European Journal of Chemistry 2012, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534

Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine


Huang Yuanyuan (1) , Bai Fang (2) , Gao Guowei (3) , Men Jian (4,*)

(1) College of Chemistry, Sichuan University, Chengdu, 610064, China
(2) College of Chemistry, Sichuan University, Chengdu, 610064, China
(3) College of Chemistry, Sichuan University, Chengdu, 610064, China
(4) College of Chemistry, Sichuan University, Chengdu, 610064, China
(*) Corresponding Author

Received: 28 Sep 2011, Accepted: 12 Oct 2011, Published: 31 Mar 2012

Abstract


The novel compound, 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine has been synthesized starting from 2,4,6-trichloro-1,3,5-triazine and characterized by 1H NMR, 13C NMR, IR, mass spectroscopy and elemental analysis. The single crystal of the title compound was obtained and subjected to X-ray diffraction analysis. The single crystal data illustrates that it belongs to the monoclinic system, space group C2/c with a = 13.818(3) Å, b = 7.8964(16) Å, c = 30.718(6) Å, β = 96.52(3) o, V = 3330.0(12) Å3, Z = 8, Dc = 1.537 g/cm3, C16H11N5O7, Mr = 385.30, µ (MoKα) = 0.124 mm−1, F(000) = 1584, the final R = 0.0489 and wR = 0.1821 for 2491 observed reflections with I>2σ(I).

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Keywords


Synthesis; Bis-maleimides; π-π Interactions; Crystal structure; 2,4,6-Trichloro-1,3,5-triazine; 2-Methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine

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DOI: 10.5155/eurjchem.3.1.17-20.534

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[1]. Adel Sayed Orabi, Sahar Said El-Sakka
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References

[1]. Chandra, R.; Rajabi, L. J. Macromol. Sci. Rev. Macromol. Chem. Phys. 1997, 37, 61-96.
http://dx.doi.org/10.1080/15321799708014733

[2]. Lee, H. N.; Rield, F. R. Mater. Soc. 1989, 13, 301-318.

[3]. Owusu, A. O.; Martin, G. C.; Gotro, J. T. Polym. Eng. Sci. 1991, 31, 1604-1609.
http://dx.doi.org/10.1002/pen.760312208

[4]. Takao, I.; Hidehiko, S. J. Appl. Polym. Sci. 1997, 65, 1349-1357.
http://dx.doi.org/10.1002/(SICI)1097-4628(19970815)65:7<1349::AID-APP12>3.0.CO;2-Q

[5]. Liu, Y. L.; Chen, Y. J.; Wei, W. L. Polym. 2003, 44, 6465-6473.
http://dx.doi.org/10.1016/j.polymer.2003.08.006

[6]. Watanabe, M.; Yoshie, N. Polym. 2006, 47, 4946-4952.
http://dx.doi.org/10.1016/j.polymer.2006.05.036

[7]. Lin, R. H.; Liu, Y. H.; Chen, Y. H.; Lee, A. C.; Ho, T. H. Eur. Polym. J. 2007, 43, 4197-4209.
http://dx.doi.org/10.1016/j.eurpolymj.2007.08.004

[8]. Lin, R. H.; Lu, W. H.; Lin, C. W. Polym. 2004, 45, 4423-4435.
http://dx.doi.org/10.1016/j.polymer.2004.04.050

[9]. Hwang, H. L.; Li, C. H.; Wang, C. S. Polym. 2006, 47, 1291-1299.
http://dx.doi.org/10.1016/j.polymer.2005.12.040

[10]. Liu, Y. L.; Chen, Y. J. Polym. 2004, 45, 1797-1804.
http://dx.doi.org/10.1016/j.polymer.2004.01.001

[11]. Fang, Q.; Li, G. Z.; Zeng, X.; Jiang, L. X. J. Appl. Polym. 2004, 93, 475-480.
http://dx.doi.org/10.1002/app.20467

[12]. Fang, Q.; Ding, X. M.; Wu, X. Y.; Jiang, L. X. Polym. 2001, 47, 7595-7602.
http://dx.doi.org/10.1016/S0032-3861(01)00274-9

[13]. Hao, J.; Jiang, L.; Cai, X. Polym. 1996, 16, 3721-3727.
http://dx.doi.org/10.1016/0032-3861(96)00186-3

[14]. Lin, J.; Yuki, Y.; Kunisada, H.; Kondo, S. J. Appl. Polym. 1990, 40, 2113-2122.
http://dx.doi.org/10.1002/app.1990.070401124

[15]. Saida, K.; Sakai, M.; Narahara, T. Japan Patent (Jpn Kokai Tokkyo Koho) 52 136 298 and 52 136 189, 1977.

[16]. Sheldrick G. M., SHELXS97. Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.

[17]. Jetti. R. K. R.; Thallapally, P. K.; Nangia, A. Chem. Comm. 2002, 952-953.

[18]. Ohkita, M.; Kawano, M.; Suzuki, T.; Tsuji, T. Chem. Comm. 2002, 3054-3055.


How to cite


Yuanyuan, H.; Fang, B.; Guowei, G.; Jian, M. Eur. J. Chem. 2012, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, H.; Fang, B.; Guowei, G.; Jian, M. Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine. Eur. J. Chem. 2012, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, H., Fang, B., Guowei, G., & Jian, M. (2012). Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine. European Journal of Chemistry, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, Huang, Bai Fang, Gao Guowei, & Men Jian. "Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine." European Journal of Chemistry [Online], 3.1 (2012): 17-20. Web. 15 Nov. 2019
Yuanyuan, Huang, Fang, Bai, Guowei, Gao, AND Jian, Men. "Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

DOI Link: https://doi.org/10.5155/eurjchem.3.1.17-20.534

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