Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O):  A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions

Saeid Farhadi; Somayeh Panahandehjoo

doi:10.5155/eurjchem.1.4.335-340.194

European Journal of Chemistry 2010, 1(4), 335-340 | doi: https://doi.org/10.5155/eurjchem.1.4.335-340.194 | Get rights and content

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Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions

Saeid Farhadi ^(1,*)

, Somayeh Panahandehjoo ⁽²⁾

⁽¹⁾ Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, IR-68135-465, Iran
⁽²⁾ Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, IR-68135-465, Iran
^(*) Corresponding Author

Received: 04 Jul 2010 | Accepted: 01 Sep 2010 | Published: 22 Dec 2010 | Issue Date: December 2010

Abstract

Decatungstodivanadogermanic acid (H₆GeW₁₀V₂O₄₀.22H₂O) was used as a novel and green heterogeneous catalyst for the acetylation of hydroxy compounds under solvent-free conditions at room temperature. Efficient and selective acetylation of various alcohols and phenols was conducted with acetic anhydride as an acetylating agent over H₆GeW₁₀V₂O₄₀.22H₂O under solvent-free conditions. All acetylated products were selectively obtained in excellent yields with very short reaction times. The reaction times were longer for the acetylation of phenols than for alcohols, so that an alcoholic OH group could be selectively acetylated in the presence of a phenolic OH group by the appropriate choice of reaction time. The catalyst can be recycled several times without observable loss of activity and selectivity.

1_4_335_340_800

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Keywords

Acetylation; Alcohols; Phenols; Decatungstodivanadogermanic acid; Heterogeneous catalyst; Solvent-free conditions

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DOI: 10.5155/eurjchem.1.4.335-340.194

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Citations

[1]. Alina Marieta Simion, Iwao Hashimoto, Yoshiharu Mitoma, Naoyoshi Egashira, Cristian Simion
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Synthetic Communications 42(6), 921, 2012
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Journal of Molecular Liquids 255, 406, 2018
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[4]. Srinivasa Rao Jetti, Divya Verma, Shubha Jain
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Journal of Catalysts 2013, 1, 2013
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How to cite

Farhadi, S.; Panahandehjoo, S. Eur. J. Chem. 2010, 1(4), 335-340. doi:10.5155/eurjchem.1.4.335-340.194

Farhadi, S.; Panahandehjoo, S. Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions. Eur. J. Chem. 2010, 1(4), 335-340. doi:10.5155/eurjchem.1.4.335-340.194

Farhadi, S., & Panahandehjoo, S. (2010). Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions. European Journal of Chemistry, 1(4), 335-340. doi:10.5155/eurjchem.1.4.335-340.194

Farhadi, Saeid, & Somayeh Panahandehjoo. "Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions." European Journal of Chemistry [Online], 1.4 (2010): 335-340. Web. 27 Sep. 2023

Farhadi, Saeid, AND Panahandehjoo, Somayeh. "Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A novel, green and reusable catalyst for efficient acetylation of alcohols and phenols under solvent-free conditions" European Journal of Chemistry [Online], Volume 1 Number 4 (22 December 2010)

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