European Journal of Chemistry

Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties



Main Article Content

Raquel Eunice Hernandez-Ramirez
Irina Victorovna Lijanova
Natalya Victorovna Likhanova
Octavio Olivares-Xometl
Luis Lartundo-Rojas

Abstract

Novel meso-porphyrins were synthesized via microwave assistance and implemented as centers to polyamide amine (PAMAM) dendrimers. The molecular structures of the porphyrins were characterized by UV-Vis, 1H and 13C NMR spectroscopy. In addition, porphyrin-PAMAM dendrimers were characterized by 1H and 13C NMR spectroscopy. The molecular weight of the prepared dendrimers were confirmed by MALDI-TOF mass spectrometry. These porphyrin-core-PAMAM-modified dendrimers were used as templates to form Ag0 species and doped nylon membranes, using the XPS technique to confirm the chemical reduction of the metal cation.


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Hernandez-Ramirez, R. E.; Lijanova, I. V.; Likhanova, N. V.; Olivares-Xometl, O.; Lartundo-Rojas, L. Synthesis of Porphyrins As Precursors to PAMAM Dendrimers and Their Metal Chelating Properties. Eur. J. Chem. 2016, 7, 49-55.

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Supporting Agencies

The Instituto de Ciencia y Tecnología del Distrito Federal (296/2010) and by the Instituto Politécnico Nacional (SIP 20151065).
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