

Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction
Elżbieta Tadeusiak (1)





(1) Department of Structural Studies, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, Łódź, PL-90-363, Poland
(2) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(3) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(4) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(5) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(*) Corresponding Author
Received: 26 Jul 2010 | Accepted: 06 Aug 2010 | Published: 22 Dec 2010 | Issue Date: December 2010
Abstract
Two amino acids, leucine and valine, were studied by X-ray powder diffraction (XRPD). The linear correlations between intensity of racemate (decrease) or enantiomer (increase) and enantiomeric excesses were observed in each case.
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DOI: 10.5155/eurjchem.1.4.319-321.224
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Ministry of Science and Higher Education
Citations
[1]. María Mar Quesada-Moreno, Albert Virgili, Eva Monteagudo, Rosa M. Claramunt, Juan Ramón Avilés-Moreno, Juan Jesús López-González, Ibon Alkorta, José Elguero
A vibrational circular dichroism (VCD) methodology for the measurement of enantiomeric excess in chiral compounds in the solid phase and for the complementary use of NMR and VCD techniques in solution: the camphor case
The Analyst 143(6), 1406, 2018
DOI: 10.1039/C7AN01855J

References
[1]. Fischer, E. Ber. Dtsch. Chem. Ges. 1904, 37, 2486-2511.
doi:10.1002/cber.190403702197
[2]. Patel, M. S.; Worsley. M. Can. J. Chem. 1970, 48, 1881-1884.
doi:10.1139/v70-310
[3]. Marvel, C. S. Org. Synth. 1940, 20, 106-108.
[4]. Shono, T.; Matsumura, Y.; Tsubata, K. Tetrahedron Lett. 1981, 22, 2411-2412.
doi:10.1016/S0040-4039(01)82922-1
[5]. Jakubke, H-D.; Jeschkeit, H. Aminosäuren, Peptide, Proteine, Akademie-Verlag, Berlin 1982.
[6]. Adams, S. S.; McCullough, K. F.; Nicholson, J. S. Arch. Int. Pharmacodyn. Ther. 1969, 178, 115-129.
PMid:5353466
[7]. Adams, S. S.; Bough, R. G.; Cliffe, E. E.; Lessel, B.; Mills, R. F. Toxicol. Appl. Pharmacol. 1969, 15, 310 330.
doi:10.1016/0041-008X(69)90032-5
[8]. Phandnis, N. V.; Suryanarayanan, R. Pharmaceutical Res. 1997, 9, 1176-1180.
doi:10.1023/A:1012198605891
PMid:9327444
[9]. Sullivan, M. P. Cancer Chemother. Rep. 1967, 51, 393.
[10]. Hill, D. L. A Review of Cyclophosphamide, Ch. C. Thomas, Springfield III 1975.
[11]. Brock, N. Cancer. Res. 1989, 41, 1-7.
[12]. Tadeusiak, E. J.; Kruszynski, R.; Misiura, K. Pol. J. Chem. 2004, 78, 431-435.
[13]. Klug, H.P.; Alexander, L.E. X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials, Wiley, New York 1974.
[14]. Harding, M. M.; Howieson, R. M. Acta Cryst. 1976, B32, 633-634.
[15]. Coll, M.; Solans, X.; Font-Altaba, M.; Subirana, J. A. Acta Cryst. 1986, C42, 599-601.
[16]. Gorbitz, C. H.; Dalhus, B. Acta Cryst. 1996, C52, 1754-1756.
[17]. Torii, K.; Iitaka, Y. Acta Cryst. 1970, B26, 1317-1326.
[18]. Dalhus, B.; Gorbitz, C. H. Acta Chem. Scand. 1996, 50, 544-548.
doi:10.3891/acta.chem.scand.50-0544
[19]. Wang, W. Q.; Gong, Y.; Liang, Z.; Sun, F. L.; Shi, D. X.; Gao, H. J.; Lin X.; Jiang, P; Wang, Z. M. Surf. Sci. 2002, 512, 379-384.
doi:10.1016/S0039-6028(02)01570-4
[20]. Blasio, B.; Pedone, C.; Sirigu, A. Acta Cryst. 1975, B31, 601; Erratum Acta Cryst. 1975, B31, 601-602.
[21]. Moller, A. Acta Chem. Scand. 1949, 3, 1326-1330.
doi:10.3891/acta.chem.scand.03-1326
[22]. Mallikarjunan, M.; Rao. S. T. Acta Cryst. 1969, B25, 296-303.
doi:10.1107/S0567740869002147
[23]. Dawson, B.; Mc Mathieson, A. L. Acta Cryst. 1951, 4, 475-477.
doi:10.1107/S0365110X51001550
[24]. Dalhus, B.; Gorbitz, C. H. Acta Cryst. 1996, C52, 1759-1761.
[25]. Flaig, R.; Koritsanszky, T.; Dittrich, B.; Wagner, A.; Luger, P. J. Am. Chem. Soc. 2002, 124, 3407-3417.
doi:10.1021/ja011492y
PMid:11916427
[26]. Jenkins, R.; Snyder, R. L. Introduction to X-Ray Powder Diffractometry, John Wiley & Sons, Inc., New York 1996.
[27]. Masciochi, N. The Rigaku J. 1997, 14, 9-16.
[28]. Harris, K. D. M.; Tremayne, M.; Kariuki, B. M. Angew. Chem. Int. Ed. 2001, 40, 1626-1651.
doi:10.1002/1521-3773(20010504)40:9<1626::AID-ANIE16260>3.0.CO;2-7
[29]. Zevin, L. S. J. Appl. Cryst. 1977, 10, 147-150.
doi:10.1107/S0021889877013144
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