European Journal of Chemistry

Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene

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Published: Mar 31, 2012
DOI: https://doi.org/10.5155/eurjchem.3.1.57-64.448
Keywords:
EPR, Antimicrobial, Molecular modeling, Potential separation, Splitting parameters, Coordination entities
Section
Research Article
Issue
Vol. 3 No. 1 (2012): March 2012
Dates
Received 2011-04-24
Accepted 2011-06-17
Published 2012-03-31


Main Article Content

Rajiv Kumar
Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India
Rajni Johar
Department of Chemistry, Guru Govind Singh Indraprashtha University, New Delhi, 110002, India
Anil Krishan Aggarwal
Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India

Abstract

9,17-Diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene, macrocycle was synthesized, thereafter formulation and designing strategies applied for the preparation of coordination entities of Co(II) and Ni(II). Coordination behaviour of N2S4 donor macrocycle towards metal ion(s) was assessed by physiochemical measurements and spectral investigations viz. elemental analysis, molar conductance, magnetic susceptibility measurements, infrared, UV-Vis, 1H and 13 C NMR, mass spectroscopy, electron paramagnetic resonance (EPR), cyclic voltammetry and molecular modeling. Side-by-side comparison of the spectral findings exposed different geometrical aspects of macrocycle and coordination entities. Cyclic voltammogram showed fully oxidized and reduced species in one unified experiment. Macrocycle and coordination entities were screened for antimicrobial effectiveness (antifungal properties against Aspergillus-niger).

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Kumar, R.; Johar, R.; Aggarwal, A. K. Synthesis, Structural Elucidation and Antimicrobial Effectiveness of Coordination Entities of Cobalt (II) and Nickel (II) Derived from 9,17-Diaza-2,6,11,15-Tetrathia-1,7,10,16-(1,2)-Tetrabenzenacyclooctadecaphan-8,17-Diene. Eur. J. Chem. 2012, 3, 57-64.

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Central Science Library, University Delhi, Delhi, India, Indian Institute of Technology Bombay and Indian Institute of Technology Delhi,
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