European Journal of Chemistry

Kinetics and mechanism of oxidation of n-butylamine and 1,3-propanediamine by potassium ferrate



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Jinhuan Shan
Yafeng Yang
Jinhuan Shan

Abstract

The kinetics of oxidation of n-butylamine and 1,3-propanediamine by home-made potassium ferrate(VI) at different conditions has been studied spectrophotometrically in the temperature range of 283.2-298.2 K. The results show first order dependence on potassium ferrate (VI) and on each reductant. The observed rate constant (kobs) decreases with the increase of [OH-], and the reaction rate has a negative fraction order with respect to [OH-]. A plausible mechanism is proposed and the rate equations derived from the mechanism was shown to fit all the experimental results. The rate constants of the rate-determining step and the thermodynamic activation parameters are calculated.

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Shan, J.; Yang, Y.; Shan, J. Kinetics and Mechanism of Oxidation of N-Butylamine and 1,3-Propanediamine by Potassium Ferrate. Eur. J. Chem. 2011, 2, 342-346.

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References

[1]. Jiang, J. Q.; Lloyd, B. Water Res. 2002, 36, 1397-1408.
http://dx.doi.org/10.1016/S0043-1354(01)00358-X

[2]. Jiang, J. Q.; Alex, P.; Mike B. J. Eniron. Managem. 2006, 79(2), 215-220.
http://dx.doi.org/10.1016/j.jenvman.2005.06.009
PMid:16182439

[3]. Li, C.; Li, X. Z.; Graham N. Water Res. 2008, 42(1-2), 109-120.
http://dx.doi.org/10.1016/j.watres.2007.07.023
PMid:17681362

[4]. Zhang, J.; Shi, Q. L.; Yang, G. M. Environ. Prot. Chem. Ind. 2000, 20, 44-47.

[5]. Sharma, V. K.; Burnett, C. R.; Yngard, R. A. Environ. Sci. Technol. 2005, 39(10), 3849-3854.
http://dx.doi.org/10.1021/es048196g

[6]. Sharma, V. K. Adv. Environ. Res. 2002, 6(2), 143-156.
http://dx.doi.org/10.1016/S1093-0191(01)00119-8

[7]. Sharma, V. K.; Smith, J. O.; Millero, F. J. Environ. Sci. Technol. 1997, 31, 2486-2491.
http://dx.doi.org/10.1021/es960755z

[8]. James, D. C. Environ. Sci. Technol. 1981, 15, 184â187.

[9]. James, D. C. Trans. Metal Chem. 1986, 11, 116-117.
http://dx.doi.org/10.1007/BF00623768

[10]. James, D. C.; Kelter, P. B. Anal. Chem. 1979, 51(11), 1828â1834.

[11]. Goff, H.; Murmann, R. K. J. Am. Chem. Soc. 1971, 93, 6058-6065.
http://dx.doi.org/10.1021/ja00752a016

[12]. Bielski, B. H. J.; Sharma, V. K. Inorg. Chem. 1991, 30, 4306-4310.
http://dx.doi.org/10.1021/ic00023a005

[13]. Bielski, B. H. J.; Rush, J. D. Free Radical Res. 1995, 22, 571-579.
http://dx.doi.org/10.3109/10715769509150329
PMid:7633578

[14]. Johnson, M. D.; Reed, J. F. Inorg. Chem. 1996, 35, 6795-6799.
http://dx.doi.org/10.1021/ic960480o
PMid:11666845

[15]. Meng, Y.; Xu, Z. S.; Chen, L. G.; Li, Y.; Dong, F. J. Chem. Ind. Eng. 1998, 15(4), 44-48.

[16]. Thompson, G. W.; Ockerman, L. T.; Schreyer, J. M. J. Am. Chem. Soc. 1951, 73, 1379-1381.
http://dx.doi.org/10.1021/ja01147a536

[17]. Dong, W. X. Detection of all kinds of Ions in the Chemical Method, Beijing Normal University Press, Beijing, 1984, pp. 94.

[18]. Han, B. X. Rapid detection method of inorganic ions, People's education press, Beijing, 1979, pp. 10.

[19]. Han, D. G.; Gao, P. L. Foundation of chemical kinetics, Beijing University Press, Beijing, 1987, pp. 212.

[20]. James, D. C.; Kelter, P. B.; Tabatabai, A.; Spichal, D.; Erickson, J.; McLaughlin, C. W. Environ. Impact Health Eff. 1985, 5, 1285â1298.

[21]. Jezowska-Trzebiatowska, B. Catal. Chem. Kinet. 1964, 212-217.

[22]. Shan, J. H.; Liu, T. Y. Acta Chem. Sinica. 1994, 52, 1140-1144.

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