European Journal of Chemistry 2022, 13(2), 168-171 | doi: https://doi.org/10.5155/eurjchem.13.2.168-171.2278 | Get rights and content

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Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct


Evrim Arslan (1) orcid , Ivan Bernal (2) orcid , Roger Lalancette (3,*) orcid

(1) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(2) Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, 2050 Johannesburg, ZA, South Africa
(3) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(*) Corresponding Author

Received: 22 Mar 2022 | Revised: 07 May 2022 | Accepted: 08 May 2022 | Published: 30 Jun 2022 | Issue Date: June 2022

Abstract


A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca21, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.


Keywords


Triazines; Formamide; X-ray diffraction; Metal basic adduct; Magnetic properties; Vanadyl acetylacetonates

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DOI: 10.5155/eurjchem.13.2.168-171.2278

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Funding information


The National Science Foundation for NSF-CRIF Grant No. 0443538 and Rutgers University, 73 Warren St., Newark, NJ, 07102, USA.

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Arslan, E.; Bernal, I.; Lalancette, R. Eur. J. Chem. 2022, 13(2), 168-171. doi:10.5155/eurjchem.13.2.168-171.2278
Arslan, E.; Bernal, I.; Lalancette, R. Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct. Eur. J. Chem. 2022, 13(2), 168-171. doi:10.5155/eurjchem.13.2.168-171.2278
Arslan, E., Bernal, I., & Lalancette, R. (2022). Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct. European Journal of Chemistry, 13(2), 168-171. doi:10.5155/eurjchem.13.2.168-171.2278
Arslan, Evrim, Ivan Bernal, & Roger Lalancette. "Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct." European Journal of Chemistry [Online], 13.2 (2022): 168-171. Web. 19 Aug. 2022
Arslan, Evrim, Bernal, Ivan, AND Lalancette, Roger. "Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct" European Journal of Chemistry [Online], Volume 13 Number 2 (30 June 2022)

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