Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2

Ikram Dhouib; Philippe Guionneau; Tahar Mhiri; Zakaria Elaoud

doi:10.5155/eurjchem.5.3.388-393.1038

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Published: Sep 30, 2014

DOI: https://doi.org/10.5155/eurjchem.5.3.388-393.1038

Keywords:

Arsenic acid, Crystal structure, Organic compounds, Raman spectroscopy, Infrared spectroscopy, Differential scanning calorimetry

Section

Research Article

Issue

Vol. 5 No. 3 (2014): September 2014

Dates

Received 2014-02-26
Accepted 2014-03-13
Published 2014-09-30

Ikram Dhouib

Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia

Philippe Guionneau

CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France

Tahar Mhiri

Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia

Zakaria Elaoud

Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia

Abstract

An organic-inorganic hybrid compound of tetraethylammonium dihydrogenarsenate bis-arsenic acid salts of formula [(CH₃CH₂)₄N].[H₂AsO₄].[H₃AsO₄]₂(TEAs) were grown by the slow evaporation and characterized by means of single crystal X-ray diffraction, thermal analysis, FT-IR and Raman spectroscopy. This compound crystallize in the space groups Cc with unit cell parameters, a= 20.105(2) Å; b= 7.342(4) Å, c = 15.292(2) Å, γ = 115(4)°, Z = 4, R= 0.07. The structure has solved using direct methods and refined by least-squares analysis. In this case, the structure consists of infinite parallel two-dimensional planes built of mutually H₂AsO₄⁻, H₃AsO₄tetrahedra connected by strong O-H···O hydrogen bonding. The thermoanalytical properties were studied using TG of TEAs method in the temperature ranges from 300 to 440 K for this hygroscopic sample. DSC measurement was carried out in the temperature range from 305 to 425 K.

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Dhouib, I.; Guionneau, P.; Mhiri, T.; Elaoud, Z. Crystal Structure, Thermal Behavior and Vibrational Studies of Tetraethylammonium Dihydrogenarsenate Bis-Arsenic Acid [(C2H5)4N].[H2AsO4].[H3AsO4]2. Eur. J. Chem. 2014, 5, 388-393.

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