European Journal of Chemistry 2010, 1(4), 312-318 | doi: https://doi.org/10.5155/eurjchem.1.4.312-318.105 | Get rights and content

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Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution


Abd El-Aziz Fouda (1) , Ahmed Al-Sarawy (2) , Emad El-Katori (3,*)

(1) Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, EG-35516, Egypt
(2) Department of Mathematical and Physical Science, Faculty of Engineering, Mansoura University, Mansoura, EG-35516, Egypt
(3) Department of Chemistry, Faculty of Science, King Khalid University, Abha, SA-61413, Saudi Arabia
(*) Corresponding Author

Received: 10 May 2010 | Accepted: 30 Sep 2010 | Published: 22 Dec 2010 | Issue Date: December 2010

Abstract


5-phenylazo-2-thioxo-thiazolidin-4-one and four of its derivatives have been investigated as corrosion inhibitors for C-steel in 1 M sulphuric acid solution using weight-loss and galvanostatic polarization techniques. The efficiency of the inhibitors increases with increase in inhibitor concentration but decreases with a rise in temperature. The conjoint effect of the thiazole derivatives and KBr, KSCN and KI has also been studied. The apparent activation energy (Ea*) and other thermodynamic parameters (ΔS*, ΔH* and ΔG*ads) for the corrosion process have also been calculated. The galvanostatic polarization data indicated that, the inhibitors were of mixed-type, but the cathode is more polarized than the anode. The slopes of the cathodic and anodic Tafel lines (ßc and ßa) are approximately constant and independent of the inhibitor concentration. The adsorption of these compounds on C-steel surface has been found to obey the Temkin's adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

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Editor-in-Chief
European Journal of Chemistry

Keywords


Corrosion inhibitors; C-steel; Weight loss; Synergistic effect; Polarization; Thiazole derivatives

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DOI: 10.5155/eurjchem.1.4.312-318.105

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Citations

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[1]. S. G. Sagdinc, Y. S. Kara
Theoretical elucidation on corrosion inhibition efficiency of 11-cyano undecanoic acid phenylamide derivatives: DFT study
Protection of Metals and Physical Chemistry of Surfaces  50(1), 111, 2014
DOI: 10.1134/S2070205114010201
/


[2]. Ashish Kumar Singh, Bhawna Chugh, Sanjeeve Thakur, Balaram Pani, Hassane Lgaz, Ill-Min Chung, Shweta Pal, Rajiv Prakash
Green approach of synthesis of thiazolyl imines and their impeding behavior against corrosion of mild steel in acid medium
Colloids and Surfaces A: Physicochemical and Engineering Aspects  599, 124824, 2020
DOI: 10.1016/j.colsurfa.2020.124824
/


[3]. Humira Assad, Richika Ganjoo, Shveta Sharma
A theoretical insight to understand the structures and dynamics of thiazole derivatives
Journal of Physics: Conference Series  2267(1), 012063, 2022
DOI: 10.1088/1742-6596/2267/1/012063
/


[4]. A.S. Fouda, A.M. Eldesoky, F.Sh. Mohamed, M.W. El-Sherbeni
Electrochemical and Quantum Chemical Investigations of some Cyanoacetamide Derivatives as Eco-Friendly Corrosion Inhibitors for Aluminum-Silicon Alloy in Acidic Solution
International Journal of Electrochemical Science  12(5), 4134, 2017
DOI: 10.20964/2017.05.10
/


[5]. Humira Assad, Ashish Kumar
Understanding functional group effect on corrosion inhibition efficiency of selected organic compounds
Journal of Molecular Liquids  344, 117755, 2021
DOI: 10.1016/j.molliq.2021.117755
/


[6]. Mahmoud N. El-Haddad, A. S. Fouda, H. A. Mostafa
Corrosion Inhibition of Carbon Steel by New Thiophene Azo Dye Derivatives in Acidic Solution
Journal of Materials Engineering and Performance  22(8), 2277, 2013
DOI: 10.1007/s11665-013-0508-0
/


[7]. Emad E. El-Katori, Saedah Al-Mhyawi
Assessment of theBassia muricataextract as a green corrosion inhibitor for aluminum in acidic solution
Green Chemistry Letters and Reviews  12(1), 31, 2019
DOI: 10.1080/17518253.2019.1569728
/


[8]. Emad E. El-Katori, A.S. Fouda, Rahma R. Mohamed
The Synergistic Impact of the Aqueous Valerian Extract and Zinc Ions for the Corrosion Protection of Mild Steel in Acidic Environment
Zeitschrift für Physikalische Chemie  233(12), 1713, 2019
DOI: 10.1515/zpch-2019-1377
/


[9]. Abd El-Aziz S. Fouda, Mohamed Eissa
Adenium obesum Extract as a Safe Corrosion Inhibitor for C-Steel in NaCl Solutions: Investigation of Biological Effects
Journal of Bio- and Tribo-Corrosion  6(4), , 2020
DOI: 10.1007/s40735-020-00394-3
/


[10]. I.B. Obot, E.E. Ebenso, I.A. Akpan, Z.M. Gasem, Ayo S. Afolabi
Thermodynamic and Density Functional Theory Investigation of Sulphathiazole as Green Corrosion Inhibitor at Mild Steel/Hydrochloric Acid Interface
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DOI: 10.1016/S1452-3981(23)13856-9
/


[11]. T. K. Chaitra, K. N. Mohana, H. C. Tandon
Study of New Thiazole Based Pyridine Derivatives as Potential Corrosion Inhibitors for Mild Steel: Theoretical and Experimental Approach
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DOI: 10.1155/2016/9532809
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DOI: 10.5229/JECST.2013.4.2.47
/


[13]. Chuan Lai, Xiulan Su, Ting Jiang, Lvshan Zhou, Bin Xie, Yulong Li, Like Zou
Corrosion Inhibition of Q235 Steel in H2SO4 Solution by N,N-Diethylammonium O,O'-di(4-bromophenyl) dithiophosphate
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DOI: 10.20964/2016.11.16
/


[14]. W.M. Yousef, Y. Reda, A.M. Eldesoky
Electrochemical Studies on the Corrosion Behaviour of Reinforcing Steel in the Presence of Cyanoacetamide Derivatives as Corrosion Inhibitors
International Journal of Electrochemical Science  13(12), 12172, 2018
DOI: 10.20964/2018.12.71
/


[15]. A. S. Fouda, F. Sh. Mohamed, M. W. El-Sherbeni
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DOI: 10.1007/s40735-016-0039-y
/


[16]. Badriah A. Al Jahdaly, Ghada S. Masaret
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DOI: 10.1016/j.molliq.2022.119933
/


[17]. Chikkur B. Pradeep Kumar, Kikkeri N. Mohana
The Effect ofAchyranthes asperaExtracts on Mild Steel Corrosion in Industrial Water Medium
ISRN Corrosion  2013, 1, 2013
DOI: 10.1155/2013/261847
/


[18]. Ivan Hameed R. Tomi, Ali. H. R. Al-Daraji, Sherien A. Aziz
Synthesis, Characterization, and Study the Inhibitory Effect of Thiazole and Thiadiazole Derivatives Toward the Corrosion of Copper in Acidic Media
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry  45(4), 605, 2015
DOI: 10.1080/15533174.2013.841226
/


References


[1]. Huilong, W.; Jiashen, Z.; Jing, L. Anti-Corros. Meth. M. 2002, 49(2), 127-132.

[2]. Saeed, T.; Ali, S. A.; Rahman, S. U. Anti-Corros. Meth. M. 2003, 50(3), 201-207.

[3]. Atia, A. A.; Saleh, M. M. J. Appl. Electrochem. 2003, 33(2), 171-177.
doi:10.1023/A:1024083117949

[4]. Tamilselvi, S.; Rajeswari, S. Anti-Corros. Meth. M. 2003, 50(3), 223-231.

[5]. Keera, S. T. Anti-Corros. Meth. M. 2003, 50(4), 280-285.

[6]. Wang, H. L., Liu, R. B.; Xin, J. Corros. Sci. 2004, 46(10), 2455-2466.
doi:10.1016/j.corsci.2004.01.023

[7]. Fouda, A. S.; Mostafa, H. A.; El-Taib-Heakel, F.; Elewady, G. Y. Corros. Sci. 2005, 47(8), 1988-2004.
doi:10.1016/j.corsci.2004.09.008

[8]. Migahed, M. A.; Mohamed, H. M.; Al-Sabagh, A. M. Mater. Chem. Phys. 2003, 80(1), 169-175.
doi:10.1016/S0254-0584(02)00456-X

[9]. Soror, T. Y.; El-Ziady, M. A. Mater. Chem. Phys. 2003, 77 (3), 697-703.
doi:10.1016/S0254-0584(02)00129-3

[10]. Lebrini, M.; Lagrenee, H.; Vezin, H.; Gengembre, L.; Bentiss, F. Corros. Sci. 2005, 47(2), 485-505.
doi:10.1016/j.corsci.2004.06.001

[11]. Mubarak, A. T. J. Sol. Chem. 2004, 33(2), 149-155.
doi:10.1023/B:JOSL.0000030282.00934.91

[12]. El-Bindary, A. A.; El-Sonbati, A. Z.; El-Mosalamy, E. H.; El-Santawy, E. M. Spectrochim. Acta Part A 2001, 57(12), 2359-2365.
doi:10.1016/S1386-1425(01)00422-X

[13]. Fouda, A. S.; El-Kaabi, S. S.; Mohamed, A. K. Corros. Prevent Contr. 1990, 37(6), 164-165.

[14]. Otieno-Alego, V.; Hope, G. A.; Flitt, H. J.; Cash, G. A.; Schweinsberg, D. P. Corros. Sci. 1992, 33(11), 1719-1734.
doi:10.1016/0010-938X(92)90004-M

[15]. Hoar, T. P.; Holliday, R. D. J. Appl. Chem. 1953, 3(11), 502-513.

[16]. El-Awady, Y. A.; Ahmed, A. I. J. Ind. Chem. 1985, 24A, 601-606.

[17]. Al-Neami, K. K.; Mohamed, A. K.; Kenawy, I. M.; Fouda, A. S. Monatsh Chem. 1995, 126, 369-376.
doi:10.1007/BF00813198

[18]. Haladky, K.; Collow, L.; Dawson, J. Br. Corros. J. 1980, 15, 20-21.

[19]. Caliskan, N.; Bilgic, S. Appl. Surf. Sci. 2000, 153, 128-133.
doi:10.1016/S0169-4332(99)00338-4

[20]. Khamis, E.; El-Ashry, E. S. H.; Ibrahim, A. K. Br. Corrosion J. 2000, 35(2), 150-154.
doi:10.1179/000705900101501191

[21]. Fouda, A. S.; Al-Sarawy, A. A.; El-Katori, E. E. Desalination, 2006, 201, 1–13.
doi:10.1016/j.desal.2006.03.519

[22]. Hammett, L. P. Physical Organic Chemistry, McGraw-Hill Book Co., N.Y., 1940

[23]. Donahue, F. M.; Nobe, K. J. Electrochem. Soc. 1965, 112(3), 886-891.
doi:10.1149/1.2423723

[24]. Smialowska, Z. S.; Kaminski, M. Corros. Sci. J. 1973, 13(1), 1-10.
doi:10.1016/0010-938X(73)90045-0


How to cite


Fouda, A.; Al-Sarawy, A.; El-Katori, E. Eur. J. Chem. 2010, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, A.; Al-Sarawy, A.; El-Katori, E. Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution. Eur. J. Chem. 2010, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, A., Al-Sarawy, A., & El-Katori, E. (2010). Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution. European Journal of Chemistry, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, Abd, Ahmed Al-Sarawy, & Emad El-Katori. "Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution." European Journal of Chemistry [Online], 1.4 (2010): 312-318. Web. 28 Sep. 2023
Fouda, Abd, Al-Sarawy, Ahmed, AND El-Katori, Emad. "Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution" European Journal of Chemistry [Online], Volume 1 Number 4 (22 December 2010)

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