European Journal of Chemistry

Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties

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Published: Mar 31, 2016
DOI: https://doi.org/10.5155/eurjchem.7.1.49-55.1352
Keywords:
Chelating, Porphyrin, Metal species, Metal complex, PAMAM sendrimers, Microwave synthesis
Section
Research Article
Issue
Vol. 7 No. 1 (2016): March 2016
Dates
Received 2015-10-28
Accepted 2015-12-05
Published 2016-03-31


Main Article Content

Raquel Eunice Hernandez-Ramirez
Instituto Politécnico Nacional, Centro de Investigación e Innovación Tecnológica, Cerrada Cecati S/N, Colonia Santa Catarina, Azcapotzalco, CP 02250, México D.F., México
Irina Victorovna Lijanova
Instituto Politécnico Nacional, Centro de Investigación e Innovación Tecnológica, Cerrada Cecati S/N, Colonia Santa Catarina, Azcapotzalco, CP 02250, México D.F., México
Natalya Victorovna Likhanova
Instituto Mexicano del Petróleo, Dirección de Investigación y Posgrado, Eje Central Lázaro Cárdenas No. 152, Col. San Bartolo Atepehuacan, México D.F., 07730, México
Octavio Olivares-Xometl
Benemérita Universidad Autónoma de Puebla, Facultad de Ingeniería Química, Av. San Claudio y 18 Sur, Col. San Manuel, Ciudad Universitaria, Puebla, 72570, México
Luis Lartundo-Rojas
Centro de Nanociencias y Micro y Nanotecnologías, Luis Enrique Erro S/N, U. Profesional Adolfo López Mateos, Gustavo A. Madero, C.P. 07738 Ciudad de México, D.F, México

Abstract

Novel meso-porphyrins were synthesized via microwave assistance and implemented as centers to polyamide amine (PAMAM) dendrimers. The molecular structures of the porphyrins were characterized by UV-Vis, 1H and 13C NMR spectroscopy. In addition, porphyrin-PAMAM dendrimers were characterized by 1H and 13C NMR spectroscopy. The molecular weight of the prepared dendrimers were confirmed by MALDI-TOF mass spectrometry. These porphyrin-core-PAMAM-modified dendrimers were used as templates to form Ag0 species and doped nylon membranes, using the XPS technique to confirm the chemical reduction of the metal cation.


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Hernandez-Ramirez, R. E.; Lijanova, I. V.; Likhanova, N. V.; Olivares-Xometl, O.; Lartundo-Rojas, L. Synthesis of Porphyrins As Precursors to PAMAM Dendrimers and Their Metal Chelating Properties. Eur. J. Chem. 2016, 7, 49-55.

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The Instituto de Ciencia y Tecnología del Distrito Federal (296/2010) and by the Instituto Politécnico Nacional (SIP 20151065).
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