European Journal of Chemistry

Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes

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Published: Dec 31, 2014
DOI: https://doi.org/10.5155/eurjchem.5.4.635-638.1131
Keywords:
Diamine, Thioether, N2O2S ligands, Pentadentate ligand, Unsymmetric ligand, Schiff base complexes
Section
Research Article
Issue
Vol. 5 No. 4 (2014): December 2014
Dates
Received 2014-08-06
Accepted 2014-08-23
Published 2014-12-31


Main Article Content

Ahmad Ali Dehghani-Firouzabadi
Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
Fahimeh Motevaseliyan
Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran

Abstract

Two thioether diamines 2-(2-aminoethylthio)aniline and 2-(3-aminopropylthio)aniline have been prepared employing a new procedure by reaction of 2-aminothiophenol and N-(2-bromoethyl)phthalimide or N-(3-bromopropyl)phthalimide, respectively. Then two new potentially pentadentate (N2O2S) Schiff base ligands derived from direct condensation between two maintained diamines and 2-hydroxybenzaldehyde or 5-bromo-2-hydroxy benzaldehyde were synthesized. Also, Zn(II) and Cd(II) complexes of Schiff base ligands have been prepared. These compounds have been characterized by physico-chemical and spectroscopic methods.


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Dehghani-Firouzabadi, A. A.; Motevaseliyan, F. Synthesis and Characterization of Four New Unsymmetrical Potentially Pentadentate Schiff Base Ligands and Related Zn(II) and Cd(II) Complexes. Eur. J. Chem. 2014, 5, 635-638.

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Supporting Agencies

Faculty of Chemistry of Yazd University and Ministry of Science, Research and Technology of Iran
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