European Journal of Chemistry

Facile Heck coupling synthesis and characterization of a novel tris(4-(pyridine-4-vinyl)phenyl)methylsilane tridentate core


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Okpara Sergeant Bull
Chioma Don-Lawson


Aromatic rigid ligands with carboxylate, phosphate, or pyridyl terminals are highly important today for application in the manufacturing of metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and other supramolecular structures. Aromatic rigid ligands give rigidity to MOFs and COFs materials. In addition, building units are important in that their judicious selection can result in a 2-D or 3-D framework with moderate or high surface area. Most aromatic linkers are based on carbon centres which are associated with a negative impact on the environment. However, in contrast, silicon-based centres are scarce and benign to the environment, even though they can be prepared facilely via metathesis. Here, we report the facile preparation of a new tris (4-(pyridine-4-vinyl)phenyl) methylsilane using the classical Heck coupling reaction. The bridging ligand was synthesized via the standard Heck coupling of 4-vinylpyridine with tris(4-bromophenyl)(methyl)silane.

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Bull, O. S.; Don-Lawson, C. Facile Heck Coupling Synthesis and Characterization of a Novel tris(4-(pyridine-4-vinyl)phenyl)methylsilane Tridentate Core. Eur. J. Chem. 2024, 15, 71-73.

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[1]. Bull, O. S.; Okpa, E. Application of green chemistry for the one-pot preparation of Tris (4-bromophenyl) chlorosilane. Int. J. Appl. Chem. 2023, 10, 1-5.

[2]. Amoroso, A. J.; Maher, J. P.; McCleverty, J. A.; Ward, M. D. Magnetic spin exchange interactions between several metal centres in paramagnetic complexes with new polynucleating bridging ligands. J. Chem. Soc. Chem. Commun. 1994, 1273-1275.

[3]. Bull, O. S.; Bull, I.; Amadi, G. K.; Obaalologhi Odu, C.; Okpa, E. O. A review on metal- organic frameworks (MOFS), synthesis, activation, characterisation, and application. Orient. J. Chem. 2022, 38, 490-516.

[4]. Bull, O. S. Solvothermal Synthesis and Characterization of a New 3D Potassium Metal-Organic Framework (MOF) Structure. J. Chem. Soc. Niger. 2020, 45, 126-134.

[5]. Sergeant Bull, O.; Monsuru Adewale, S.; Okpa, E. Production of biodiesel from waste cooking oil using A zinc-based metal-organic framework (Zn-MOF) as catalyst. Int. J. Appl. Chem. 2024, 11, 1-6.

[6]. Bull, O. S.; Bull, I.; Amadi, G. K.; Odu, C. O. Covalent Organic Frameworks (COFS): A Review. J. Appl. Sci. Environ. Manage. 2022, 26, 145-179.

[7]. Li, J.-R.; Ma, Y.; McCarthy, M. C.; Sculley, J.; Yu, J.; Jeong, H.-K.; Balbuena, P. B.; Zhou, H.-C. Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord. Chem. Rev. 2011, 255, 1791-1823.

[8]. Prasad, T. K.; Suh, M. P. Control of interpenetration and gas‐sorption properties of metal-organic frameworks by a simple change in ligand design. Chemistry 2012, 18, 8673-8680.

[9]. Xie, Z.; Xu, W.; Cui, X.; Wang, Y. Recent progress in metal-organic frameworks and their derived nanostructures for energy and environmental applications. ChemSusChem 2017, 10, 1645-1663.

[10]. Evans, J. D.; Garai, B.; Reinsch, H.; Li, W.; Dissegna, S.; Bon, V.; Senkovska, I.; Fischer, R. A.; Kaskel, S.; Janiak, C.; Stock, N.; Volkmer, D. Metal-organic frameworks in Germany: From synthesis to function. Coord. Chem. Rev. 2019, 380, 378-418.

[11]. Odu, C. O.; Obunwo, C. C.; Bull, O. S. Solvothermal synthesis and characterization of terephthalic acid-based metal-Organic Frameworks and their catalytic application in biodiesel production. Journal of Chemical Society of Nigeria 2023, 48, 474-483.

[12]. Gangu, K. K.; Maddila, S.; Mukkamala, S. B.; Jonnalagadda, S. B. A review on contemporary Metal-Organic Framework materials. Inorganica Chim. Acta 2016, 446, 61-74.

[13]. Braga, D.; Grepioni, F. Making crystals from crystals: a green route to crystal engineering and polymorphism. Chem. Commun. (Camb.) 2005, 3635-3645.

[14]. Furukawa, H.; Kim, J.; Ockwig, N. W.; O'Keeffe, M.; Yaghi, O. M. Control of vertex geometry, structure dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline Metal−Organic frameworks and polyhedra. J. Am. Chem. Soc. 2008, 130, 11650-11661.

[15]. Bull, O. S.; Bull, I.; Amadi, G. K. Global Warming and technologies for carbon capture and storage. J. Appl. Sci. Environ. Manage. 2020, 24, 1671-1686.

[16]. Bull, O. S.; Lickiss, P.; Davies, R. Silicon-Containing Cofs and Mofs for Co2 Capture, Imperial College London: Great Britain, 2018. (accessed February 21, 2023).

[17]. Wang, D.; Niu, Y.; Wang, Y.; Han, J.; Feng, S. Tetrahedral silicon-centered imidazolyl derivatives: Promising candidates for OLEDs and fluorescence response of Ag (I) ion. J. Organomet. Chem. 2010, 695, 2329-2337.

[18]. Wander, M.; Hausoul, P. J. C.; Sliedregt, L. A. J. M.; van Steen, B. J.; van Koten, G.; Klein Gebbink, R. J. M. Synthesis of polyaryl rigid-core carbosilane dendrimers for supported organic synthesis. Organometallics 2009, 28, 4406-4415.

[19]. Gontarczyk, K.; Durka, K.; Klimkowski, P.; Luliński, S.; Serwatowski, J.; Woźniak, K. Synthesis and characterization of di-, tri- and tetraboronic acids based on phenyl- and thienylsilane cores. J. Organomet. Chem. 2015, 783, 1-9.

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