European Journal of Chemistry

Flotation-separation of toxic metal ions from aqueous solutions using thiosemicarbazide derivatives as chelating agents and oleic acid as a surfactant



Main Article Content

Shaban El-Sayed Ghazy
Gaber Mohamed Abu El-Reash
Ola Ahmed Al-Gammal
Tarek Mohamed Yousef

Abstract

A simple and rapid procedure was developed for flotation-separation of toxic metal ions namely Hg2+, Mn2+ and Cd2+ from aqueous solutions. Thiosemicarbazide derivatives such as: 1-(amino-N-phenylmethanethio)-4-(pyridine-2-yl)thiosemicarbazide (H2PPS), N-phenyl-2-(pyridine-2-ylcarbamothioyl)hydrazinecarboxamide (H2PBO), 1-(amino(thioformyl)-N-phenylform)-4-(pyridine-2-yl)thiosemicarbazide (H2APO), and 1-(amino-N-(pyridine-3-yl) methanethio)-4-(pyridine-2-yl)thiosemicarbazide (H2PPY) have been used as organic chelating agents and oleic acid (HOL) as a surfactant. The different parameters affecting the flotation process namely, metal ion, ligands and surfactant concentrations, foreign ions (which are normally present in fresh and saline waters), pH and temperature are examined. About 100% of mercury, cadmium and manganese ions float at room temperature (~ 25 oC), at a metal:ligand ratio of 1:2  and at pH ~5. The procedure was successfully applied to recover Hg2+, Mn2+ and Cd2+ ions spiked into some water samples. The flotation mechanism is suggested based on some physical and chemical studies on the ligands and metal-complexes isolated from the floated layers.

1_2_76_82_800


icon graph This Abstract was viewed 1818 times | icon graph Article PDF downloaded 791 times

How to Cite
(1)
Ghazy, S. E.-S.; Abu El-Reash, G. M.; Al-Gammal, O. A.; Yousef, T. M. Flotation-Separation of Toxic Metal Ions from Aqueous Solutions Using Thiosemicarbazide Derivatives As Chelating Agents and Oleic Acid As a Surfactant. Eur. J. Chem. 2010, 1, 76-82.

Article Details

Author Biographies

Shaban El-Sayed Ghazy, Department of Chemistry, Faculty of ScienceMansoura University, Mansoura-35516, Egypt

Shaban El-Sayed Ghazy is a Professor of Analytical Chemistry in the Department of Chemistry, Faculty of Science, Mansoura University. He also serves as Head of the Analytical group and as supervisor of the Environment Lab in the same department. His research interests include applications of flotation and sorption techniques in the field of wastewater treatment, pre-concentration prior to AAS and spectrophotometric determination and removal of pollutants from water samples. He has published more than 80 research papers in specialised journals

Gaber Mohamed Abu El-Reash, Department of Chemistry, Faculty of ScienceMansoura University, Mansoura-35516, Egypt

Gaber Mohamed Abu El-Reash is a professor of Inorganic Chemistry in the Department of Chemistry, Faculty of Science, Mansoura University. His research interests are in the field of preparing ligands, their metal complexes and thier analytical and biological applications.

Ola Ahmed Al-Gammal, Department of Chemistry, Faculty of ScienceMansoura University, Mansoura-35516, Egypt

Ola Ahed Al-Gammal is a Lecturer in the Department of Chemistry, Faculty of Science, Mansoura University. His research interests is in the field of preparing ligands, their metal complexes and thier analytical and biological applications.

Tarek Mohamed Yousef, Department of Chemistry, Faculty of ScienceMansoura University, Mansoura-35516, Egypt

Tarek Yousef is a researcher in Forensic Medicine,

He is pursuing his Ph.D. thesis under the supervision of Professor S.E. Ghazy, Professor Gaber Mohamed Abu El-Reess and Dr. Ola Ahmed Al-Gammal.

 

Share
Crossref - Scopus - Google - European PMC
References

[1]. Sitting, M. Hand Book of Toxic and Hazardous Chemicals, Noyes Publications, Park Ridge, NJ, 1981.

[2]. Kadirvelu, K.; Thamaraislvi, K.; Namasivayam, C. Sep. Purif. Technol. 2001, 24, 497-505.
doi:10.1016/S1383-5866(01)00149-6

[3]. Hasar, H. J. Hazard. Mater. 2003, 97, 49-57.
doi:10.1016/S0304-3894(02)00237-6

[4]. Al-Asheh, S.; Duvnjak Z. Sep. Sci. Technol, 1997, 33, 1303-1329.
doi:10.1080/01496399808544985

[5]. Gksungure, Y.; Uren, S.; Güvenc, U. Bioresource Technol. 2005, 96, 103-109.
doi:10.1016/j.biortech.2003.04.002
PMid:15364087

[6]. Kim, J. S.; Akeprathumchia, S.; Wickrasinghe, S. J. Member. Sci. 2001, 182, 161- 172.
doi:10.1016/S0376-7388(00)00564-0

[7]. Blöcher, C.; Dorda, J.; Mavrov, V.; Chmiel, H.; Lazaridis, N. K.; Matis, K. A. Water Res. 2003, 37, 4018-4026.
doi:10.1016/S0043-1354(03)00314-2

[8]. Ghazy, S. E. Sep. Sci. Technol. 1995, 30, 933-947.
doi:10.1080/01496399508015408

[9]. Sorensen, E. M. B. Metal Poisoning in Fish, CRC Press Inc, Boca Raton, Florida, 1991.

[10]. Ghazy, S. E.; Mostafa G.A. E. Canadian J. Anal. Sci. Spect. 2008 53, 28-35.

[11]. Chubar, N.; Carvalho, J. R.; Correia, M. J. N. Colloids and Surfaces A, 2003, 230, 57-65.
doi:10.1016/j.colsurfa.2003.09.014

[12]. Aschner, M.; Erikson, K. M.; Dorman, D. C. J. Crit. Rev. Toxicol. 2005, 35, 1–32.
doi:10.1080/10408440590905920
PMid:15742901

[13]. Quintanar, L. Inorg. Chim. Acta 2008, 361, 875-884.
doi:10.1016/j.ica.2007.09.008

[14]. Mizuike, A. Fresenius' J. Anal. Chem. 1986, 324, 672-677.
doi:10.1007/BF00468377

[15]. Leyden, D. E.; Wegscheider, W. Anal. Chem. 1981, 53, 1059A-1065A.
doi:10.1021/ac00232a002

[16]. Zouboulis, A. I.; Lazaridis, N. K.; Zamboulis, D. Sep. Sci. Technol.1994, 29, 385-400.
doi:10.1080/01496399408002490

[17]. Stoica, L.; Dinculescu, M.; Plapcianu, C.G. Water Res. 1998, 32, 3021-3030.
doi:10.1016/S0043-1354(98)00065-7

[18]. Rubio, J.; Souza, M. L.; Smith, R. W. Minerals Eng., 2002, 15, 139-155.
doi:10.1016/S0892-6875(01)00216-3

[19]. Doyle, F. M. Int. J. Miner. Process. 2003, 72, 387-399.
doi:10.1016/S0301-7516(03)00113-3

[20]. Doyle, F. M.; Liu, Z. J. Colloid Interface Sci. 2003, 258, 396-403.
doi:10.1016/S0021-9797(02)00092-9

[21]. Cora, M. G.; Hung, Y-T. Int. J. Environ. Eng. 2009, 1, 3-19.
doi:10.1504/IJEE.2009.026439

[22]. Kidkoro, T.; Matusi, K.; Ishiwata, S.; Sasaki, T. Bull. Chem. Soc. Jpn. 1988, 61, 1505-1508.
doi:10.1246/bcsj.61.1505

[23]. Kabil, M. A. Fresenius J. Anal. Chem. 1994, 348, 246-247.
doi:10.1007/BF00325367

[24]. Voyce, D.; Zeitlin, H. Anal. Chim. Acta 1974, 69, 27-34.
doi:10.1016/0003-2670(74)80004-8

[25]. Feng, X.; Ryan, D.E. Intern. J. Environ. Anal. Chem. 1985, 19, 273–280.
doi:10.1080/03067318508077038
PMid:4008161

[26]. Ghazy, S. E.; Rakha, T.H.; El-Kady, E. M.; El-Asmy, A. A. Indian J. Chem. Technol. 2000, 7, 178-182.

[27]. Clarke, A. N.; Wilson, D. J. Sep. Purif. Reviews 1978, 7, 55 – 98.
doi:10.1080/03602547808066055

[28]. Mathew, L.; Reddy, M. L.; Prasada Rao, T.; Iyer, C.S.P.; Damodaran, A.D. Microchimica Acta 1997, 127, 125-128.
doi:10.1007/BF01243176

[29]. Ghazy, S. E. Sep. Sci. Technol. 1994, 29, 935-941.
doi:10.1080/01496399408006637

[30]. Ghazy, S. E.; Kabil, M. A.; Shallaby, A. M.; Ammar, N. S. Indian J. Chem. Technol. 2001, 8, 211-218.

[31]. Akl, M. A.; Khalifa, M. E.; Ghazy, S. E.; Hassanien, M. M. Anal. Sci. 2002, 18, 1235-1240.
doi:10.2116/analsci.18.1235
PMid:12458709

[32]. Pavlovska, G.; Čundiva, K.; Stafilov, T.; Zendelovska, D. Sep. Sci. Technol. 2003, 38, 1111-1124.
doi:10.1081/SS-120018126

[33]. Ulewicz, M.; Walkowiak, W.; Krystyna Brandt, K.; Porwolik-Czomperlik, I. Sep. Sci. Technol. 2003, 38, 633-645.
doi:10.1081/SS-120016655

[34]. Jurkiewicz, K. Colloids and Surfaces A 2006, 276, 207–212.
doi:10.1016/j.colsurfa.2005.09.047

[35]. Scorzelli, I. B.; Fragomeni, A. L.; Torem, M.L. Minerals Eng. 1999, 12, 905-917.
doi:10.1016/S0892-6875(99)00077-1

[36]. Matis, K. A.; Zouboulis, A.I. Biotechnol. Bioeng. 2004, 44, 354-360.
doi:10.1002/bit.260440313
PMid:18618752

[37]. Ulewicz, M.; Walkowiak, W.; Bartsch, R. A. Sep. Purif. Technol. 2006, 48, 264–269.
doi:10.1016/j.seppur.2005.07.037

[38]. Hiraide, M.; Ito, T.; Baba, M.; Kawaguchi, H.; Mizuike, A. Anal. Chem. 1980, 52, 804–807.
doi:10.1021/ac50056a008

[39]. Mumallah, N. A.; Wilson, D. J. Sep. Sci. Technol. 1981, 16, 213-228.
doi:10.1080/01496398108068514

[40]. Zendelovska, D.; Čundeva, K.; Stafilov, T. Microchimica Acta 2000, 135, 1436-5073.
doi:10.1007/s006040070018

[41]. Tuzen, M.; Soylak, M. J. Hazardous Materials 2009, 162, 724-729.
doi:10.1016/j.jhazmat.2008.05.087

[42]. Gregory, O. J.; Barnett, S. M.; Deluise, F. J. Sep. Sci. Technol. 1980, 15, 1499–1512.
doi:10.1080/01496398008055602

[43]. Moruzzi, R.; Reali, M. A. P.; Patrizzi, L. J. A Different View of Removing Iron and Manganese Complexes Using Dissolved Air Flotation, In Young Researchers, 2004, Edited by Lens. P.; Stuetz, R. IWA Publishing, London, UK, pp. 259-266.

[44]. Ghazy, S. E.; Kabil, M. A. Bull. Chem. Soc. Jpn. 1994, 67, 474-478.
doi:10.1246/bcsj.67.2098

[45]. Marczenko, Z. Separation and Spectrophotometric Determination of Elements, John Wiley & Sons, New York, Toronto 1986.

[46]. Mohsen, A.; Omar, M. E.; Labouta, I. M.; Kasem, M. G.; Boudais, J. J. Pharm. Sci. 1983, 72, 1226-1228.
doi:10.1002/jps.2600721034
PMid:6644581

[47]. West, D. X.; Swearingen, J. K.; El-Swaf, A. K. Trans. Met. Chem. 2004, 29, 80-83.

[48]. Ghazy, S. E; Samra, S. E.; Mahdy, A. M.; El-Morsy, S. M. Anal. Sci. 2006, 22, 377-382.
doi:10.2116/analsci.22.377

[49]. Klassen, V. I.; Mokrousov, V. A. An Introduction to the Theory of Flotation, Butterworths, London, 1963.

[50]. Caballero, M.; Cela, R.; Perez-Bustamante, J. A. Talanta 1990, 37, 275-300.
doi:10.1016/0039-9140(90)80056-L

[51]. Ramachandra, R. S. Surface Chemistry of Froth Flotation, Vol. 2 Reagents and Mechanisms, 2nd ed., Kluer Academic/Plenum Puplishers, New York, 1982.

[52]. Pol’kin, S. I.; Berger, G. S.; Revazashavili, I. B.; Shchepkina, M. M. Izv. Vyssh. Ucheb. Zaved., Tsvet. Met., 1968, 11, 6-11.

[53]. Ghazy, S. E.; Mostafa, H. A.; El-Farra, S. A.; Fouda, A. S. Indian J. Chem. Technol. 2004, 11, 787-792.

Supporting Agencies

Mansoura University, Faculty of Science, Chemistry Department, Egypt
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).