European Journal of Chemistry

Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions

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Published: Dec 22, 2010
DOI: https://doi.org/10.5155/eurjchem.1.4.335-340.194
Keywords:
Acetylation, Alcohols, Phenols, Decatungstodivanadogermanic acid, Heterogeneous catalyst, Solvent-free conditions
Section
Research Article
Issue
Vol. 1 No. 4 (2010): December 2010
Dates
Received 2010-07-04
Accepted 2010-09-01
Published 2010-12-22


Main Article Content

Saeid Farhadi
Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, IR-68135-465, Iran
Somayeh Panahandehjoo
Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, IR-68135-465, Iran

Abstract

Decatungstodivanadogermanic acid (H6GeW10V2O40.22H2O) was used as a novel and green heterogeneous catalyst for the acetylation of hydroxy compounds under solvent-free conditions at room temperature. Efficient and selective acetylation of various alcohols and phenols was conducted with acetic anhydride as an acetylating agent over H6GeW10V2O40.22H2O under solvent-free conditions. All acetylated products were selectively obtained in excellent yields with very short reaction times. The reaction times were longer for the acetylation of phenols than for alcohols, so that an alcoholic OH group could be selectively acetylated in the presence of a phenolic OH group by the appropriate choice of reaction time. The catalyst can be recycled several times without observable loss of activity and selectivity.

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Farhadi, S.; Panahandehjoo, S. Decatungstodivanadogermanic Heteropoly Acid (H6GeW10V2O40.22H2O): A Novel, Green and Reusable Catalyst for Efficient Acetylation of Alcohols and Phenols under Solvent-Free Conditions. Eur. J. Chem. 2010, 1, 335-340.

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