European Journal of Chemistry

Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent

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Published: Sep 30, 2011
DOI: https://doi.org/10.5155/eurjchem.2.3.324-330.272
Keywords:
Complexation, Salophen’s derivatives, DMF, Spectrophotometric study, KINFIT program, Metal ions
Section
Research Article
Issue
Vol. 2 No. 3 (2011): September 2011
Dates
Received 2010-09-04
Accepted 2010-12-08
Published 2011-09-30


Main Article Content

Ardeshir Shokrollahi
Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran
Mehrourang Ghaedi
Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran
Sara Alipour
University of Applied Science and Technology, Pasargad Branch, Saadatshahr, 73741-173, Iran
Ali Hossein Kianfar
Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran

Abstract

The complexation behaviour of some salophen,s derivatives with few transition and heavy metal cations in N,N'-dimethyl formamid as nonaqueous solvent at 25 oC and 0.05 M tetra ethylammonium perchlorate to investigate the effect of structure were studied by spectrophotometric method. The formation of complexes between ligands and metal ions of the types ML, ML2 or M2L was observed. The overall stability constants of such complexes were evaluated by computer refinement of absorption-mole ratio data using the KINFIT program.

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Shokrollahi, A.; Ghaedi, M.; Alipour, S.; Kianfar, A. H. Spectrophotometric Study of Complexation Between a Series of Salophens and Some Transition Metal Ions in DMF Solvent. Eur. J. Chem. 2011, 2, 324-330.

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