Solvatochromism and potentiometic studies of some active nitroso- and nitroso-azo- compounds

Mamdouh Saad Masoud; Ekram Abd El-Moniem Khalil; Saeda Abou El-Thana Abou El Enein; Hesham Mostafa Kamel

doi:10.5155/eurjchem.2.3.420-432.407

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Published: Sep 30, 2011

DOI: https://doi.org/10.5155/eurjchem.2.3.420-432.407

Keywords:

Nitroso, Pyridin-6-ylazo, Triazene, Effect of solvents, Potentiometry, Spectrophotometry

Section

Review Article

Issue

Vol. 2 No. 3 (2011): September 2011

Dates

Received 2011-02-16
Accepted 2011-04-16
Published 2011-09-30

Mamdouh Saad Masoud

Chemistry Department, Faculty of Science, Alexandria University, Alexandria, 21547, Egypt

Ekram Abd El-Moniem Khalil

Chemistry Department, Faculty of Science, Alexandria University, Alexandria, 21547, Egypt

Saeda Abou El-Thana Abou El Enein

Chemistry Department, Faculty of Science, Minufiya University, Shebin El-Kom, 32511, Egypt

Hesham Mostafa Kamel

Chemistry Department, Faculty of Science, Alexandria University, Alexandria, 21547, Egypt

Abstract

The stability studies of biologically active 2,4-dinitrosoresorcinol, o-carboxy phenylazo-dinitrosoresorcinol, N,N`-bis-[4,4`-(1,3-diphenyltriazine)]-diacetamide, 2-amino-6-phenylazo-pyridin-3-ol, 2-amino-3-hydroxy-pyridin-6-ylazo)-benzoic acid, 4-(2-amino-3-hydroxy-pyridin-6-ylazo)-benzoic acid ethyl ester and N-[4-(2-amino-3-hydroxy-pyridin-6-ylazo)-phenyl]-acetamide compounds were studied. The dissociation constants were determined potentiometrically. The thermodynamic parameters of dissociation were evaluated. Regression analysis is applied for correlating the different parameters. The results help to assign the solute-solvent interactions and the solvatochromic potential of the investigated compounds. The electronic character of the substituent and the chemical nature of the solvent are major factors for the observed solvatochromism.

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Masoud, M. S.; Khalil, E. A. E.-M.; El Enein, S. A. E.-T. A.; Kamel, H. M. Solvatochromism and Potentiometic Studies of Some Active Nitroso- and Nitroso-Azo- Compounds. Eur. J. Chem. 2011, 2, 420-432.

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