Synthesis of an E-BODIPY based fluorescent Co-polymer containing organoboron quinolate units

Priya Hewavitharanage; Prince Nzeata; Jeffrey Wiggins

doi:10.5155/eurjchem.3.1.13-16.543

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Published: Mar 31, 2012

DOI: https://doi.org/10.5155/eurjchem.3.1.13-16.543

Keywords:

BODIPY, Stokes shift, Fluorescence, Donor-acceptor, Energy transfer, Organoboron quinolate

Section

Research Article

Issue

Vol. 3 No. 1 (2012): March 2012

Dates

Received 2011-11-10
Accepted 2012-01-04
Published 2012-03-31

Priya Hewavitharanage

Department of Chemistry, University of Southern Indiana, Evansville, Indiana, 47712, USA

Prince Nzeata

Department of Chemistry, University of Southern Indiana, Evansville, Indiana, 47712, USA

Jeffrey Wiggins

School of Polymers and High Performance Materials, University of Southern Mississippi, Hattiesburg, Mississippi, 39406, USA

Abstract

A novel fluorescent co-polymer with an organoboron quinolate and an E-BODIPY (BODIPY: 4,4-difluoro-4-bora-3a-4a-diaza-s-indacene) moiety was synthesized with the aim of producing a donor-acceptor polymeric system where the organoboron quinolate acts as the donor and the E-BODIPY moiety is the acceptor. The polymer has three prominent absorption bands: 264 nm (corresponding to the organoboron quinolate), 397 nm (corresponding to the organoboron quinolate and BODIPY) and 516 nm (corresponding to the E-BODIPY moiety). Excitation of the organoboron quinolate at 264 nm resulted in emission at 525 nm, giving a 261 nm Stokes shift. Energy transfer from the donor (organoboron quinolate) unit to the acceptor (BODIPY) explains the origin of this large Stokes shift.

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How to Cite

(1)

Hewavitharanage, P.; Nzeata, P.; Wiggins, J. Synthesis of an E-BODIPY Based Fluorescent Co-Polymer Containing Organoboron Quinolate Units. Eur. J. Chem. 2012, 3, 13-16.

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Supporting Agencies

Science and Engineering Research Grant Award of University of the Southern Indiana (Project No, 17228-01780), Faculty Research and Creative Work Award of the University of Southern Indiana (Project No, 17271-01780) and the Indiana Academy of Science (Proj

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