European Journal of Chemistry

Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer

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Published: Jun 30, 2019
DOI: https://doi.org/10.5155/eurjchem.10.2.125-130.1849
Keywords:
Pb(II), 1D polymer, Phenanthroline, X-ray crystal structure, Fluorescence property, Supramolecular interactions
Section
Research Article
Issue
Vol. 10 No. 2 (2019): June 2019
Dates
Received 2019-03-17
Accepted 2019-05-04
Published 2019-06-30
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Prafullya Kumar Mudi
Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
http://orcid.org/0000-0002-3365-0961
Chanchal Kumar Pal
Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
http://orcid.org/0000-0003-2821-8880
Bhaskar Biswas
Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
http://orcid.org/0000-0002-5447-9729

Abstract

A one dimensional (1D) lead(II) coordination polymer, [Pb(Phen)(NO3)(OAC)(H2O)]n (1) (Phen = 1,10-Phenanthroline; OAc = Acetate) was isolated in crystalline phase and characterized through different analytical techniques. Single crystal X-ray structural analysis of compound 1 revealed that the Pb(II) polymer crystallized in a monoclinic system with P21/c space group. Pb2+ ion adopted a highly distorted octahedral geometry having O3 (water) and O5 (nitrate) at axial positions (∠O3-Pb1-O5 of 145.02°) and acetate oxygen (O4), phenanthroine nitrogens (N3, N4) and oxygen (O2) atom from bridging nitrate made a distorted square plane. This Pb(II) polymer exhibited good fluorescence property in solid state. The steric arrangement of distorted square plane around Pb(II) ion by Phen, acetate and bridging nitrate ion makes a huge gap around Pb(II) ion where a stereo-active lone pair of electrons may possibly be occupied.

 


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Mudi, P. K.; Pal, C. K.; Biswas, B. Synthesis, Supramolecular Architecture and Fluorescence Property of a Mixed Ligand 1D Pb(II) Coordination Polymer. Eur. J. Chem. 2019, 10, 125-130.

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Supporting Agencies

The Science and Engineering Research Board (SERB), (Teachers Associateship for Research Excellence (No. TAR/2018/000473 dtd. 01-3-2019)), New Delhi, India.
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