European Journal of Chemistry 2017, 8(2), 109-111 | doi: https://doi.org/10.5155/eurjchem.8.2.109-111.1548 | Get rights and content






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Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n


Najat Lauibi Ghali (1) , Mohammed Jassim Al-Assadi (2) , Hadi Salman Al-Lami (3,*) , Abdul Amir Hassan Kadhum (4)

(1) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(2) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(3) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(4) Department of Chemical Engineering, National University of Malaysia, Pekan Bangi, 43600 Bangi, Selangor, Malaysia
(*) Corresponding Author

Received: 24 Jan 2017 | Revised: 23 Feb 2017 | Accepted: 16 Mar 2017 | Published: 30 Jun 2017 | Issue Date: June 2017

Abstract


The organo-inorganic polymer, poly[{Cu(NO2-acac)2}3]n, has been prepared and its crystal structure was determined. The structure consists of a trimeric unit in which, acetylacetone ligated symmetrically to copper atoms that pose in the center of octahedrons. The three octahedral fragments of the trimer are linked to each other through nitro group. Crystal Data: C10H12CuN2O8, Mr = 351.76, triclinic, P-1 (No. 2), a = 5.8237(2) Å, b = 7.7963(3) Å, c = 7.8847(3) Å, α = 81.988(2)°, b = 75.294(2)°, γ = 72.217(2)°, V = 328.98(2) Å3, T = 143(2) K, Z = 1, Z' = 0.5, μ(Mo Kα) = 1.703, 3021 reflections measured, 1421 unique (Rint = 0.0156) which were used in all calculations. The final wR2 was 0.0686 (all data) and R1 was 0.0217 (I > 2σ (I)).


Keywords


Octahedron; Acetyl acetone; Crystal structure; Copper(II) complex; Coordination polymer; Organo-inorganic polymer

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DOI: 10.5155/eurjchem.8.2.109-111.1548

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Funding information


Chemical Engineering, the National University of Malaysia, Malaysia

References

[1]. Batter, S. R.; Champness, N. R.; Chew, X. M.; Garcia, M. J.; Kitagawa, S.; Ohrstrom, L.; O'keeffe, M.; Suh, M. P.; Reedijk, J. Pure Appl. Chem. IUPAC 2013, 85(8), 1715-1724.

[2]. Fromm, K. Coord. Chem. Rev. 2008, 252(8-9), 856-885.
https://doi.org/10.1016/j.ccr.2007.10.032

[3]. You, X. Coord. Chem. Rev. 2006, 35, 3257-3263.

[4]. Atwood, J. L. Inclusion Compounds in Ullmanu's Encyclopedia of Industrial Chemistry, Weily-VCH, Weinheim, 2012.

[5]. Bureekaew, S. Sci. Techno. Adv. Mater. 2007, 9, 2-4.

[6]. Hoskins, B. F.; Robson, R. J. Amer. Chem. Soc. 1999, 112(4), 1546-1554.
https://doi.org/10.1021/ja00160a038

[7]. Gardner, G. B.; Venkataraman, D.; Moore, J. S.; Lees, S. Nature 1997, 374, 792-795.
https://doi.org/10.1038/374792a0

[8]. Keller, S. W. Angew. Chem. Int. Ed., Engl. 1997, 36(3), 247-248.
https://doi.org/10.1002/anie.199702471

[9]. Abrahams, B. F.; Hoskins, D. M.; Robson, R. Nature 1994, 369, 727-729.
https://doi.org/10.1038/369727a0

[10]. Bowmaker, G. A.; Hanna, J. V.; Healy, P. C.; Reid, J. C.; Rickard, C. E.; White, A. H. J. Chem. Soc., Dalton Trans. 2000, 753-768.
https://doi.org/10.1039/a908427d

[11]. Lazarou, K. N.; Perlepcs, S. P.; Psycharis, V.; Raptopoulou, C. P. Polyhedron 2008, 27(9-10), 2131-2142.
https://doi.org/10.1016/j.poly.2008.04.005

[12]. Stuant, R. B.; Suzanne, M. N.; David, R. T. Coordination polymers: Design, Analysis and Application. RSC Publishing, 2008.

[13]. Hagerman, D.; Hammond, R. P.; Haushalter, R.; Zubieta, J. Chem. Mater. 1998, 10(8), 2091-2100.

[14]. Tong, M. L.; Chen, H. J.; Chen, X. M. Inorg. Chem. 2000, 39(10), 2235-2238.
https://doi.org/10.1021/ic991312+

[15]. Dong, Y. B.; Smith, M. D.; Loye, H. C. Inorg. Chem. 2000, 39(21), 4927-4935.
https://doi.org/10.1021/ic0006504

[16]. Dong, Y. B.; Smith, M. D.; Layland, R. C.; zur Loye, H. C. Chem. Mater. 2000, 12, 1156-1161.
https://doi.org/10.1021/cm9907965

[17]. Mustapha, A. B.; Mose, L. J. Amer. Chem. Soc. 2014, 4(3), 280-285.
https://doi.org/10.9734/ACSJ/2014/7529

[18]. Baker, M. H.; Dorweiller, J. D.; Amande, N. L.; Pike, R. D.; Berry, S. M. Polyhedron 2009, 28(1), 188-194.
https://doi.org/10.1016/j.poly.2008.10.019

[19]. Singh, P. R.; Sahai, R. Aust. J. Chem. 1967, 20, 649-655.
https://doi.org/10.1071/CH9670649

[20]. Sheldrick, G. M. SHELXL-97, Program for Solution Crystal Structure, University of Gottingen, Germany, 1997.

[21]. LeBrun, P. C.; Lyon, W. D.; Kuska, H. A. J. Crystallogr. Spectrosc. Res. 1986, 6, 889-893.
https://doi.org/10.1007/BF01188194

[22]. Golochoubain, H. Asian J. Chem. 2008, 20(8), 5834-5838.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Ghali, N.; Al-Assadi, M.; Al-Lami, H.; Kadhum, A. Eur. J. Chem. 2017, 8(2), 109-111. doi:10.5155/eurjchem.8.2.109-111.1548
Ghali, N.; Al-Assadi, M.; Al-Lami, H.; Kadhum, A. Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n. Eur. J. Chem. 2017, 8(2), 109-111. doi:10.5155/eurjchem.8.2.109-111.1548
Ghali, N., Al-Assadi, M., Al-Lami, H., & Kadhum, A. (2017). Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n. European Journal of Chemistry, 8(2), 109-111. doi:10.5155/eurjchem.8.2.109-111.1548
Ghali, Najat, Mohammed Jassim Al-Assadi, Hadi Salman Al-Lami, & Abdul Amir Hassan Kadhum. "Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n." European Journal of Chemistry [Online], 8.2 (2017): 109-111. Web. 24 Oct. 2020
Ghali, Najat, Al-Assadi, Mohammed, Al-Lami, Hadi, AND Kadhum, Abdul. "Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

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DOI Link: https://doi.org/10.5155/eurjchem.8.2.109-111.1548

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