of some new palladium(II) complexes containing amine or azomethine groups
European Journal of Chemistry  8(2), 155, 2017
DOI: 10.5155/eurjchem.8.2.155-161.1564
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How to cite


Al-Fregi, A.; Adnan, M. Eur. J. Chem. 2016, 7(2), 195-200. doi:10.5155/eurjchem.7.2.195-200.1409
Al-Fregi, A.; Adnan, M. Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions. Eur. J. Chem. 2016, 7(2), 195-200. doi:10.5155/eurjchem.7.2.195-200.1409
Al-Fregi, A., & Adnan, M. (2016). Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions. European Journal of Chemistry, 7(2), 195-200. doi:10.5155/eurjchem.7.2.195-200.1409
Al-Fregi, Adil, & Mayada Abdulaa Adnan. "Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions." European Journal of Chemistry [Online], 7.2 (2016): 195-200. Web. 14 Nov. 2019
Al-Fregi, Adil, AND Adnan, Mayada. "Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions" European Journal of Chemistry [Online], Volume 7 Number 2 (30 June 2016)

DOI Link: https://doi.org/10.5155/eurjchem.7.2.195-200.1409

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