European Journal of Chemistry

Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n

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Published: Jun 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.2.109-111.1548
Keywords:
Octahedron, Acetyl acetone, Crystal structure, Copper(II) complex, Coordination polymer, Organo-inorganic polymer
Section
Research Article
Issue
Vol. 8 No. 2 (2017): June 2017
Dates
Received 2017-01-24
Accepted 2017-03-16
Published 2017-06-30


Main Article Content

Najat Lauibi Ghali
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Mohammed Jassim Al-Assadi
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Hadi Salman Al-Lami
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Abdul Amir Hassan Kadhum
Department of Chemical Engineering, National University of Malaysia, Pekan Bangi, 43600 Bangi, Selangor, Malaysia

Abstract

The organo-inorganic polymer, poly[{Cu(NO2-acac)2}3]n, has been prepared and its crystal structure was determined. The structure consists of a trimeric unit in which, acetylacetone ligated symmetrically to copper atoms that pose in the center of octahedrons. The three octahedral fragments of the trimer are linked to each other through nitro group. Crystal Data: C10H12CuN2O8, Mr = 351.76, triclinic, P-1 (No. 2), a = 5.8237(2) Å, b = 7.7963(3) Å, c = 7.8847(3) Å, α = 81.988(2)°, b = 75.294(2)°, γ = 72.217(2)°, V = 328.98(2) Å3, T = 143(2) K, Z = 1, Z' = 0.5, μ(Mo Kα) = 1.703, 3021 reflections measured, 1421 unique (Rint = 0.0156) which were used in all calculations. The final wR2 was 0.0686 (all data) and R1 was 0.0217 (I > 2σ (I)).


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Ghali, N. L.; Al-Assadi, M. J.; Al-Lami, H. S.; Kadhum, A. A. H. Synthesis and Crystal Structure of poly{bis-(3-Nitro-2,4-Pentanediono)-copper(II)}, [Cu(NO2-acac)2]n. Eur. J. Chem. 2017, 8, 109-111.

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