European Journal of Chemistry 2023, 14(1), 109-113 | doi: https://doi.org/10.5155/eurjchem.14.1.109-113.2390 | Get rights and content

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Synthesis and crystal structure of the copper (II) carboxylate with 2,2-bipyridine, [Cu(4-mba)2(bipy)(H2O)]


Sibel Demir Kanmazalp (1,*) orcid , Adnan Qadir (2) orcid , Necmi Dege (3) orcid

(1) Naci Topçuoğlu Vocational School, Biomedical Device Technology Program, Gaziantep University, Gaziantep, 27600, Turkey
(2) Department of Chemistry, College of Science, Salahaddin University, Erbil, 44001, Iraq
(3) Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Samsun, Turkey
(*) Corresponding Author

Received: 22 Dec 2022 | Revised: 11 Jan 2023 | Accepted: 25 Jan 2023 | Published: 31 Mar 2023 | Issue Date: March 2023

Abstract


The new Cu(II) carboxylate complex, aqua(2,2'-bipyridine-κ2N,N')bis(4-methylbenzoato-κO)copper(II) [Cu(4-mba)2(bipy)(H2O)] (4-mba: 4-methylbenzoate, bipy: 2,2'-bipyridine) was synthesized, and the molecular structure of the complex was characterized by the single crystal X-ray diffraction technique. The X-ray diffraction analysis indicated that the asymmetric unit comprises an independent molecule. Crystal data for [Cu(4-meb)2(2,2-bipy)(H2O)]: Triclinic, space group P-1 (no. 2), a = 7.0452(13) Å, b = 11.260(2) Å, c = 16.635(3) Å, α = 103.543(7)°, β = 91.002(7)°, γ = 104.106(6)°, V = 1240.4(4) Å3, Z = 2, T = 296 K, μ(MoKα) = 0.918 mm-1, Dcalc = 1.360 g/cm3, 51364 reflections measured (5.054° ≤ 2Θ ≤ 57.38°), 6258 unique (Rint = 0.0398, Rsigma = 0.0284) which were used in all calculations. The final R1 was 0.0392 (I > 2σ(I)) and wR2 was 0.1021 (all data). The Cu(II) ion was found to be coordinated with two nitrogen atoms of the 2,2'-bipyridine ligand, two oxygen atoms of the 4-methyl benzoate molecule, and one oxygen atom of the aqua ligand. In the three-dimensional supramolecular architecture, molecules are connected through pairs of O-H···O and C-H···O intermolecular interactions, consisting of chains. The molecule also demonstrates Cg···Cg intermolecular interactions between six-membered rings of 2,2'-bipyridine.


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European Journal of Chemistry

Keywords


Synthesis; Carboxylate; Cu(II) complex; Crystal structure; Single-crystal XRD; Hydrogen bonding

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DOI: 10.5155/eurjchem.14.1.109-113.2390

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The Scientific and Technological. Research Application and Research Center, Sinop University, Sinop, Turkey.

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How to cite


Kanmazalp, S.; Qadir, A.; Dege, N. Eur. J. Chem. 2023, 14(1), 109-113. doi:10.5155/eurjchem.14.1.109-113.2390
Kanmazalp, S.; Qadir, A.; Dege, N. Synthesis and crystal structure of the copper (II) carboxylate with 2,2-bipyridine, [Cu(4-mba)2(bipy)(H2O)]. Eur. J. Chem. 2023, 14(1), 109-113. doi:10.5155/eurjchem.14.1.109-113.2390
Kanmazalp, S., Qadir, A., & Dege, N. (2023). Synthesis and crystal structure of the copper (II) carboxylate with 2,2-bipyridine, [Cu(4-mba)2(bipy)(H2O)]. European Journal of Chemistry, 14(1), 109-113. doi:10.5155/eurjchem.14.1.109-113.2390
Kanmazalp, Sibel, Adnan Qadir, & Necmi Dege. "Synthesis and crystal structure of the copper (II) carboxylate with 2,2-bipyridine, [Cu(4-mba)2(bipy)(H2O)]." European Journal of Chemistry [Online], 14.1 (2023): 109-113. Web. 31 May. 2023
Kanmazalp, Sibel, Qadir, Adnan, AND Dege, Necmi. "Synthesis and crystal structure of the copper (II) carboxylate with 2,2-bipyridine, [Cu(4-mba)2(bipy)(H2O)]" European Journal of Chemistry [Online], Volume 14 Number 1 (31 March 2023)

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European Journal of Chemistry 2023, 14(1), 109-113 | doi: https://doi.org/10.5155/eurjchem.14.1.109-113.2390 | Get rights and content

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