The kinetic analysis of non-isothermal carisoprodol reaction  in nitrogen atmosphere using the invariant kinetic parameters method

Laila Tosson Kamel

doi:10.5155/eurjchem.5.3.507-512.1047

European Journal of Chemistry 2014, 5(3), 507-512 | doi: https://doi.org/10.5155/eurjchem.5.3.507-512.1047 | Get rights and content

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The kinetic analysis of non-isothermal carisoprodol reaction in nitrogen atmosphere using the invariant kinetic parameters method

Laila Tosson Kamel ^(1,*)

⁽¹⁾ Narcotic Department, National Center for Social and Criminal Research, Zamalek, Giza, 11561, Egypt
^(*) Corresponding Author

Received: 11 Mar 2014 | Accepted: 15 Apr 2014 | Published: 30 Sep 2014 | Issue Date: September 2014

Abstract

The non-isothermal kinetic parameters corresponding to the thermal decomposition of carisoprodol under nitrogen atmosphere was investigated at four different heating rates 5, 10, 15 and 20 °C/min. The activation energy was determined using three linear isoconversional methods, Friedman, Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose. Results showed good agreement with each other. Invariant kinetic parameters (IKP) method was applied in the conversion range of 0.2 ≤ α ≤ 0.8 for the determination of the kinetic triplet. E_inv= 95.81 kJ/mol, A_inv = 2.275×10⁷1/min and the decomposition mechanism corresponds to nucleation and growth, following the Avrami-Erofeev model, A1.5, as the kinetic model. The Perez-Maqueda et al. criterion associated with the independence of activation parameters on the heating rate (by means of Coats-Redfern and Flynn-Wall equation) confirmed the model.

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Editor-in-Chief

European Journal of Chemistry

Keywords

Carisoprodol; Thermal analysis; Perez-Maqueda criterion; Invariant kinetic parameters; Linear isoconversional methods; Non-isothermal kinetic parameters

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DOI: 10.5155/eurjchem.5.3.507-512.1047

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National Center for Social and Criminal Research, Egypt

Citations

[1]. Ali Bilici, Ruhiye Nilay Tezel, İsmet Kaya, Fatih Doğan
Synthesis and Characterization and Thermal Decomposition Kinetics of Poly (quinoline)-Copper Composite
Celal Bayar Üniversitesi Fen Bilimleri Dergisi , 187, 2018
DOI: 10.18466/cbayarfbe.393015

[2]. Hermínio P. Diogo, Joaquim J. Moura Ramos, M. Fátima M. Piedade
Thermal behavior and dynamic fragility in amorphous carisoprodol. Correlation between the dynamic and thermodynamic fragilities
Thermochimica Acta 663, 99, 2018
DOI: 10.1016/j.tca.2018.03.012

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How to cite

Kamel, L. Eur. J. Chem. 2014, 5(3), 507-512. doi:10.5155/eurjchem.5.3.507-512.1047

Kamel, L. The kinetic analysis of non-isothermal carisoprodol reaction in nitrogen atmosphere using the invariant kinetic parameters method. Eur. J. Chem. 2014, 5(3), 507-512. doi:10.5155/eurjchem.5.3.507-512.1047

Kamel, L. (2014). The kinetic analysis of non-isothermal carisoprodol reaction in nitrogen atmosphere using the invariant kinetic parameters method. European Journal of Chemistry, 5(3), 507-512. doi:10.5155/eurjchem.5.3.507-512.1047

Kamel, Laila. "The kinetic analysis of non-isothermal carisoprodol reaction in nitrogen atmosphere using the invariant kinetic parameters method." European Journal of Chemistry [Online], 5.3 (2014): 507-512. Web. 2 Jul. 2022

Kamel, Laila. "The kinetic analysis of non-isothermal carisoprodol reaction in nitrogen atmosphere using the invariant kinetic parameters method" European Journal of Chemistry [Online], Volume 5 Number 3 (30 September 2014)

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DOI Link: https://doi.org/10.5155/eurjchem.5.3.507-512.1047

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