Synthesis and corrosion inhibition evaluation of novel aminic nitrogen-bearing 1,2,4-triazole Schiff base compounds

Wael Abdel Gayed Ahmed Arafa; Nady Hashem El-Sayed

doi:10.5155/eurjchem.5.4.563-569.1083

PDF

Published: Dec 31, 2014

DOI: https://doi.org/10.5155/eurjchem.5.4.563-569.1083

Keywords:

EIS, Copper, Inhibitor, Schiff base, Polarization, Heterocycles

Section

Research Article

Issue

Vol. 5 No. 4 (2014): December 2014

Dates

Received 2014-04-23
Accepted 2014-06-15
Published 2014-12-31

Wael Abdel Gayed Ahmed Arafa

Chemistry Department, Faculty of Science, Fayoum University, Fayoum City, 63514, Egypt

Nady Hashem El-Sayed

Chemistry Department, Faculty of Science, Fayoum University, Fayoum City, 63514, Egypt

Abstract

Simple, effective, and high yield synthetic procedure for the synthesis of Schiff bases 5a-c is described. The scope of this reaction was investigated and noted that the presence of nickel(II) nitrate hexahydrate gave the corresponding Schiff bases in excellent yields. The inhibition effects of N-((1-phenyl-3-(thiophen-2-yl)-1H-pyrazol-5-yl)methylene)-4H-1,2,4-triazol-3-amine (PTP), 5c, have been investigated against the corrosion of copper in 0.5 M HCl solution. The investigations were accomplished using potentiodynamic polarization and electrochemical impedance measurements. Potentiodynamic polarization measurements indicated that the examined compound is mixed-type inhibitor. The results of electrochemical impedance indicated that the values of the charge transfer resistance and the inhibition efficiency tend to be increased by increasing the inhibitor concentration.

This Abstract was viewed 1500 times |

Article PDF downloaded 952 times

How to Cite

(1)

Arafa, W. A. G. A.; El-Sayed, N. H. Synthesis and Corrosion Inhibition Evaluation of Novel Aminic Nitrogen-Bearing 1,2,4-Triazole Schiff Base Compounds. Eur. J. Chem. 2014, 5, 563-569.

Links for Article

Crossref - Scopus - Google - European PMC

References

[1]. Sztanke, K.; Maziarka, A.; Osinka, A.; Sztanke, M. Bioorg. Med. Chem. 2013, 21, 3648-3666.
http://dx.doi.org/10.1016/j.bmc.2013.04.037

[2]. Alireza, A.; Zahra, A. Turk. J. Chem. 2013, 37, 867-878.
http://dx.doi.org/10.3906/kim-1207-74

[3]. Abd El-halim, H. F.; Omar, M. M.; Mohamed, G. G. Spectrochim. Acta A 2011, 78, 36-44.

[4]. Khungar, B.; Rao, M. S.; Pericherla, K.; Nehra, P.; Jain, N.; Panwar, J.; Kumar, A. C. R. Chimie 2012, 15, 669-674.
http://dx.doi.org/10.1016/j.crci.2012.05.023

[5]. Cezar, S.; Maria, P.; Cristian, T. Turk. J. Chem. 2008, 32, 487-493.

[6]. Atif, S. T.; Magda, N. A. N.; Magda, A. A. E; Samar, S. T. Med. Chem. Res. 2012, 21, 4139-4149.
http://dx.doi.org/10.1007/s00044-011-9960-2

[7]. Gehad, G. M.; Mohamed, M. O.; Ahmed, M. H. Turk. J. Chem. 2006, 30, 361-382.

[8]. Omar, M. M.; Mohamed, G. G.; Ibrahim, A. A. Spectrochim. Acta A 2009, 73, 358-369.
http://dx.doi.org/10.1016/j.saa.2009.02.043

[9]. Behpour, M.; Ghoreishi, S. M.; Salavati-Niasari, M.; Ebrahimi, B. Mater. Chem. Phys. 2008, 107, 153-157.
http://dx.doi.org/10.1016/j.matchemphys.2007.06.068

[10]. Aytac, H. U.; Ozmen, U.; Kabasakaloglu, M. Mater. Chem. Phys. 2005, 89, 176-181.
http://dx.doi.org/10.1016/j.matchemphys.2004.09.003

[11]. Behpour, M.; Ghoreishi, S. M.; Soltani, N.; Salavati-Niasari, M.; Hamadanian, M.; Gandomi, A. Corros. Sci. 2008, 50, 2172-2181.
http://dx.doi.org/10.1016/j.corsci.2008.06.020

[12]. Ashassi-Sorkhabi, H.; Shaabani, B.; Seifzadeh, D. Appl. Surf. Sci. 2005, 239, 154-164.
http://dx.doi.org/10.1016/j.apsusc.2004.05.143

[13]. Ahamad, I.; Prasad, R.; Quraishi, M. A. Mater. Chem. Phys. 2010, 124, 1155–1165.
http://dx.doi.org/10.1016/j.matchemphys.2010.08.051

[14]. Mohamed, H. A.; Farag, A. A.; Badran, B. M. J. Appl. Poly. Sci. 2010, 117, 1270-1278.

[15]. Finsgar, M. Corros. Sci. 2013, 77, 350-359.
http://dx.doi.org/10.1016/j.corsci.2013.08.026

[16]. Pan, Y. C.; Wen, Y.; Zhang, R.; Wang, Y. Y.; Zhang, Z. R.; Yang, H. F. Appl. Surf. Sci. 2012, 258, 3956-3961.
http://dx.doi.org/10.1016/j.apsusc.2011.12.070

[17]. Kovacevic, N.; Kokalj, A. Corros. Sci. 2013, 73, 7-17.
http://dx.doi.org/10.1016/j.corsci.2013.03.016

[18]. Sudheer, M. A. Corros. Sci. 2013, 70, 161-169.
http://dx.doi.org/10.1016/j.corsci.2013.01.025

[19]. Dermaj, A.; Hajjaji, N.; Joiret, S.; Rahmounia, K.; Srhiri, A.; Takenouti, H.; Vivier, V. Electrochim. Acta 2007, 52, 4654-4662.
http://dx.doi.org/10.1016/j.electacta.2007.01.068

[20]. AppaRao, B. V.; Narsihma, R. M.; Sreedhar, B. Prog. Org. Coat. 2014, 77, 202-212.

[21]. Fouda, A. S.; Wahed, H. A. Arab. J. Chem., doi: 10.1016/j.arabjc.2011.02.0.

[22]. Vera, R.; Bastidas, F.; Villarroel, M.; Oliva, A.; Molinari, A.; Ramirez, D.; del Rio, R. Corros. Sci. 2008, 50, 729-736.
http://dx.doi.org/10.1016/j.corsci.2007.10.004

[23]. Dafali, A.; Hammouti, B.; Touzani, R.; Kertit, S.; Ramdani, A.; El Kacemi, K. Anti-Corr. Meth. Mater 2002, 49, 96-104.

[24]. Safak, S.; Duran, B.; Yurt, A.; Turkoglu, G. Corros. Sci. 2012, 54, 251-259.
http://dx.doi.org/10.1016/j.corsci.2011.09.026

[25]. Emregul, K. C.; Atakol, O. Mater. Chem. Phys. 2004, 83, 373-379.
http://dx.doi.org/10.1016/j.matchemphys.2003.11.008

[26]. Streitwieser, A.; Heathcock, C. H.; Kosower, E. M. Introduction to Organic Chemistry, Prentice Hall, New Jersey, USA, 1998.

[27]. Chakraborti, A. K.; Bhagat, S.; Rudrawar, S. Tetrahedron Lett. 2004, 45, 7641-7644.
http://dx.doi.org/10.1016/j.tetlet.2004.08.097

[28]. Da Silva, C. M.; Da Silva, D. L.; Modolo, L. V.; Alves, R. B.; De Resende, M. A.; Martins, C. V. B.; De Fatima, A. J. Adv. Res. 2011, 2, 1-8.
http://dx.doi.org/10.1016/j.jare.2010.05.004

[29]. Soderberg, T. Organic Chemistry with a Biological Emphasis, University of Minesota, Moris, 2012.

[30]. Hajjaji, N.; Rico, I.; Srhiri, A.; Lattes, A.; Soufiaoui, M.; Bachir, B. Corros. 1993, 49, 326-334.
http://dx.doi.org/10.5006/1.3316057

[31]. El-Sayed, M. S.; Erasmus, R. M.; Comins, J. D. J. Colloid Interf. Sci. 2007, 311, 144-151.
http://dx.doi.org/10.1016/j.jcis.2007.02.064

[32]. Zhang, D. Q.; Gao, L. X.; Zhou, G. D. J. Appl. Surf. Sci. 2004, 225, 287-293.
http://dx.doi.org/10.1016/j.apsusc.2003.10.016

[33]. Sherif, E. M.; Park, S. M. Electrochim. Acta 2006, 51, 4665-4673.
http://dx.doi.org/10.1016/j.electacta.2006.01.007

[34]. Ma, H.; Chem, S.; Niu, L.; Zhao, S.; Li, S.; Li, D. J. Appl. Electrochem. 2002, 32, 65–72.
http://dx.doi.org/10.1023/A:1014242112512

[35]. Mansfield, F. Corrosion Mechanisms, Marcel Dekker, New York, 1987.

[36]. El-Hafez, G.; Badawy, W. A. Electrochim. Acta 2013, 108, 860-866.
http://dx.doi.org/10.1016/j.electacta.2013.06.079

[37]. Hamed, E. Mater. Chem. Phys. 2010, 121, 70-76.
http://dx.doi.org/10.1016/j.matchemphys.2009.12.044

[38]. El-Haddad, M. N. Int. J. Biol. Macromol. 2013, 55, 142-149.
http://dx.doi.org/10.1016/j.ijbiomac.2012.12.044

Supporting Agencies

Most read articles by the same author(s)

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)

Downloads

Metrics