European Journal of Chemistry

Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate

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Published: Dec 31, 2021
DOI: https://doi.org/10.5155/eurjchem.12.4.389-393.2151
Keywords:
Carbonyl, IR spectra, Crystal structure, Ruthenium complex, 1, 10-Phenanthroline, Computational chemistry
Section
Research Article
Issue
Vol. 12 No. 4 (2021): December 2021
Dates
Received 2021-07-15
Accepted 2021-08-28
Published 2021-12-31
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Tsugiko Takase
Department of Natural Sciences and Informatics, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, Japan
https://orcid.org/0000-0001-6508-4733
Dai Oyama
Department of Natural Sciences and Informatics, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, Japan
https://orcid.org/0000-0003-2388-9212

Abstract

Ruthenium(II) complexes containing both 1,10-phenanthroline (Phen) and carbonyl (CO) ligands are important molecules for various applications including catalysis. In this work, the molecular structure of [Ru(Phen)2(CO)2]2+ was determined via X-ray diffraction analysis for the first time. The complex exhibits substitutional disorder of one of counter-anions in the asymmetric unit, with different occupancies for CF3SO3- (0.72) and PF6- (0.28). The ruthenium atom is coordinated in a distorted octahedral environment by two carbonyl carbon atoms and four nitrogen atoms from bis-Phen ligands. The cation displays a cis configuration of the carbonyl ligands. Several hydrogen bonds and π-π interactions are present in the crystal. In addition to structural characterization, IR spectral data for the complex is compared with calculated values. These results provide fundamental data for understanding various properties of related ruthenium complexes.


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Takase, T.; Oyama, D. Synthesis and Structural Analysis of Cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-Trifluoromethanesulfonate 0.28-Hexafluoridophosphate. Eur. J. Chem. 2021, 12, 389-393.

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Japan Society for the Promotion of Science, Japan.
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