European Journal of Chemistry

Crystal structure of N,N,N',N'-tetramethylethylenediammonium dinitrate



Main Article Content

Zaouali Zgolli Donia
Hbib Boughzala
Ahmed Driss

Abstract

N,N,N',N'-tetramethylethylenediammonium dinitrate has been synthesized. The crystal and molecular structure of the title compound has been determined from single crystal X-ray diffraction data. C6H18N4O6, M =242.24, Triclinic, a = 6.040(2) Å, b = 6.834(3) Å, c = 7.867(2) Å, α = 74.1120(10)°, β = 83.700(2)°, γ = 80.314(2)°, V = 307.12(19) Å3, T = 298(2) K, space group P-1 (no. 2), Z = 1, μ(Mo-Kα) = 0.115, 2383 reflections measured, 1342 unique (Rint = 0.0169) which were used in all calculations. The final wR(F2) was 0.1262 (all data). In the title compound, C6H18N22+.2NO3-, both N atoms of the cationic moiety are protonated and linked via hydrogen bonds to two trigonal planar nitrate anions. Two types of classical hydrogen bonds are observed: N1-H…O1 and N1-H…O2. These bonds link the cations and the anions together, forming a one-dimensional network and reinforcing the cohesion of the ionic structure.

2_3_314_316_800


icon graph This Abstract was viewed 1153 times | icon graph Article PDF downloaded 584 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Donia, Z. Z.; Boughzala, H.; Driss, A. Crystal Structure of N,N,N’,N’-Tetramethylethylenediammonium Dinitrate. Eur. J. Chem. 2011, 2, 314-316.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Gessner, V. H.; Daschlein, C.; Strohmann, C. Acta Cryst. 2009, E65, o383-o383.

[2]. Gessner, V. H.; Strohmann, C. J. Am. Chem. Soc. 2008, 130, 14412-14413.
http://dx.doi.org/10.1021/ja8058205
PMid:18842047

[3]. Kohler, F. H; Hertkorn, N. J. Blumel. Chem. Ber. 1987, 120, 2081-2082.

[4]. Misra, T. K.; Cheng, J.; Liao, F. L.; Lu, T. H.; Chung, C. S. J. Coord. Chem. 2007, 60, 1855-1866.
http://dx.doi.org/10.1080/00958970701203107

[5]. Nastase, S.; Tuna, F.; Maxim, C.; Muryn, C. A.; Avarvari, N.; Winpenny, R. E. P.; Andruh, M. Cryst. Growth Des. 2007, 7, 1825-1831.
http://dx.doi.org/10.1021/cg070332g

[6]. Sheldrick, G. M. SHELXS-97 a Program for Crystal Structure Determination, University of Gottingen, Germany. 1997.

[7]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 2, 837-838.
http://dx.doi.org/10.1107/S0021889899006020

[8]. DIAMOND - Visual Crystal Structure Information System CRYSTAL IMPACT, Postfach 1251, D-53002, Bonn.

[9]. Lin, J.; Xu, Y.; Shi, T.; Liu, D.; Chen, W. Acta Cryst. 2008, E64, o129-o129.

[10]. Kabak, M.; Elerman, Y.; Ãnaleroglu, C.; Mert, Y.; Durlu, T. N. Acta Cryst. 2000, C56, e66-e67.

[11]. Annan, T. A.; Chadha, R. K; Tuck, D. G. Acta Cryst. 1991, C47, 151-153.

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).