European Journal of Chemistry 2014, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929

Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)


Naushad Ahmad (1) , Rizwan Wahab (2,*) , Suliman Yousef Al Oma (3)

(1) Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(2) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(3) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(*) Corresponding Author

Received: 21 Sep 2013, Accepted: 30 Oct 2013, Published: 31 Mar 2014

Abstract


A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.


Keywords


Kinetics; Polymers; Activation energy; Polycondensation; Thermal degradation; Antibacterial activity

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DOI: 10.5155/eurjchem.5.1.155-161.929

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How to cite


Ahmad, N.; Wahab, R.; Al Oma, S. Eur. J. Chem. 2014, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929
Ahmad, N.; Wahab, R.; Al Oma, S. Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde). Eur. J. Chem. 2014, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929
Ahmad, N., Wahab, R., & Al Oma, S. (2014). Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde). European Journal of Chemistry, 5(1), 155-161. doi:10.5155/eurjchem.5.1.155-161.929
Ahmad, Naushad, Rizwan Wahab, & Suliman Yousef Al Oma. "Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)." European Journal of Chemistry [Online], 5.1 (2014): 155-161. Web. 20 Aug. 2019
Ahmad, Naushad, Wahab, Rizwan, AND Al Oma, Suliman. "Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)" European Journal of Chemistry [Online], Volume 5 Number 1 (31 March 2014)

DOI Link: https://doi.org/10.5155/eurjchem.5.1.155-161.929

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