European Journal of Chemistry

X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components

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Published: Jun 30, 2018
DOI: https://doi.org/10.5155/eurjchem.9.2.121-125.1712
Keywords:
Synthon, Organic salt, Diethanolamine, Aminobenzoic acid, X-ray crystallography, Molecular recognition
Section
Research Article
Issue
Vol. 9 No. 2 (2018): June 2018
Dates
Received 2018-04-12
Accepted 2018-05-05
Published 2018-06-30
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Aziz Bakhtiyarovich Ibragimov
Institute of General and Inorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
http://orcid.org/0000-0002-2709-7979
Bakhtiyar Sabirkhanovich Zakirov
Institute of General and Inorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
http://orcid.org/0000-0001-6664-8019
Bakhtiyar Tulyaganovich Ibragimov
Institute of Bioorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
http://orcid.org/0000-0002-9700-6227
Jamshid Mengnorovich Ashurov
Institute of Bioorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
http://orcid.org/0000-0002-4441-2803

Abstract

Two organic salts between diethanolamine (DEA) and ortho- and para-isomers (OABA and PABA) of aminobenzoic acid (ABA) have been obtained and their X-ray single crystal structures determined. In both salts, cationic and anionic components are incorporated into dimers by the two H-bonds formed between ABA carboxylate oxygen atoms and nitrogen and one of oxygen atoms of DEA which close a cycle with the graph-set notation of R22(9). Further dimers are associated by intricate systems of the H-bonds into 1D- and 3D-network structures in crystals of DEA·OABA and DEA·PABA, respectively. H-bonding which generates these dimers may be considered as a synthon specific for yielding of salts between DEA and mono-substituted aromatic benzoic acids.


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Ibragimov, A. B.; Zakirov, B. S.; Ibragimov, B. T.; Ashurov, J. M. X-Ray Structures of Organic Salts Between Diethanolamine and Ortho- and Para-Isomers of Aminobenzoic Acid: A Specific Synthon Responsible for an Association of the Components. Eur. J. Chem. 2018, 9, 121-125.

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