European Journal of Chemistry

Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline

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Published: Dec 31, 2017
DOI: https://doi.org/10.5155/eurjchem.8.4.367-370.1636
Keywords:
Sulfur ligands, Bidentate nitrogen ligands, Heterocyclicdithiocarbamate, Tetramethylenedithiocarbimate, Pentamethylenedithiocarbimate, Nickel(II) mixed ligand complexes
Section
Research Article
Issue
Vol. 8 No. 4 (2017): December 2017
Dates
Received 2017-08-11
Accepted 2017-10-07
Published 2017-12-31


Main Article Content

Salih Hamza Abbas
Department of Chemistry, College of Science, University of Basrah, Basrah, 61004, Iraq

Abstract

Two ligands; pyrrolidine-1-carbodithioate sodium (L1) and piperidine-1-carbodithioate sodium salt(L2) and their nickel(II) mixed ligands complexes with 1,10-phenanthroline (L3) have been synthesized and characterized by FT-IR, UV-visible,1H NMR spectra. The biological activities of these complexes were also evaluated. The spectral data indicated that the 1,10-phenanthrolineand dithiocarbamate ligands are considered as a bidentate nitrogen and sulfur ligands, respectively. The study suggested that the above ligands formed complexes of general formula [Ni(Lx)2(L3)1] and [Ni(Lx)1(L3)2]Cl (x=1 or 2) mononuclear (monomer) complexes. The complexes show moderate and selective activity against tested microorganisms.


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Abbas, S. H. Synthesis, Characterization and Biological Activity of Some nickel(II) Mixed Ligands Complexes of Dithiocarbamate and 1,10-Phenanthroline. Eur. J. Chem. 2017, 8, 367-370.

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