Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct

Evrim Arslan; Ivan Bernal; Roger Lalancette

doi:10.5155/eurjchem.13.2.168-171.2278

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Published: Jun 30, 2022

DOI: https://doi.org/10.5155/eurjchem.13.2.168-171.2278

Keywords:

Triazines, Formamide, X-ray diffraction, Metal basic adduct, Magnetic properties, Vanadyl acetylacetonates

Section

Research Article

Issue

Vol. 13 No. 2 (2022): June 2022

Dates

Received 2022-03-22
Accepted 2022-05-08
Published 2022-06-30

Evrim Arslan

Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA

https://orcid.org/0000-0001-9712-3573

Ivan Bernal

Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, 2050 Johannesburg, ZA, South Africa

https://orcid.org/0000-0002-8168-5907

Roger Lalancette

Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA

https://orcid.org/0000-0002-3470-532X

Abstract

A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca2₁, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.

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Arslan, E.; Bernal, I.; Lalancette, R. Vanadyl(acetylacetonate)2 Mediated Hydrolytic Splitting of 1,3,5-Triazine in a Solution of Toluene at 130 °C: The Crystal Structure of Its Axial Formamide Adduct. Eur. J. Chem. 2022, 13, 168-171.

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Supporting Agencies

The National Science Foundation for NSF-CRIF Grant No. 0443538 and Rutgers University, 73 Warren St., Newark, NJ, 07102, USA.

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